Fluorinated Heterometallic β-Diketonates as Volatile Single-Source Precursors for the Synthesis of Low-Valent Mixed-Metal Fluorides

2011 ◽  
Vol 133 (4) ◽  
pp. 692-694 ◽  
Author(s):  
Anantharamulu Navulla ◽  
Alexander A. Tsirlin ◽  
Artem M. Abakumov ◽  
Roman V. Shpanchenko ◽  
Haitao Zhang ◽  
...  
Keyword(s):  
Single Source ◽  
Single Source Precursors ◽  
Mixed Metal ◽  
Metal Fluorides ◽  
Low Valent

ChemInform Abstract: Fluorinated Heterometallic β-Diketonates as Volatile Single-Source Precursors for the Synthesis of Low-Valent Mixed-Metal Fluorides.

ChemInform ◽  
2011 ◽  
Vol 42 (16) ◽  
pp. no-no
Author(s):  
Anantharamulu Navulla ◽  
Alexander A. Tsirlin ◽  
Artem M. Abakumov ◽  
Roman V. Shpanchenko ◽  
Haitao Zhang ◽  
...  
Keyword(s):  
Single Source ◽  
Single Source Precursors ◽  
Mixed Metal ◽  
Metal Fluorides ◽  
Low Valent

Rubidium–Alkaline-Earth Trifluoroacetate Hybrids as Self-Fluorinating Single-Source Precursors to Mixed-Metal Fluorides

2019 ◽  
Vol 58 (5) ◽  
pp. 3041-3049 ◽  
Author(s):  
Regina G. Szlag ◽  
Leopoldo Suescun ◽  
B. Dulani Dhanapala ◽  
Federico A. Rabuffetti
Keyword(s):  
Alkaline Earth ◽  
Single Source ◽  
Single Source Precursors ◽  
Mixed Metal ◽  
Metal Fluorides

Aerosol Routes to Perovskite Phase Mixed Metal Oxides

1993 ◽  
Vol 310 ◽  
Author(s):  
C.D. Chandler ◽  
Q. Powell ◽  
M.J. Hampden-Smith ◽  
T.T. Kodas
Keyword(s):  
Metal Oxide ◽  
Low Temperatures ◽  
Perovskite Phase ◽  
Mixed Metal Oxide ◽  
Single Source ◽  
Single Source Precursors ◽  
Mixed Metal ◽  
Oxide Powders ◽  
Metal Organic ◽  
Oxide Particles

AbstractSub-micron sized metal oxide particles were formed via aerosol decomposition using single-source mixed metal-organic precursors specifically designed to decompose at low temperatures. The advantage of these single-source precursors over mixtures of individual precursors is that each particle contains a fixed stoichiometry and molecular level homogeneity. Furthermore, the loss of volatile intermediates (such as PbO) may be avoided. Aerosol processing routes can produce uniform sub-micron sized powder that can be sintered at low temperatures for various thin film and membrane applications. The single-source precursors were prepared in pyridine by reaction of divalent metal α-hydroxycarboxylates of general empirical formula A(O2CCMe2OH)2 (where A = Pb, Ca, Sr, Ba; Me = methyl) with metal alkoxides (for example, Ti(O-i-Pr)4) with the elimination of two equivalents of alcohol. These species were then hydrolyzed in solution and yellow powders were isolated by removal of the pyridine solvent in vacuo. These powders were dissolved in water and used to prepare mixed metal oxide powders via spray pyrolysis. Phase-pure submicron-sized particles of PbTiO3 and BaTiO3 were produced at temperatures of 600-900 °C. The particles were hollow, ranged in size from 0.1 to 1 μm and consisted of 30-50 nm crystallites.

scholarly journals The use of mixed-metal single source precursors for the synthesis of complex metal oxides

2020 ◽  
Vol 56 (6) ◽  
pp. 854-871 ◽  
Author(s):  
Haijiao Lu ◽  
Dominic S. Wright ◽  
Sebastian D. Pike
Keyword(s):  
Metal Oxide ◽  
Metal Oxides ◽  
Oxide Materials ◽  
Single Source ◽  
Feature Article ◽  
Single Source Precursors ◽  
Mixed Metal ◽  
Complex Metal ◽  
Complex Metal Oxides ◽  
Complex Metal Oxide

This Feature Article highlights the use of mixed-metal single source precursors to directly access useful complex metal oxide materials.

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