Solar energy storage reactions. Determination of the structure of the complex formed by visible irradiation of Rh2(bridge)42+ in aqueous hydrochloric acid solutions

1979 ◽  
Vol 18 (10) ◽  
pp. 2671-2673 ◽  
Author(s):  
Kent R. Mann ◽  
Robert A. Bell ◽  
Harry B. Gray





1960 ◽  
Vol 38 (12) ◽  
pp. 2488-2492 ◽  
Author(s):  
D. E. Ryan

Zirconium is completely precipitated by benzoylphenylhydroxylamine from 0.5 N acid solutions. The complex formed in sulphuric acid solutions has a constant composition, Zr(C13H10O2N)4, and is used for the direct weighing of zirconium; the factor is 0.0970. The product precipitated from hydrochloric acid solutions must be ignited to the oxide. The reaction is sensitive, 1 p.p.m. of zirconium being detectable, and quantitative determination of 0.2 mg is possible. Thorium and the rare earths do not interfere.



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