scholarly journals Pore-Filling-Dependent Selectivity Effects in the Vapor-Phase Separation of Xylene Isomers on the Metal−Organic Framework MIL-47

2008 ◽  
Vol 130 (22) ◽  
pp. 7110-7118 ◽  
Author(s):  
Vincent Finsy ◽  
Harry Verelst ◽  
Luc Alaerts ◽  
Dirk De Vos ◽  
Pierre A. Jacobs ◽  
...  
Keyword(s):  
Phase Separation ◽  
Vapor Phase ◽  
Metal Organic Framework ◽  
Pore Filling ◽  
Metal Organic ◽  
Xylene Isomers ◽  
Organic Framework

Single- and Multicomponent Vapor-Phase Adsorption of Xylene Isomers and Ethylbenzene in a Microporous Metal−Organic Framework

2009 ◽  
Vol 113 (30) ◽  
pp. 13173-13179 ◽  
Author(s):  
Marco P. M. Nicolau ◽  
Patrick S. Bárcia ◽  
Jose M. Gallegos ◽  
José A. C. Silva ◽  
Alírio E. Rodrigues ◽  
...  
Keyword(s):  
Vapor Phase ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Xylene Isomers ◽  
Organic Framework

Solvent-Free Powder Synthesis and MOF-CVD Thin Films of the Mesoporous Metal-Organic Framework MAF-6

2019 ◽  
Author(s):  
Timothée Stassin ◽  
Ivo Stassen ◽  
Joao Marreiros ◽  
Alexander John Cruz ◽  
Rhea Verbeke ◽  
...  
Keyword(s):  
Vapor Phase ◽  
Metal Organic Framework ◽  
Chemical Vapor ◽  
Uptake Capacity ◽  
Powder Synthesis ◽  
Crystalline Films ◽  
Metal Organic ◽  
Mesoporous Metal ◽  
First Time ◽  
Organic Framework

A simple solvent- and catalyst-free method is presented for the synthesis of the mesoporous metal-organic framework (MOF) MAF-6 (RHO-Zn(eIm)2) based on the reaction of ZnO with 2-ethylimidazole vapor at temperatures ≤ 100 °C. By translating this method to a chemical vapor deposition (CVD) protocol, mesoporous crystalline films could be deposited for the first time entirely from the vapor phase. A combination of PALS and Kr physisorption measurements confirmed the porosity of these MOF-CVD films and the size of the MAF-6 supercages (diam. ~2 nm), in close agreement with powder data and calculations. MAF-6 powders and films were further characterized by XRD, TGA, SEM, FTIR, PDF and EXAFS. The exceptional uptake capacity of the mesoporous MAF-6 in comparison to the microporous ZIF-8 is demonstrated by vapor-phase loading of a molecule larger than the ZIF-8 windows.

scholarly journals Vapor‐Phase Linker Exchange of the Metal–Organic Framework ZIF‐8: A Solvent‐Free Approach to Post‐synthetic Modification

2019 ◽  
Vol 58 (51) ◽  
pp. 18471-18475
Author(s):  
João Marreiros ◽  
Lenz Van Dommelen ◽  
Guillaume Fleury ◽  
Rodrigo Oliveira‐Silva ◽  
Timothée Stassin ◽  
...  
Keyword(s):  
Vapor Phase ◽  
Metal Organic Framework ◽  
Solvent Free ◽  
Metal Organic ◽  
Linker Exchange ◽  
Organic Framework

Liquid-Phase Adsorption and Separation of Xylene Isomers by the Flexible Porous Metal–Organic Framework MIL-53(Fe)

2012 ◽  
Vol 24 (14) ◽  
pp. 2781-2791 ◽  
Author(s):  
Racha El Osta ◽  
Abel Carlin-Sinclair ◽  
Nathalie Guillou ◽  
Richard I. Walton ◽  
Frederik Vermoortele ◽  
...  
Keyword(s):  
Liquid Phase ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Liquid Phase Adsorption ◽  
Metal Organic ◽  
Xylene Isomers ◽  
Organic Framework

Framework Breathing in the Vapour-Phase Adsorption and Separation of Xylene Isomers with the Metal-Organic Framework MIL-53

2009 ◽  
Vol 15 (31) ◽  
pp. 7724-7731 ◽  
Author(s):  
Vincent Finsy ◽  
Christine E. A. Kirschhock ◽  
Gill Vedts ◽  
Michael Maes ◽  
Luc Alaerts ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Vapour Phase ◽  
Metal Organic ◽  
Xylene Isomers ◽  
Organic Framework

scholarly journals Modeling adsorption equilibria of xylene isomers in a microporous metal–organic framework

2012 ◽  
Vol 155 ◽  
pp. 220-226 ◽  
Author(s):  
Patrick S. Bárcia ◽  
Marco P.M. Nicolau ◽  
Jose M. Gallegos ◽  
Banglin Chen ◽  
Alírio E. Rodrigues ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Adsorption Equilibria ◽  
Metal Organic ◽  
Xylene Isomers ◽  
Organic Framework

scholarly journals Vapor-Phase Linker Exchange of the Metal-Organic Framework ZIF-8: A Solvent-Free Approach to Post-Synthetic Modification

2019 ◽  
Author(s):  
Joao Marreiros ◽  
Lenz Van Dommelen ◽  
Guillaume Fleury ◽  
Rodrigo de Oliveira-Silva ◽  
Timothée Stassin ◽  
...  
Keyword(s):  
Single Crystal ◽  
Vapor Phase ◽  
Metal Organic Framework ◽  
Solvent Free ◽  
Metal Organic ◽  
Crystal Core ◽  
Linker Exchange ◽  
Selection Of ◽  
Organic Framework

Here we present a novel, solvent-free approach to post-synthetic linker exchange in ZIF-8 through exposure to linker vapor. As in the solvent-based approach, this vapor-phase linker exchange (VPLE) method retains the parent SOD topology and proceeds in a single-crystal to single-crystal manner. The scope of linkers that can be incorporated through VPLE was studied and criteria for the selection of further candidates were formulated. In large crystals, the incoming linker was found to form domains instead of distributing homogeneously, similar as for solution-based linker exchange. In contrast to the latter approach, VPLE yields a higher concentration of the incoming linker in the crystal core instead of the shell.

scholarly journals Vapor-Phase Infiltration inside a Microporous Porphyrinic Metal–Organic Framework for Postsynthesis Modification

2020 ◽  
Vol 59 (14) ◽  
pp. 10129-10137
Author(s):  
Siddhartha De ◽  
Gia Co Quan ◽  
Ben Gikonyo ◽  
Charlotte Martineau-Corcos ◽  
Colin Bousige ◽  
...  
Keyword(s):  
Vapor Phase ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework
Sign in / Sign up

Export Citation Format

Share Document