Precise Control and Consecutive Modulation of Spin Transition Temperature Using Chemical Migration in Porous Coordination Polymers

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Two iron(iii) complexes, [Fe(qsal-X)2]OTs·nH2O, are found to exhibit abrupt spin crossover with the spin transition temperature substituent dependent, and X⋯O halogen bonds linking the spin centres.


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The incorporation of photochromic moieties into porous coordination polymers is of particular interest due to it can endow them various switchable functions in the electrical conductivity, luminescence, and magnetism. In...


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Control of pore distribution of porous carbons from porous coordination polymers.


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