scholarly journals Molecular Attraction, IV, On Biot's Formula for Vapor Pressure and Some Relations at the Critical Temperature

1905 ◽  
Vol 9 (5) ◽  
pp. 402-417 ◽  
Author(s):  
J. E. Mills
1969 ◽  
Vol 47 (3) ◽  
pp. 267-273 ◽  
Author(s):  
D. H. Bowman ◽  
Ronald A. Aziz ◽  
C. C. Lim

The vapor pressure of liquid argon, krypton, and xenon was measured from below the normal boiling temperature to close to the critical temperature. Functional relations were fitted by a multiple regression analysis to the experimental data. Data of other authors are compared directly with the results presented here.Comparison of the vapor pressure curves for the three liquids showed that the classical corresponding states principle was obeyed only poorly and that it was necessary to include quantum corrections in comparing the reduced curves. The adjusted reduction factors agreed reasonably well with those found from vapor pressure analysis by other workers. De Boer plots on the basis of our potential parameters are more linear than those using the parameters of Boato and Casanova.


1933 ◽  
Vol 9 (5) ◽  
pp. 419-423 ◽  
Author(s):  
J. Marsden ◽  
A. C. Cuthbertson

This paper presents the results of the measurement of the vapor pressure of vinyl acetate, over the temperature range from 0 °C. to the normal boiling point. The determinations were carried out on vacuum distilled samples with an isoteniscope, differing slightly in detail from that used by Smith and Menzies(7).The normal boiling point is 72.5 °C. The molecular heat of evaporation has been found to be 8211 calories. The equation which represents the results is[Formula: see text]Trouton's constant and the critical temperature have been found to be 23.8 and 228.3 °C.


1930 ◽  
Vol 52 (10) ◽  
pp. 3839-3843 ◽  
Author(s):  
G. H. Cady ◽  
J. H. Hildebrand

1967 ◽  
Vol 12 (2) ◽  
pp. 199-202 ◽  
Author(s):  
William D. McCain ◽  
Waldemar T. Ziegler

1974 ◽  
Vol 52 (22) ◽  
pp. 2220-2222 ◽  
Author(s):  
Toyoaki Kimura ◽  
Gordon R. Freeman

The mobility of electrons in xenon increases from 1080 cm2/Vs at 168 K to a maximum of 3900 cm2/Vs at 220 K, then decreases as the temperature is increased further, reaching 21 cm2/Vs at the critical temperature, 290 K. The pressure on the sample was the vapor pressure of the liquid and the field strength was 16 V/cm. Electron scattering appears to be gas-like in the liquid near the critical region, while electron transport occurs in conduction bands in the liquid at lower temperatures.


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