Electrolytes:  Equilibria in Solutions and Phase Equilibria. Calculation of Multicomponent Systems and Experimental Data on the Activities of Water, Vapor Pressures, and Osmotic Coefficients By G. G. Aseyev (Khar'kov State Institute of Culture). Translated by Stanislav N. Gorin. Begell House:  New York. 1999. vi + 758 pp. $225.00. ISBN 1-56700-122-X.

2000 ◽  
Vol 122 (6) ◽  
pp. 1250-1250
Keyword(s):  
Experimental Data ◽  
New York ◽  
Water Vapor ◽  
Phase Equilibria ◽  
Osmotic Coefficients ◽  
Multicomponent Systems ◽  
Vapor Pressures ◽  
State Institute

Isopiestic determination of osmotic coefficients and evaluation of vapor pressures for solutions of KI, NH4SCN and KSCN in methanol at 25 °C

2004 ◽  
Vol 111 (1-3) ◽  
pp. 7-13
Author(s):  
Karamat Nasirzadeh ◽  
M.T. Zafarani-Moattar
Keyword(s):  
Osmotic Coefficients ◽  
Vapor Pressures

Phase Equilibria in Ferrous Calcium Silicate Slags: Part II. Evaluation of Experimental Data and Computer Thermodynamic Models

2008 ◽  
Vol 39 (2) ◽  
pp. 189-199 ◽  
Author(s):  
Stanko Nikolic ◽  
Hector Henao ◽  
Peter C. Hayes ◽  
Evgueni Jak
Keyword(s):  
Experimental Data ◽  
Phase Equilibria ◽  
Calcium Silicate ◽  
Thermodynamic Models

Phase equilibria in the ternary system (LiCl+Li2SO4+H2O) at T=308.15K and p=0.1MPa: Experimental data and predictions using the Pitzer model

2015 ◽  
Vol 391 ◽  
pp. 85-89 ◽  
Author(s):  
Yuanhui Liu ◽  
Yafei Guo ◽  
Xuekui Wang ◽  
Tianlong Deng
Keyword(s):  
Experimental Data ◽  
Ternary System ◽  
Phase Equilibria ◽  
Pitzer Model

Solid-Fluid Phase Equilibria Measurement for Mixtures of Methane, Carbon-Dioxide and N-Hexadecane

2021 ◽  
Author(s):  
Oluwakemi Victoria Eniolorunda ◽  
Antonin Chapoy ◽  
Rod Burgass
Keyword(s):  
Experimental Data ◽  
Carbon Dioxide ◽  
Equation Of State ◽  
Phase Equilibria ◽  
Activity Coefficients ◽  
Fluid Phase ◽  
Ternary Mixtures ◽  
Binary Interaction ◽  
Thermodynamic Models ◽  
Methane Carbon

Abstract In this study, new experimental data using a reliable approach are reported for solid-fluid phase equilibrium of ternary mixtures of Methane-Carbon-dioxide- n-Hexadecane for 30-73 mol% CO2 and pressures up to 24 MPa. The effect of varying CO2 composition on the overall phase transition of the systems were investigated. Three thermodynamic models were used to predict the liquid phase fugacity, this includes the Peng Robison equation of state (PR-EoS), Soave Redlich-Kwong equation of state (SRK-EoS) and the Cubic plus Association (CPA) equation of state with the classical mixing rule and a group contribution approach for calculating binary interaction parameters in all cases. To describe the wax (solid) phase, three activity coefficient models based on the solid solution theory were investigated: the predictive universal quasichemical activity coefficients (UNIQUAC), Universal quasi-chemical Functional Group activity coefficients (UNIFAC) and the predictive Wilson approach. The solid-fluid equilibria experimental data gathered in this experimental work including those from saturated and under-saturated conditions were used to check the reliability of the various phase equilibria thermodynamic models.

scholarly journals A thermodynamic description of metastable c-TiAlZrN coatings with triple spinodally decomposed domains

2017 ◽  
Vol 53 (2) ◽  
pp. 85-93 ◽  
Author(s):  
J. Zhou ◽  
L. Zhang ◽  
L. Chen ◽  
Y. Du ◽  
Z.K. Liu
Keyword(s):  
Experimental Data ◽  
Phase Equilibria ◽  
First Principles ◽  
Thermodynamic Description ◽  
Quantitative Description ◽  
Experimental Phase Equilibria ◽  
Free Energies ◽  
Calphad Technique ◽  
Important Input ◽  
Good Agreement

A critical thermodynamic assessment of the metastable c-TiAlZrN coatings, which are reported to spinodally decompose into triple domains, i.e., c-TiN, c-AlN, and c-ZrN, was performed via the CALculation of PHAse Diagram (CALPHAD) technique based on the limited experimental data as well as the first-principles computed free energies. The metastable c-TiAlZrN coatings were modeled as a pseudo-ternary phase consisting of c-TiN, c-AlN and c-ZrN species, and described using the substitutional solution model. The thermodynamic descriptions for the three boundary binaries were directly taken from either the CALPHAD assessment or the first-principles results available in the literature except for a re-adjustment of the pseudo-binary c-AlN/c-ZrN system based on the experimental phase equilibria in the pseudo-ternary system. The good agreement between the calculated phase equilibria and the experimental data over the wide temperature range was obtained, validating the reliability of the presently obtained thermodynamic descriptions for the c-TiAlZrN system. Based on the present thermodynamic description, different phase diagrams and thermodynamic properties can be easily predicted. It is anticipated that the present thermodynamic description of the metastable c-TiAlZrN coatings can serve as the important input for the later quantitative description of the microstructure evolution during service life.

Modeling of Solid/Fluid Phase Equilibria in Multicomponent Systems at High Pressure

2001 ◽  
Vol 24 (6) ◽  
pp. 607-612 ◽  
Author(s):  
M. Seiler ◽  
J. Groß ◽  
B. Bungert ◽  
G. Sadowski ◽  
W. Arlt
Keyword(s):  
High Pressure ◽  
Phase Equilibria ◽  
Fluid Phase ◽  
Multicomponent Systems ◽  
Fluid Phase Equilibria

Phase Equilibria in the Ternary System Hexacosane + Dibenzofuran + Biphenyl: Experimental Data and Prediction with DISQUAC Model

2014 ◽  
Vol 59 (6) ◽  
pp. 1991-1997 ◽  
Author(s):  
Abdelaziz Chikh Baelhadj ◽  
Omar Dahmani ◽  
Rachid Mahmoud ◽  
Fabrice Mutelet ◽  
Mohammed Bouroukba ◽  
...  
Keyword(s):  
Experimental Data ◽  
Ternary System ◽  
Phase Equilibria ◽  
Disquac Model
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