Preparation of cationic cobalt phenoxide and ethoxide complexes and their reversible reaction with carbon dioxide

Author(s):  
Stephen J. Archibald ◽  
Simon P. Foxon ◽  
Jonathan D. Freeman ◽  
James E. Hobson ◽  
Robin N. Perutz ◽  
...  
2012 ◽  
Vol 51 (18) ◽  
pp. 9683-9693 ◽  
Author(s):  
Graham E. Dobereiner ◽  
Jianguo Wu ◽  
Michael G. Manas ◽  
Nathan D. Schley ◽  
Michael K. Takase ◽  
...  

2014 ◽  
Vol 07 (02) ◽  
pp. 1450012 ◽  
Author(s):  
Xiang Jun Sun ◽  
Ju Jie Luo ◽  
Meng Zhang ◽  
Jin Ping Li

A Carbon dioxide-facilitated transport highway ( CO 2-FTH) on the microporous surface of a membrane matrix was designed using the amino carrier 3-aminopropyltriethoxysilane (APTES). Owing to the reversible reaction between CO 2 molecules and fixed-site carriers, this supported ionic liquid membrane was able to selectively transfer CO 2 more quickly. This concept may inspire means of fabricating a highly permeable and selective membrane to break through Robeson's upper bound.


1926 ◽  
Vol 9 (5) ◽  
pp. 631-650 ◽  
Author(s):  
S. F. Cook

1. When copper chloride is allowed to act on Aspergillus niger there is at first a period during which there is no change in the rate of the production of carbon dioxide, following which the rate of respiration falls. The interval of no change is called the latent period. 2. When the copper is removed from the external solution before the end of the latent period this interval is prolonged. The rate of respiration then falls to a new level below the normal level. 3. Experiments on Nitella and on Valonia indicate that the copper penetrates the cell almost immediately. 4. The length of the latent period varies inversely as a constant power of the concentration of the copper. 5. These results are explained by assuming that the copper is made active in the respiration system by means of a reversible reaction. By using appropriate velocity constants the experimental curves can be duplicated by calculated curves.


Author(s):  
Shreyasi Dutta ◽  
Shrinkhla Shrinkla ◽  
Mohamed Khalil Kallangodan ◽  
Anand VP Gurumoorthy

Abstract: One of the promising technologies for isolating carbon dioxide from a mixture of industrial flue gases is the calcium looping process. This process involves a reversible reaction between sorbent Calcium Oxide and Carbon Dioxide. Because sorbent loses its activity after multiple cycles, hydration step was proposed, which is another reversible reaction where deactivated sorbent is treated with steam to form Ca(OH)2, which undergoes the backward reaction to give back the regenerated sorbent. Blamey et al. (2016) developed a shrinking core model based on which, studies were carried out on a small experimental reactor. This paper aims at developing a hybrid model by combining [1] first principles model and an ANN model for improved prediction of the conversion in hydration of calcium looping process and to scale it up for optimal operations. The hybrid model is tested for various combinations of training variables and data sets with respect to temperature and cycle number and it is found that the hybrid model indeed gives better results. The performance prediction of Hybrid modelling is compared to the individual performance prediction of the ANN model and First principles approach


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