Crystal-field splitting of the Cr4+ terms in LiAlO2 oxide crystal

2004 ◽  
Vol 106 (3-4) ◽  
pp. 205-210 ◽  
Author(s):  
Souha Kammoun
1967 ◽  
Vol 19 (25) ◽  
pp. 1417-1420 ◽  
Author(s):  
Walter N. Hardy ◽  
James R. Gaines

1974 ◽  
Vol 52 (18) ◽  
pp. 1759-1764 ◽  
Author(s):  
F. T. Hedgcock ◽  
S. Lenis ◽  
P. L. Li ◽  
J. O. Ström-Olsen ◽  
E. F. Wassermann

We have extended the low temperature magnetic anisotropy measurements on single crystals of zinc containing up to 600 p.p.m. manganese from magnetic fields of 9 to 56 kG. The crystal field splitting parameters determined at low magnetic fields also characterizes the magnetic anisotropy at high magnetic fields. Manganese–manganese interaction effects are observed in the magnetic anisotropy at manganese concentrations greater than 300 p.p.m. Low temperature magnetic anisotropy measurements on single crystals of zinc containing up to 164 p.p.m. chromium are reported and indicate a crystal field splitting of 0.16 K for the chromium ion.


2014 ◽  
Vol 53 (19) ◽  
pp. 10359-10369 ◽  
Author(s):  
Seira Shintoyo ◽  
Keishiro Murakami ◽  
Takeshi Fujinami ◽  
Naohide Matsumoto ◽  
Naotaka Mochida ◽  
...  

1996 ◽  
Vol 442 ◽  
Author(s):  
Harald Overhof

AbstractThe electronic properties of 3d transition metal (TM) defects located on one of the four different tetrahedral positions in 3C SiC are shown to be quite site-dependent. We explain the differences for the 3d TMs on the two substitutional sites within the vacancy model: the difference of the electronic structure between the carbon vacancy VC and the silicon vacancy VSi is responsible for the differences of the 3d TMs. The electronic properties of 3d TMs on the two tetrahedral interstitial sites differ even more: the TMs surrounded tetrahedrally by four Si atoms experience a large crystal field splitting while the tetrahedral C environment does not give rise to a significant crystal field splitting at all. It is only in the latter case that high-spin configurations are predicted.


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