High-Purity Hydrogen Production by Sorption-Enhanced Steam Reforming of Ethanol: A Cyclic Operation Simulation Study

2014 ◽  
Vol 53 (20) ◽  
pp. 8515-8527 ◽  
Author(s):  
Yi-Jiang Wu ◽  
Ping Li ◽  
Jian-Guo Yu ◽  
Adelino F. Cunha ◽  
Alirio E. Rodrigues
2022 ◽  
Vol 184 ◽  
pp. 592-603
Author(s):  
Baoxu Zhang ◽  
Yumin Chen ◽  
Bing Zhang ◽  
Ruifeng Peng ◽  
Qiancheng Lu ◽  
...  

Author(s):  
Ligang Wei ◽  
Kunlan Li ◽  
Yingchong Ma

Abstract A thermodynamic analysis of glycerol steam reforming in the presence of a CO2 adsorbent (CaO) and solid oxygen transfer material (Fe2O3) for high-purity hydrogen production was performed using the Gibbs free energy minimization method. CO in reformate gas was reduced via CO oxidation by Fe2O3 into CO2 coupled with in situ CO2 capture by CaO. The high-purity hydrogen produced without using a downstream reactor has potential application in proton exchange membrane fuel cells (PEMFCs). The influence of temperature (300–1000 °C), pressure (0.1–1.0 MPa), and mole ratios of H2O/glycerol (1–10), CaO/glycerol (0–6), and Fe2O3/glycerol (0–6) on equilibrium gas compositions and carbon formation was evaluated. The produced gas (99.8 mol% H2 and 12.8 ppm CO) was obtained without carbon formation under the optimal conditions (450 °C, 0.1 MPa, CaO/glycerol mole ratio of 3, Fe2O3/glycerol mole ratio of 3 and H2O/glycerol mole ratio of 10), and can be directly used in PEMFCs. However, further optimizations are needed.


Fuel ◽  
2021 ◽  
Vol 293 ◽  
pp. 120430
Author(s):  
Chengxiong Dang ◽  
Hanke Li ◽  
Guangxing Yang ◽  
Yonghai Cao ◽  
Hongjuan Wang ◽  
...  

2013 ◽  
Vol 38 (27) ◽  
pp. 11902-11909 ◽  
Author(s):  
Binlin Dou ◽  
Chao Wang ◽  
Haisheng Chen ◽  
Yongchen Song ◽  
Baozheng Xie

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