Crystal Field Splitting of the Ground State of Terbium(III) and Dysprosium(III) Complexes with a Triimidazolyl Tripod Ligand and an Acetate Determined by Magnetic Analysis and Luminescence

2014 ◽  
Vol 53 (19) ◽  
pp. 10359-10369 ◽  
Author(s):  
Seira Shintoyo ◽  
Keishiro Murakami ◽  
Takeshi Fujinami ◽  
Naohide Matsumoto ◽  
Naotaka Mochida ◽  
...  
Keyword(s):  
Crystal Field ◽  
Ground State ◽  
Crystal Field Splitting ◽  
Field Splitting ◽  
Magnetic Analysis

Large Ground-State and Excited-State Crystal Field Splitting of 8-fold-Coordinate Cm3+in [Y(H2O)8]Cl3·15-crown-5

2006 ◽  
Vol 110 (11) ◽  
pp. 5279-5285 ◽  
Author(s):  
Patric Lindqvist-Reis ◽  
Clemens Walther ◽  
Reinhardt Klenze ◽  
Andreas Eichhöfer ◽  
Thomas Fanghänel
Keyword(s):  
Excited State ◽  
Crystal Field ◽  
Ground State ◽  
Crystal Field Splitting ◽  
Field Splitting

scholarly journals Magnetic Susceptibility Studies and Possible Ground State Crystal Field Splitting of Two Organometallic Neptunium(IV) Complexes

1969 ◽  
Vol 24 (4) ◽  
pp. 616-620 ◽  
Author(s):  
R. D. Fischer ◽  
P. Laubereac
Keyword(s):  
Magnetic Susceptibility ◽  
Liquid Helium ◽  
Crystal Field ◽  
Ground State ◽  
Room Temperature ◽  
Crystal Field Splitting ◽  
Zero Field ◽  
Molecular Symmetry ◽  
Zero Field Splitting ◽  
Field Splitting

Abstract Extensive paramagnetic susceptibility studies between liquid helium and room temperature have been carried out on polycrystalline samples of the two organometallic Np(IV)-complexes Np(C5H5)4 and (C5H5)3NpCl. From a combined interpretation of the corresponding 1/Xm-vs-T-and μ2eff-vs-T-curves, respectively, is suggested that, in accordance with the tetrahedral molecular symmetry to be assumed for Xp(C5H5)4, a cubic Τ8 crystal field level should lie lowest in this compound. The zero field splitting is apparentlv smaller th an 5 cm-1.

Crystal-Field Splitting of Orthohydrogen in Solid Parahydrogen

1967 ◽  
Vol 19 (25) ◽  
pp. 1417-1420 ◽  
Author(s):  
Walter N. Hardy ◽  
James R. Gaines
Keyword(s):  
Crystal Field ◽  
Crystal Field Splitting ◽  
Field Splitting
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