Rigorous Kinetic Modeling and Optimization Study of a Modified Claus Unit for an Integrated Gasification Combined Cycle (IGCC) Power Plant with CO2 Capture

2012 ◽  
Vol 51 (5) ◽  
pp. 2362-2375 ◽  
Author(s):  
Dustin Jones ◽  
Debangsu Bhattacharyya ◽  
Richard Turton ◽  
Stephen E. Zitney
Author(s):  
S De ◽  
P K Nag

The effect of supplementary firing on the performance of an integrated gasification combined cycle (IGCC) power plant is studied. The results are presented with respect to a simple ‘unfired’ IGCC power plant with single pressure power generation for both the gas and the steam cycles as reference. The gases are assumed as real with variable specific heats. It is found that the most favourable benefit of supplementary firing can be obtained for a low temperature ratio R T only. For higher R T, only a gain in work output is possible with a reverse effect on the overall efficiency of the plant. The second law analysis reveals that the exergy loss in the heat-recovery steam generator is most significant as the amount of supplementary firing increases. It is also noteworthy that, although the total exergy loss of the plant decreases with higher supplementary firing for a low R T (= 3.0), the reverse is the case for a higher R T (= 6.0).


Author(s):  
Peng Pei ◽  
Manohar Kulkarni

Integrated Gasification Combined Cycle (IGCC) is believed to be one of the most promising technologies to offer electricity and other de-carbon fuels with carbon capture requirement as well as to meet other emission regulations at a relatively low cost. As one of the most important parts, different gasification technologies can greatly influence the performance of the system. This paper develops a model to examine the feasibilities and advantages of using Ultra Superheated Steam (USS) gasification technology in IGCC power plant with carbon dioxide capture and storage (CCS). USS gasification technology converts coal into syngas by the endothermic steam reforming reaction, and the heat required for this reaction is provided by the sensible heat in the ultra superheated steam. A burner utilizes synthetic air (21% O2 and 79% H2O) to burn fuel gas to produce the USS flame for the gasification process. The syngas generated from USS gasification has a higher hydrogen fraction (more than 50%) then other gasification processes. This high ratio of hydrogen is considered to be desired for a “capture-ready” IGCC plant. After gas cleanup and water gas shift reaction, the syngas goes to the Selexol process for carbon dioxide removal. Detailed calculations and analysis are performed to test the performance of USS gasification technology used in IGCC generation systems. Final results such as net output, efficiency penalty for CO2 capture part, and net thermal efficiency are calculated and compared when three different coal types are used. This paper uses published data of USS gasification from previous research at the University of North Dakota. The model also tries to treat the IGCC with carbon dioxide capture system as a whole thermal system, the superheated steam used in USS gasification can be provided by extracting steam from the lower pressure turbine in the Rankine Cycle. The model will make reasonable use of various waste energies and steams for both mechanical and chemical processes to improve the performance of the plant, and incorporate CO2 capture system into the design concept of the power plant.


Sign in / Sign up

Export Citation Format

Share Document