Pd–Pb/SDB Bimetallic Catalysts for The Direct Oxidative Esterification of Methacrolein to Methyl Methacrylate

2012 ◽  
Vol 51 (46) ◽  
pp. 15004-15010 ◽  
Author(s):  
Baohe Wang ◽  
Wenjuan Sun ◽  
Jing Zhu ◽  
Weili Ran ◽  
Shuang Chen
2018 ◽  
Vol 20 (15) ◽  
pp. 9965-9974 ◽  
Author(s):  
Jing Ma ◽  
Xueqing Yang ◽  
Yan Nie ◽  
Baohe Wang

Taking the one-step oxidative esterification of MAL to MMA as a model reaction, the effects of the hydrophobic carrier SDB copolymer, the reactant CH3OH and the product MMA during the adsorption of H2O on a Pd surface were investigated.


2012 ◽  
Vol 512-515 ◽  
pp. 2390-2393
Author(s):  
Gui Hua Li ◽  
An Feng Wang

In this present work, rare earth elements La was added to catalysts for the oxidative esterification of methacrolein (MAL) to methyl methacrylate(MMA). Catalysts were characterized by means of BET techniques. Effects of La proportion, material liquid pH and catalyst amount on catalytic performance were investigated. The results indicated that the addation of La in appropriate proportion could improve the catalyst’s activity. 1.0% was found to be the optimum La additional amount. Under the condition of reation temperature 323K, w%(catalyst) 3.6%, proportion of La in the catalyst 1%, pH of material liquid 10.0 the MMA yield could reached up to 89.8%.


ChemCatChem ◽  
2017 ◽  
Vol 9 (7) ◽  
pp. 1230-1241 ◽  
Author(s):  
Jun Gao ◽  
Guoli Fan ◽  
Lan Yang ◽  
Xinzhong Cao ◽  
Peng Zhang ◽  
...  

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