Reactions of 2-Mercaptobenzoic Acid with Divalent Alkaline Earth Metal Ions:  Synthesis, Spectral Studies, and Single-Crystal X-ray Structures of Calcium, Strontium, and Barium Complexes of 2,2‘-Dithiobis(benzoic acid)†,‡

2001 ◽  
Vol 40 (27) ◽  
pp. 6870-6878 ◽  
Author(s):  
Ramaswamy Murugavel ◽  
Kanhayalal Baheti ◽  
Ganapathi Anantharaman
Author(s):  
John Bacsa ◽  
Fernando Cortés-Guzmán ◽  
Lillian G. G. Ramírez-Palma ◽  
Christian Wallen ◽  
Christopher Scarborough

X-ray crystallographic and theoretical charge density data for a series of compounds [(Co(Ts3tren))M(Co(Ts3tren))] (M = Mg, Ca, Sr and Ba) is examined. The crystal structures are isostructural and the alkaline earth metal ions have the same arrangement of donor oxygen atoms despite the large variation in ionic radii. The isomorphism of these molecules is surprising and a theoretical examination of the electronic structures, with the different metal ions along the series, provides detailed insight into their stabilities. The theoretical and experimental data are consistent and agree well. The local properties of the Co(II) ion and its donor atoms are relatively independent of the alkali earth metal.


2011 ◽  
Vol 50 (15) ◽  
pp. 6956-6964 ◽  
Author(s):  
Wen-Jian Chen ◽  
Da-Hai Yu ◽  
Xin Xiao ◽  
Yun-Qian Zhang ◽  
Qian-Jiang Zhu ◽  
...  

Author(s):  
Yiran Wang ◽  
Wen Zhang ◽  
Xianjie Zeng ◽  
Tao Deng ◽  
Jianyou Wang

2011 ◽  
Vol 3 (1) ◽  
Author(s):  
Nelly Mateeva ◽  
Shihab Deiab ◽  
Edikan Archibong ◽  
Donka Tasheva ◽  
Bereket Mochona ◽  
...  

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