Theoretical Study of Structure, Bonding, and Electronic Behavior of Low-Valent Bismuth Cyclopentadienyl and Pentamethylcyclopentadienyl Half-Sandwich Compounds

2009 ◽  
Vol 48 (14) ◽  
pp. 6986-6996 ◽  
Author(s):  
Kirill Yu. Monakhov ◽  
Gerald Linti
Keyword(s):  
Theoretical Study ◽  
Sandwich Compounds ◽  
Low Valent ◽  
Half Sandwich ◽  
Electronic Behavior

scholarly journals Uranium(iv) cyclobutadienyl sandwich compounds: synthesis, structure and chemical bonding

2020 ◽  
Vol 56 (6) ◽  
pp. 944-947 ◽  
Author(s):  
Nikolaos Tsoureas ◽  
Akseli Mansikkamäki ◽  
Richard A. Layfield
Keyword(s):  
Chemical Bonding ◽  
Molecular Structures ◽  
Sandwich Complexes ◽  
Sandwich Complex ◽  
Sandwich Compounds ◽  
Bonding Properties ◽  
Half Sandwich

The synthesis, molecular structures and bonding properties of two uranium(iv) cyclobutadienyl half-sandwich complexes and a doubly activated cyclobutadienyl sandwich complex are described.

scholarly journals Strong metal–borane interactions in low-valent cyclopentadienyl rhodium complexes

2019 ◽  
Vol 55 (85) ◽  
pp. 12837-12840
Author(s):  
Maxime Boudjelel ◽  
Sonia Mallet-Ladeira ◽  
Ghenwa Bouhadir ◽  
Didier Bourissou
Keyword(s):  
Rhodium Complexes ◽  
Low Valent ◽  
Half Sandwich

Half-sandwich Rh(i) complexes stabilized by η3-BCC or η1-B borane coordination.

Dual Catalytic Cycle of H2 and H2O Oxidations by a Half-Sandwich Iridium Complex: A Theoretical Study

2019 ◽  
Vol 58 (11) ◽  
pp. 7274-7284 ◽  
Author(s):  
Kei Ikeda ◽  
Yuta Hori ◽  
Muhammad Haris Mahyuddin ◽  
Yoshihito Shiota ◽  
Aleksandar Staykov ◽  
...  
Keyword(s):  
Theoretical Study ◽  
Catalytic Cycle ◽  
Iridium Complex ◽  
Half Sandwich

Construction of double- and triple-decker sandwich compounds from half-sandwich compounds: a theoretical assessment

2015 ◽  
Vol 21 (8) ◽  
Author(s):  
Mei Zhang ◽  
Xueying Zhang ◽  
Lingpeng Meng ◽  
Qingzhong Li ◽  
Xiaoyan Li
Keyword(s):  
Sandwich Compounds ◽  
Theoretical Assessment ◽  
Half Sandwich

Stacking of cyclopentadienyl organometallic sandwich and half-sandwich compounds. Strong interactions of sandwiches at large offsets

CrystEngComm ◽  
2018 ◽  
Vol 20 (31) ◽  
pp. 4506-4514 ◽  
Author(s):  
Dušan P. Malenov ◽  
Ivana S. Antonijević ◽  
Michael B. Hall ◽  
Snežana D. Zarić
Keyword(s):  
Strong Interactions ◽  
Sandwich Compounds ◽  
Half Sandwich

73% of stacking of Cp sandwiches in the CSD is at large offsets, since these interactions are relatively strong. Much weaker stacking between Cp half-sandwiches is surprising 60% of all stacks, due to more simultaneous interactions.

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