Interaction of Carbon Dioxide with Transition-Metal-Substituted Heteropolyanions in Nonpolar Solvents. Spectroscopic Evidence for Complex Formation

1998 ◽  
Vol 37 (17) ◽  
pp. 4344-4352 ◽  
Author(s):  
Steven H. Szczepankiewicz ◽  
Calogero M. Ippolito ◽  
Brian P. Santora ◽  
Thomas J. Van de Ven ◽  
Giuseppe A. Ippolito ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Complex Formation ◽  
Transition Metal ◽  
Spectroscopic Evidence ◽  
Nonpolar Solvents

Carbon Dioxide-Mediated C(sp2)–H Arylation of Primary and Secondary Benzylamines

2018 ◽  
Author(s):  
Mohit Kapoor ◽  
Pratibha Chand-Thakuri ◽  
Michael Young
Keyword(s):  
Carbon Dioxide ◽  
Transition Metal ◽  
Bond Activation ◽  
Bond Formation ◽  
Carbon Bond ◽  
Chelate Effect ◽  
Free Amine ◽  
Carbon Carbon Bond ◽  
New Strategy ◽  
Metal Catalyzed

Carbon-carbon bond formation by transition metal-catalyzed C–H activation has become an important strategy to fabricate new bonds in a rapid fashion. Despite the pharmacological importance of <i>ortho</i>-arylbenzylamines, however, effective <i>ortho</i>-C–C bond formation from C–H bond activation of free primary and secondary benzylamines using Pd<sup>II</sup> remains an outstanding challenge. Presented herein is a new strategy for constructing <i>ortho</i>-arylated primary and secondary benzylamines mediated by carbon dioxide (CO<sub>2</sub>). The use of CO<sub>2</sub> is critical to allowing this transformation to proceed under milder conditions than previously reported, and that are necessary to furnish free amine products that can be directly used or elaborated without the need for deprotection. In cases where diarylation is possible, a chelate effect is demonstrated to facilitate selective monoarylation.

scholarly journals How bulk and surface properties of Ti4SiC3, V4SiC3, Nb4SiC3 and Zr4SiC3 tune reactivity: A computational study

2021 ◽  
Author(s):  
Matthew Quesne ◽  
C. Richard A. Catlow ◽  
Nora Henriette De Leeuw
Keyword(s):  
Carbon Dioxide ◽  
Transition Metal ◽  
Surface Properties ◽  
In Silico ◽  
Computational Study ◽  
Max Phase ◽  
Early Transition Metal ◽  
Silicon Carbides ◽  
Carbon Dioxide Hydrogenation ◽  
Early Transition

We present several in silico insights into the MAX-phase of early transition metal silicon carbides and explore how these affect carbon dioxide hydrogenation. Periodic desity functional methodology is applied to...

Complex Formation of Semifluorinated γ-Cyclodextrin and Surfactants in Liquid Carbon Dioxide

2006 ◽  
Vol 45 (10) ◽  
pp. 3434-3437 ◽  
Author(s):  
Ha Soo Hwang ◽  
Min Young Lee ◽  
Yeon Tae Jeong ◽  
Seong-Soo Hong ◽  
Yeong-Soon Gal ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Complex Formation ◽  
Liquid Carbon ◽  
Liquid Carbon Dioxide

Competition between Cd(II) and other divalent transition metal ions during complex formation with amino acids, peptides, and chelating agents

2016 ◽  
Vol 327-328 ◽  
pp. 55-69 ◽  
Author(s):  
Maurizio Remelli ◽  
Valeria M. Nurchi ◽  
Joanna I. Lachowicz ◽  
Serenella Medici ◽  
M. Antonietta Zoroddu ◽  
...  
Keyword(s):  
Amino Acids ◽  
Complex Formation ◽  
Transition Metal ◽  
Metal Ions ◽  
Chelating Agents ◽  
Transition Metal Ions
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