Formation of excited intermediates in recoil carbon atom reactions. Pressure-dependence studies in the gas phase

1969 ◽  
Vol 91 (24) ◽  
pp. 6584-6590 ◽  
Author(s):  
Michael John Welch ◽  
Alfred P. Wolf
Keyword(s):  
Carbon Atom ◽  
Gas Phase ◽  
Pressure Dependence

GAS PHASE RAMAN SPECTRUM OF TCNQ AND PRESSURE DEPENDENCE OF THE MODES IN CRYSTALS OF TNCQ°

1981 ◽  
Vol 42 (C6) ◽  
pp. C6-323-C6-325
Author(s):  
C. Carlone ◽  
N. K. Hota ◽  
H. J. Stolz ◽  
M. Elbert ◽  
H. Kuzmany ◽  
...  
Keyword(s):  
Raman Spectrum ◽  
Gas Phase ◽  
Pressure Dependence

“Stripping” the Carbon Atom of Methyl Halide by a Cationic Holmium Complex: A Gas-Phase Study

2015 ◽  
Vol 21 (41) ◽  
pp. 14305-14308 ◽  
Author(s):  
Shaodong Zhou ◽  
Maria Schlangen ◽  
Jilai Li ◽  
Xiao-Nan Wu ◽  
Helmut Schwarz
Keyword(s):  
Carbon Atom ◽  
Gas Phase ◽  
Phase Study ◽  
Methyl Halide

Far‐Infrared Collision‐Induced Absorption in CO2. II. Pressure Dependence in the Gas Phase and Absorption in the Liquid

1971 ◽  
Vol 55 (3) ◽  
pp. 1039-1045 ◽  
Author(s):  
G. Birnbaum ◽  
W. Ho ◽  
A. Rosenberg
Keyword(s):  
Gas Phase ◽  
Pressure Dependence ◽  
Far Infrared ◽  
Induced Absorption

Rapid Gas-Phase Reactions. Amines and Boron Trifluoride. II. Pressure Dependence of Rate Constant

1969 ◽  
Vol 91 (27) ◽  
pp. 7607-7610 ◽  
Author(s):  
Sol Glicker ◽  
R. A. Marcus
Keyword(s):  
Gas Phase ◽  
Rate Constant ◽  
Pressure Dependence ◽  
Boron Trifluoride ◽  
Gas Phase Reactions

A THEORETICAL STUDY OF THE INTERACTIONS OF IODO-PERFLUOROCARBON AND IODO-HYDROCARBON WITH HALOID ANIONS

2006 ◽  
Vol 05 (04) ◽  
pp. 719-732 ◽  
Author(s):  
YANHUA WANG ◽  
JIANWEI ZOU ◽  
YUNXIANG LU ◽  
QINGSEN YU
Keyword(s):  
Carbon Atom ◽  
Gas Phase ◽  
Theoretical Study ◽  
Halogen Bonds ◽  
Interatomic Distances ◽  
Geometrical Data ◽  
Opposite Order ◽  
Anion Complexes ◽  
Insight Into ◽  
Fluorine Anion

Ab initio calculations have been performed on a series of complexes formed between iodo-perfluorocarbons(PFCs) and iodo-hydrocarbons(HCs) and haloid anions to gain a deeper insight into the nature of halogen bonds. It appears that halogen bonds in these complexes are much stronger than neutral halogen bonds. Calculations also show that the strength of halogen bonds in iodo-PFC⋯ haloid anion dimers are greater than those in iodo-HC⋯ haloid anion dimers. A comparison of the two complex series reveals that the hybridization state of the carbon atom bonded to iodine has a less pronounced effect on the interatomic distances I⋯X in the iodo-PFC series in relation to the iodo-HC series. PCM calculations used to investigate the solvent effect on halogen bonds unveil that, in the gas phase, fluorine anion prefers to form halogen-bonded complexes with respect to chloride, bromide, and iodine anions; however, the preference is not obvious, and even an opposite order is observed in solutions. It is worth mentioning that the iodo-PFC⋯ fluorine anion complexes present a special structure, i.e. the interatomic I⋯F distances in these complexes are relatively short and the corresponding C–I bonds tend to be further broken. These features, in combination with the geometrical data, indicate that ate-complexes are formed between iodo-PFC and fluorine anions.

Reactions of the isopropoxyl radical. Part II. Pressure dependence and kinetics of pyrolysis at 160–200° in the gas phase

1966 ◽  
Vol 0 (0) ◽  
pp. 245-249 ◽  
Author(s):  
D. L. Cox ◽  
R. A. Livermore ◽  
L. Phillips
Keyword(s):  
Gas Phase ◽  
Pressure Dependence ◽  
Kinetics Of
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