Mild, Reversible Reaction of Iridium(III) Amido Complexes with Carbon Dioxide

2012 ◽  
Vol 51 (18) ◽  
pp. 9683-9693 ◽  
Author(s):  
Graham E. Dobereiner ◽  
Jianguo Wu ◽  
Michael G. Manas ◽  
Nathan D. Schley ◽  
Michael K. Takase ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Reversible Reaction ◽  
Amido Complexes

scholarly journals CO2 activation by permethylpentalene amido zirconium complexes

2021 ◽  
Author(s):  
Elizabeth Hamilton ◽  
Alexander Kilpatrick ◽  
Zoe Turner ◽  
Duncan Fraser ◽  
Jean-Charles Buffet ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Co2 Activation ◽  
Amido Complexes ◽  
Zirconium Complexes

We report the synthesis and characterisation of new permethylpentalene zirconium bis(amido) and permethylpentalene zirconium cyclopentadienyl mono(amido) complexes, and their reactivity with carbon dioxide.

Preparation of cationic cobalt phenoxide and ethoxide complexes and their reversible reaction with carbon dioxide

2002 ◽  
pp. 2797-2799 ◽  
Author(s):  
Stephen J. Archibald ◽  
Simon P. Foxon ◽  
Jonathan D. Freeman ◽  
James E. Hobson ◽  
Robin N. Perutz ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Reversible Reaction

Constructing CO2-facilitated transport highway in supported ionic liquid membranes

2014 ◽  
Vol 07 (02) ◽  
pp. 1450012 ◽  
Author(s):  
Xiang Jun Sun ◽  
Ju Jie Luo ◽  
Meng Zhang ◽  
Jin Ping Li
Keyword(s):  
Carbon Dioxide ◽  
Ionic Liquid ◽  
Upper Bound ◽  
Liquid Membrane ◽  
Facilitated Transport ◽  
Reversible Reaction ◽  
Liquid Membranes ◽  
Supported Ionic Liquid ◽  
Selective Membrane ◽  
Supported Ionic Liquid Membranes

A Carbon dioxide-facilitated transport highway ( CO 2-FTH) on the microporous surface of a membrane matrix was designed using the amino carrier 3-aminopropyltriethoxysilane (APTES). Owing to the reversible reaction between CO 2 molecules and fixed-site carriers, this supported ionic liquid membrane was able to selectively transfer CO 2 more quickly. This concept may inspire means of fabricating a highly permeable and selective membrane to break through Robeson's upper bound.

scholarly journals A LATENT PERIOD IN THE ACTION OF COPPER ON RESPIRATION

1926 ◽  
Vol 9 (5) ◽  
pp. 631-650 ◽  
Author(s):  
S. F. Cook
Keyword(s):  
Carbon Dioxide ◽  
Aspergillus Niger ◽  
Latent Period ◽  
Normal Level ◽  
Copper Chloride ◽  
External Solution ◽  
Reversible Reaction ◽  
Constant Power

1. When copper chloride is allowed to act on Aspergillus niger there is at first a period during which there is no change in the rate of the production of carbon dioxide, following which the rate of respiration falls. The interval of no change is called the latent period. 2. When the copper is removed from the external solution before the end of the latent period this interval is prolonged. The rate of respiration then falls to a new level below the normal level. 3. Experiments on Nitella and on Valonia indicate that the copper penetrates the cell almost immediately. 4. The length of the latent period varies inversely as a constant power of the concentration of the copper. 5. These results are explained by assuming that the copper is made active in the respiration system by means of a reversible reaction. By using appropriate velocity constants the experimental curves can be duplicated by calculated curves.

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