THE DETERMINATION OF ZIRCONIUM WITH BENZOYLPHENYLHYDROXYLAMINE

1960 ◽  
Vol 38 (12) ◽  
pp. 2488-2492 ◽  
Author(s):  
D. E. Ryan
Keyword(s):  
Hydrochloric Acid ◽  
Quantitative Determination ◽  
Sulphuric Acid ◽  
Rare Earths ◽  
Acid Solutions ◽  
Constant Composition ◽  
Hydrochloric Acid Solutions

Zirconium is completely precipitated by benzoylphenylhydroxylamine from 0.5 N acid solutions. The complex formed in sulphuric acid solutions has a constant composition, Zr(C13H10O2N)4, and is used for the direct weighing of zirconium; the factor is 0.0970. The product precipitated from hydrochloric acid solutions must be ignited to the oxide. The reaction is sensitive, 1 p.p.m. of zirconium being detectable, and quantitative determination of 0.2 mg is possible. Thorium and the rare earths do not interfere.

Hydrogen-induced cracking of pure titanium in sulphuric acid and hydrochloric acid solutions using constant load method

2008 ◽  
Vol 50 (9) ◽  
pp. 2691-2697 ◽  
Author(s):  
Rokuro Nishimura ◽  
Jun Shirono ◽  
Akinobu Jonokuchi
Keyword(s):  
Hydrochloric Acid ◽  
Sulphuric Acid ◽  
Pure Titanium ◽  
Constant Load ◽  
Acid Solutions ◽  
Hydrochloric Acid Solutions ◽  
Hydrogen Induced Cracking

THE SEPARATION OF SMALL AMOUNTS OF THE PLATINUM METALS: 1. THE COLORIMETRIC DETERMINATION OF RHODIUM AND ITS SEPARATION FROM IRIDIUM

1961 ◽  
Vol 39 (12) ◽  
pp. 2389-2393 ◽  
Author(s):  
D. E. Ryan
Keyword(s):  
Hydrochloric Acid ◽  
Stannous Chloride ◽  
Colorimetric Determination ◽  
Acid Solutions ◽  
Platinum Metals ◽  
Hydrochloric Acid Solutions ◽  
Product Separation ◽  
Chromous Chloride ◽  
Made In

A method for separating small amounts of rhodium from iridium is described. In 3 to 9 M hydrochloric acid solutions, the amber-to-red complex of bivalent rhodium with 4,5-dimethyl-2-mercaptothiazole is formed after reduction of tervalent rhodium with chromous or stannous chloride. Rhodium is quantitatively separated from iridium by chloroform extraction of this product; separation can be made in solutions that have been fumed with sulphuric acid if chromous chloride is used for the prior reduction of the rhodium. The complex, after removal of the chloroform, is dissolved in dilute hydrochloric acid, and the optical density of the resulting colored solution is measured.

Tritrimetric determination of ruthenium in hydrochloric acid solutions by prereduction with excess iron(II)

1970 ◽  
Vol 42 (4) ◽  
pp. 533-534 ◽  
Author(s):  
Lawrence W. Potts ◽  
Peter J. Lingane
Keyword(s):  
Hydrochloric Acid ◽  
Acid Solutions ◽  
Excess Iron ◽  
Hydrochloric Acid Solutions
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