New Neutral Nickel and Palladium Sandwich Catalysts: Synthesis of Ultra-High Molecular Weight Polyethylene (UHMWPE) via Highly Controlled Polymerization and Mechanistic Studies of Chain Propagation

2020 ◽  
Vol 142 (15) ◽  
pp. 7198-7206 ◽  
Author(s):  
Quan H. Tran ◽  
Maurice Brookhart ◽  
Olafs Daugulis
Keyword(s):  
Molecular Weight ◽  
High Molecular Weight ◽  
Chain Propagation ◽  
Mechanistic Studies ◽  
Controlled Polymerization ◽  
Ultra High Molecular Weight

Effect of Carbon Coating on the Properties of Gamma Irradiated Ultra-High-Molecular-Weight Polyethylene Specimens

2000 ◽  
Vol 28 (3-4) ◽  
pp. 445-449 ◽  
Author(s):  
Debi P. Mukherjee ◽  
Alan L. Ogden ◽  
R. H. Mayeux ◽  
U. Siriwardane ◽  
H. R. Patel
Keyword(s):  
Molecular Weight ◽  
High Molecular Weight ◽  
Carbon Coating ◽  
Gamma Irradiated ◽  
Ultra High Molecular Weight

Mechanistic Study and Development of Catalytic Reactions of Sm(II)

2018 ◽  
Author(s):  
Sandepan Maity ◽  
Robert Flowers
Keyword(s):  
Molecular Weight ◽  
High Molecular Weight ◽  
Proton Donor ◽  
Catalytic Reactions ◽  
Mechanistic Study ◽  
Mechanistic Studies ◽  
Cyclization Reactions ◽  
Mechanistic Approach ◽  
Donor Source

Despite the broad utility and application of SmI<sub>2</sub>in synthesis, the reagent is used in stoichiometric amounts and has a high molecular weight, resulting in a large amount of material being used for reactions requiring one or more equivalents of electrons. We report mechanistic studies on catalytic reactions of Sm(II) employing a terminal magnesium reductant and trimethyl silyl chloride in concert with a non-coordinating proton donor source. Reactions using this approach permitted reductions with as little as 1 mol% Sm. The mechanistic approach enabled catalysis employing HMPA as a ligand, facilitating the development of catalytic Sm(II) 5-<i>exo</i>-<i>trig </i>ketyl olefin cyclization reactions.

Application of ultra-high molecular weight polyethylene in a hydraulic drive

2020 ◽  
pp. 77-78
Keyword(s):  
Molecular Weight ◽  
Low Temperature ◽  
High Molecular Weight ◽  
Hydraulic Drive ◽  
Control Valve ◽  
Hydraulic Control ◽  
Hydraulic Motor ◽  
Hydraulic Pump ◽  
Hydraulic Oil ◽  
Ultra High Molecular Weight

The use of ultra-high molecular weight polyethylene (UHMW PE) for the manufacture of various parts, in particular cuffs for hydraulic drives, is proposed. The properties and advantages of UHMW PE in comparison with other polyethylene materials are considered. Keywords ultra-high molecular weight polyethylene, hydraulic pump, hydraulic motor, hydraulic control valve, hydraulic oil, low temperature. [email protected]

scholarly journals Structure, processing and performance of ultra-high molecular weight polyethylene (IUPAC Technical Report). Part 4: sporadic fatigue crack propagation

2020 ◽  
Vol 92 (9) ◽  
pp. 1521-1536
Author(s):  
Clive Bucknall ◽  
Volker Altstädt ◽  
Dietmar Auhl ◽  
Paul Buckley ◽  
Dirk Dijkstra ◽  
...  
Keyword(s):  
Molecular Weight ◽  
Fatigue Crack ◽  
Crack Propagation ◽  
High Molecular Weight ◽  
Fatigue Crack Propagation ◽  
Crack Tip ◽  
Individual Growth ◽  
Paris Equation ◽  
Number Of Cycles ◽  
Ultra High Molecular Weight

AbstractFatigue tests were carried out on compression mouldings supplied by a leading polymer manufacturer. They were made from three batches of ultra-high molecular weight polyethylene (UHMWPE) with weight-average relative molar masses, ${\overline{M}}_{\mathrm{W}}$, of about 0.6 × 106, 5 × 106 and 9 × 106. In 10 mm thick compact tension specimens, crack propagation was so erratic that it was impossible to follow standard procedure, where crack-tip stress intensity amplitude, ΔK, is raised incrementally, and the resulting crack propagation rate, da/dN, increases, following the Paris equation, where a is crack length and N is number of cycles. Instead, most of the tests were conducted at fixed high values of ΔK. Typically, da/dN then started at a high level, but decreased irregularly during the test. Micrographs of fracture surfaces showed that crack propagation was sporadic in these specimens. In one test, at ΔK = 2.3 MPa m0.5, there were crack-arrest marks at intervals Δa of about 2 μm, while the number of cycles between individual growth steps increased from 1 to more than 1000 and the fracture surface showed increasing evidence of plastic deformation. It is concluded that sporadic crack propagation was caused by energy-dissipating crazing, which was initiated close to the crack tip under plane strain conditions in mouldings that were not fully consolidated. By contrast, fatigue crack propagation in 4 mm thick specimens followed the Paris equation approximately. The results from all four reports on this project are reviewed, and the possibility of using fatigue testing as a quality assurance procedure for melt-processed UHMWPE is discussed.

Sign in / Sign up

Export Citation Format

Share Document