Identification of an Extensive Series of Cationic Silver Heterometallic Dithiocarbamate Complexes and Observation of Catalytic Ligand-Exchange Reactions by Electrospray Mass Spectrometry

1994 ◽  
Vol 33 (12) ◽  
pp. 2548-2554 ◽  
Author(s):  
Alan M. Bond ◽  
Ray Colton ◽  
Yvonne A. Mah ◽  
John C. Traeger
Keyword(s):  
Mass Spectrometry ◽  
Ligand Exchange ◽  
Electrospray Mass Spectrometry ◽  
Exchange Reactions

Role of sterics in phosphine-ligated gold clusters

2019 ◽  
Vol 21 (4) ◽  
pp. 1689-1699 ◽  
Author(s):  
Katherine A. Parrish ◽  
Mary King ◽  
Marshall R. Ligare ◽  
Grant E. Johnson ◽  
Heriberto Hernández
Keyword(s):  
Mass Spectrometry ◽  
Electrospray Ionization ◽  
Ligand Exchange ◽  
Gold Clusters ◽  
Solution Phase ◽  
Ionization Mass ◽  
Exchange Reactions ◽  
The Stability ◽  
Insight Into

This study examined the solution-phase exchange reactions of triphenylphosphine (PPh3) ligands on Au8L72+ (L = PPh3) gold clusters with three different tolyl ligands using electrospray ionization mass spectrometry to provide insight into how steric differences in the phosphines influence the extent of ligand exchange and the stability of the resulting mixed-phosphine clusters.

Lanthanide Complexes of the Kläui Metalloligand, CpCo(P═O(OR)2)3: An Examination of Ligand Exchange Kinetics between Isotopomers by Electrospray Mass Spectrometry

2012 ◽  
Vol 51 (22) ◽  
pp. 12436-12443 ◽  
Author(s):  
Kevin J. H. Allen ◽  
Emma C. Nicholls-Allison ◽  
Kevin R. D. Johnson ◽  
Rajinder S. Nirwan ◽  
David J. Berg ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Ligand Exchange ◽  
Lanthanide Complexes ◽  
Electrospray Mass Spectrometry ◽  
Exchange Kinetics

Ligandenaustauschreaktionen von Molybdänhexacarbonyl mit dreizähnigen diaciden Liganden / Ligand Exchange Reactions of Molybdenum Hexacarbonyl with Tridentate Diacidic Ligands

1997 ◽  
Vol 52 (9) ◽  
pp. 1077-1081
Author(s):  
W. Banße ◽  
J. Fliegner ◽  
H. Hennig ◽  
A. Lehmann ◽  
I. Starke ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Ligand Exchange ◽  
Thermal Activation ◽  
Molybdenum Hexacarbonyl ◽  
Reaction Products ◽  
Exchange Reactions

Abstract Ligand exchange reactions of molybdenum hexacarbonyl with tridentate diacidic ligands were studied by means of photochemical and thermal activation. The reaction products were characterized by mass spectrometry. Species such as MoL2, MoH2L2 and MoO2L could be identified.

Electrospray mass spectrometry of lanthanide β-diketone complexes. II-Ligand-exchange processes involving acetate ions and Ln(tfc)3 complexes

1992 ◽  
Vol 27 (11) ◽  
pp. 1176-1180 ◽  
Author(s):  
Jonathan M. Curtis ◽  
Peter J. Derrick ◽  
André Schnell ◽  
Emilie Constantin ◽  
Richard T. Gallagher ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Ligand Exchange ◽  
Electrospray Mass Spectrometry ◽  
Exchange Processes

Spontaneous Etching of Metal Fluorides Using Ligand-Exchange Reactions: Landscape Revealed by Mass Spectrometry

2021 ◽  
Vol 33 (19) ◽  
pp. 7719-7730
Author(s):  
Ann Lii-Rosales ◽  
Andrew S. Cavanagh ◽  
Andreas Fischer ◽  
Thorsten Lill ◽  
Steven M. George
Keyword(s):  
Mass Spectrometry ◽  
Ligand Exchange ◽  
Exchange Reactions ◽  
Metal Fluorides
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