Complex formation in the gas-phase reaction of hydrogen bromide with di-tert-butyl peroxide

1967 ◽  
Vol 71 (6) ◽  
pp. 1836-1838 ◽  
Author(s):  
Leslie Batt ◽  
Frank R. Cruickshank
Keyword(s):  
Complex Formation ◽  
Gas Phase ◽  
Hydrogen Bromide ◽  
Phase Reaction ◽  
Gas Phase Reaction ◽  
Tert Butyl ◽  
Butyl Peroxide

scholarly journals Pressure dependent low temperature kinetics for CN + CH3CN: competition between chemical reaction and van der Waals complex formation

2016 ◽  
Vol 18 (22) ◽  
pp. 15118-15132 ◽  
Author(s):  
Chantal Sleiman ◽  
Sergio González ◽  
Stephen J. Klippenstein ◽  
Dahbia Talbi ◽  
Gisèle El Dib ◽  
...  
Keyword(s):  
Low Temperature ◽  
Complex Formation ◽  
Gas Phase ◽  
Rate Coefficient ◽  
Flow Reactor ◽  
Slow Flow ◽  
Phase Reaction ◽  
Gas Phase Reaction ◽  
Low Temperature Kinetics ◽  
Temperature And Pressure

The gas phase reaction between the CN radical and acetonitrile CH3CN was investigated experimentally with a CRESU apparatus and a slow flow reactor as well as theoretically to explore the temperature and pressure dependence of its rate coefficient from 354 K down to 23 K.

ChemInform Abstract: Products of the Gas-Phase Reaction of Methyl tert-Butyl Ether with the OH Radical in the Presence of NOx

ChemInform ◽  
2010 ◽  
Vol 23 (5) ◽  
pp. no-no
Author(s):  
E. C. TUAZON ◽  
W. P. L. CARTER ◽  
S. M. ASCHMANN ◽  
R. ATKINSON
Keyword(s):  
Gas Phase ◽  
Methyl Tert Butyl Ether ◽  
Phase Reaction ◽  
Oh Radical ◽  
Butyl Ether ◽  
Gas Phase Reaction ◽  
Tert Butyl

The gas-phase reaction of acetic acid with hydrogen bromide

1969 ◽  
Vol 22 (4) ◽  
pp. 713 ◽  
Author(s):  
NJ Daly ◽  
MF Gilligan
Keyword(s):  
Carbon Monoxide ◽  
Acetic Acid ◽  
Gas Phase ◽  
Rate Constant ◽  
Methyl Bromide ◽  
Hydrogen Bromide ◽  
Phase Reaction ◽  
Gas Phase Reaction ◽  
First Order ◽  
The Family

In the gas phase, acetic acid reacts with hydrogen bromide in the temperature range 412-492� to give methyl bromide, carbon monoxide, and water. The reaction is first order in each reagent, and the variation of rate constant with temperature is described by the equation �� ����������������� k2 = 1011.67exp(-30400/RT) ml mole-1 sec-1 Possible transition states for the reaction are examined. A mechanism involving an intermediate of the type CH3CO+Br- is possible if the reaction is of the family represented by the hydrogen bromide catalysed decompositions of trimethylacetic, isobutyric, and propionic acids.

scholarly journals The gas-phase reaction of hydrogen bromide with vinyl chloride

1970 ◽  
Vol 23 (11) ◽  
pp. 2379
Author(s):  
KD King ◽  
ES Swinbourne
Keyword(s):  
Gas Phase ◽  
Vinyl Chloride ◽  
Hydrogen Bromide ◽  
Phase Reaction ◽  
Gas Phase Reaction

scholarly journals The gas-phase reaction of acetic acid with hydrogen bromide. The effect of methanol

1971 ◽  
Vol 24 (5) ◽  
pp. 1081
Author(s):  
NJ Daly ◽  
MF Gilligan
Keyword(s):  
Acetic Acid ◽  
Gas Phase ◽  
Hydrogen Bromide ◽  
Phase Reaction ◽  
Gas Phase Reaction
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