Thermodynamic Analysis of Air-Blown Staged Gasification of Coal in a Flow

One of the ways to environmentally friendly use coal is an integrated gasification combined cycle. The most common oxidizing agent employed in gasification is oxygen. It is feasible to use air instead of oxygen to reduce the cost of generated electricity. The air gasification downsides can be reduced by using heated air and organizing a staged process. The paper is concerned with a thermodynamic analysis of the MHPS (Mitsubishi Hitachi Power Systems) air-blown staged gasifier. The analysis relies on an original approach that suggests investigating experimental data on a set of calculated ones. The experimental run nears the thermodynamic optimum, which coincides with the carbon boundary line. Cold gas efficiency can be increased from 78.6 to 81.5% by reducing the equivalence ratio. Thus, the temperature will decrease from 1 200 to 1 100 °C. The experimental run of the MHPS gasifier is not optimal thermodynamically, but it is probably optimal kinetically. The fact is that the rates of heterophase reactions decline near the carbon boundary, which leads to a sharp increase in fuel underburning and a decrease in efficiency. The experimental run is also located close to the region with the maximum thermal efficiency of the process, which is indicative of the high efficiency of converting air heat into chemical energy of producer gas.

Optimization of Integrated Gasification Combined-Cycle Power Plant for Polygeneration of Power and Chemicals

Efficient and flexible operation is essential for competitiveness in the energy market. However, the CO2 emissions of conventional power plants have become an increasingly significant environmental dilemma. In this study, the optimization of a steam power process of an IGCC was carried out, which improved the overall performance of the plant. CCPP with a subcritical HRSG was modelled using EBSILON Professional. The numerical results of the model were validated by measurements for three different load cases (100, 80, and 60%). The results are in agreement with the measured data, with deviations of less than 5% for each case. Based on the model validation, the model was modified for the use of syngas as feed and the integration of heat into an IGCC process. The integration was optimized with respect to the performance of the CCPP by varying the extraction points, adjusting the steam parameters of the extractions and modifying the steam cycle. For the 100% load case, a steam turbine power achieved increase of +34.2%. Finally, the optimized model was subjected to a sensitivity analysis to investigate the effects of varying the extraction mass flows on the output.

Synthesis of ZnO-CuO and ZnO-Co3O4 Materials with Three-Dimensionally Ordered Macroporous Structure and Its H2S Removal Performance at Low-Temperature

H2S is a common but hazardous impurity in syngas, biogas, or natural gas. For some advanced power generation technologies, such as integrated gasification combined cycle (IGCC), solid oxide fuel cells, H2S content needs to be reduced to an acceptable level. In this work, a series of highly porous Zn-Cu and Zn-Co composites with three-dimensionally ordered macropores (3DOM) structure were synthesized via the colloidal crystal template method and used to remove H2S at 150 °C and one atm. Scanning electron microscopy (SEM), transmission electron microscopy (TEM), nitrogen adsorption studies, X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS) were carried out to analyze the fresh and spent adsorbents. The results show that all the adsorbents possess well-ordered macropores, a large surface area, and a highly dispersed active phase. The relative content of Zn and (Cu or Co) has a significant influence on the desulfurization performance of adsorbents. The addition of CuO significantly increases the sulfur capacity and 3DOM-Zn0.5Cu0.5 shows the largest sulfur capacity of all the adsorbents, reaching up to 102.5 mg/g. The multiple adsorption/regeneration cycles of 3DOM-Zn0.5Cu0.5 and 3DOM-Zn0.5Co0.5 indicate that the as-prepared adsorbents are stable, and the sulfur capacity can still exceed 65% of the fresh adsorbents after six cycles.

Research and development of high efficiency low emission combined cycle power plant arrangements

Coal-fired steam turbine thermal power plants produce a large part of electricity. These power plants usually have low efficiency and high carbon dioxide emission. An application of combined cycle power plants with coal gasification equipped with carbon capture and storage systems may increase the efficiency and decrease the harmful emission. This paper describes investigation of the oxidizer type in the integrated gasification combined cycle combustion chamber and its influence upon the energy and environmental performance. The integrated gasification combined cycle and oxy-fuel combustion technology allow the carbon dioxide capture and storage losses 58% smaller than the traditional air combustion one. The IGCC with air combustion without and with carbon dioxide capture and storage has 53.54 and 46.61% and with oxy-fuel combustion has 34.94 and 32.67% net efficiency. Together with this the CO2 emission drops down from 89.9 to 10.6 gm/kWh. The integrated coal gasification combined cycle with air oxidizer has the best net efficiency.

Investigation on the Cause of the SO2 Generation during Hot Gas Desulfurization (HGD) Process

In the integrated gasification combined cycle (IGCC) process, the sulfur compounds present in coal are converted to hydrogen sulfide (H2S) when the coal is gasified. Due to its harmful effects on sorbent/solvent and environmental regulations, H2S needs to be removed from the product gas stream. To simulate the H2S removal process, desulfurization was carried out using a dry sorbent as a fluidizing material within a bubbling, high-temperature fluidized bed reactor. The ZnO-based sorbent showed not only an excellent capacity of H2S removal but also long-term stability. However, unexpected SO2 gas at a concentration of several hundred ppm was detected during the desulfurization reaction. Thus, we determined that there is an unknown source that supplies oxygen to ZnS, and identified the oxygen supplier through three possibilities: oxygen by reactant (fresh sorbent, ZnO), byproduct (ZnSO4), and product (H2O). From the experiment results, we found that the H2O produced from the reaction reacts with ZnS, resulting in SO2 gas being generated during desulfurization. The unknown oxygen source during desulfurization was deduced to be oxygen from H2O produced during desulfurization. That is, the oxygen from produced H2O reacts with ZnS, leading to SO2 generation at high temperature.

Investigation of Air Extraction and Carbon Capture in an Integrated Gasification Combined Cycle (IGCC) System

Coal is one of the major sources of energy currently as it provides up to 38.5% of the total electricity produced in the world. Burning coal produces pollutants and large amounts of CO2, which contribute to climate change, environmental pollution, and health hazards. Therefore, it is our obligation to utilize coal in a cleaner way. Cleaner coal energy can be produced by using an ultra-supercritical Pulverized Coal (PC) power plant, or by employing the Integrated Gasification Combined Cycle (IGCC). Since the 1970s, the IGCC technology has been developed and demonstrated, but it has still not been widely commercialized. One of the methods to improve IGCC performance is to save the compression power of the air separation unit (ASU) by extracting the compressed air from the exit of the gas turbine as a portion of or the entire air input to the ASU. This paper investigates the effect of various levels of air integration on the IGCC performance. The results show that a moderate air integration ranging from 15% to 20% provides the most effective air-integration. An analysis of implementing a sour-shift pre-combustion carbon capture results in a significant loss of about 5.5 points in efficiency. This study also provides the effect of air integration and carbon capture on emissions including NOx, SOx, CO2, and water consumption.