Conformational Regulation of Multivalent Terpyridine Ligands for Self-Assembly of Heteroleptic Metallo-Supramolecules

2020 ◽  
Vol 142 (39) ◽  
pp. 16661-16667
Author(s):  
Shi-Cheng Wang ◽  
Kai-Yu Cheng ◽  
Jun-Hao Fu ◽  
Yuan-Chung Cheng ◽  
Yi-Tsu Chan
Keyword(s):  
Self Assembly ◽  
Terpyridine Ligands ◽  
Conformational Regulation

Self-assembly of π-conjugated bis(terpyridine) ligands with zinc(II) ions: New metallosupramolecular materials for optoelectronic applications

2009 ◽  
Vol 47 (16) ◽  
pp. 4083-4098 ◽  
Author(s):  
Andreas Winter ◽  
Christian Friebe ◽  
Manuela Chiper ◽  
Martin D. Hager ◽  
Ulrich S. Schubert
Keyword(s):  
Self Assembly ◽  
Terpyridine Ligands ◽  
Optoelectronic Applications

Amalgamating 4′-substituted 4,2′:6′,4′′-terpyridine ligands with double-helical chains or ladder-like networks

RSC Advances ◽  
2016 ◽  
Vol 6 (11) ◽  
pp. 9270-9277 ◽  
Author(s):  
Guoqi Zhang ◽  
Jiawen Tan ◽  
Tonya Phoenix ◽  
David R. Manke ◽  
James A. Golen ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Self Assembly ◽  
Structural Diversity ◽  
Metal Organic ◽  
Terpyridine Ligands ◽  
First Time

HgII-mediated self-assembly of metal–organic coordination polymers based on 4,2′:6′,4′′-terpyridine derivatives is for the first time presented and the structural diversity dependent upon the use of 4′-substituents of ligand is revealed.

Self-assembly of giant supramolecular cubes with terpyridine ligands as vertices and metals on edges

2014 ◽  
Vol 5 (3) ◽  
pp. 1221-1226 ◽  
Author(s):  
Chao Wang ◽  
Xin-Qi Hao ◽  
Ming Wang ◽  
Cunlan Guo ◽  
Bingqian Xu ◽  
...  
Keyword(s):  
Metal Ions ◽  
Self Assembly ◽  
Terpyridine Ligands

Giant metallo-supramolecular cubes were assembled by using tritopic terpyridine ligands as corners and metal ions as edges.

Hexagon Wreaths: Self-Assembly of Discrete Supramolecular Fractal Architectures Using Multitopic Terpyridine Ligands

2014 ◽  
Vol 136 (18) ◽  
pp. 6664-6671 ◽  
Author(s):  
Ming Wang ◽  
Chao Wang ◽  
Xin-Qi Hao ◽  
Jingjing Liu ◽  
Xiaohong Li ◽  
...  
Keyword(s):  
Self Assembly ◽  
Terpyridine Ligands

Synthesis and photophysical properties for fluorescent hexameric metallomacrocycles: Zinc(II)-mediated self-assembly of bis(terpyridine) ligands

2007 ◽  
Vol 360 (5) ◽  
pp. 1780-1784 ◽  
Author(s):  
Seok-Ho Hwang ◽  
Charles N. Moorefield ◽  
Pingshan Wang ◽  
Jeong-Yeol Kim ◽  
Sang-Won Lee ◽  
...  
Keyword(s):  
Self Assembly ◽  
Photophysical Properties ◽  
Terpyridine Ligands

Thermo-responsive metallo-supramolecular gels based on terpyridine end-functionalized amphiphilic diblock copolymers

2013 ◽  
Vol 1499 ◽  
Author(s):  
Jérémy Brassinne ◽  
Charles-André Fustin ◽  
Jean-François Gohy
Keyword(s):  
Mechanical Properties ◽  
Diblock Copolymer ◽  
Self Assembly ◽  
Micellar Solution ◽  
Diblock Copolymers ◽  
Solution Temperature ◽  
Selective Solvent ◽  
Critical Solution Temperature ◽  
Terpyridine Ligands ◽  
Amphiphilic Diblock Copolymers

ABSTRACTA thermo-responsive hydrogel was prepared on the basis of terpyridine endfunctionalized polystyrene-block-poly(N-isopropylacrylamide) diblock copolymer. As a first level of assembly, the copolymer was dissolved in a selective solvent to yield micelles bearing terpyridine ligands at the extremity of the coronal chains. The second level of self-assembly was triggered upon addition of metal ions to the micellar solution. Mechanical properties of the accordingly obtained micellar gel were finally characterized by rotational rheometry, below and above the lower critical solution temperature.

Self-assembly and photo-responsive behavior of bis-terpyridyl Eu3+-complex L1

2019 ◽  
Vol 43 (48) ◽  
pp. 19355-19364
Author(s):  
Chuan Dong ◽  
Jin Yuan ◽  
Heinz Hoffmann ◽  
Jingcheng Hao
Keyword(s):  
Self Assembly ◽  
Terpyridine Ligands ◽  
Responsive Behavior

In the present paper, a bis-terpyridyl Eu3+ complex (bis-terpyridyl Eu3+-complex L1) was synthesized through the coordination between Eu3+ and a compound L1 with an azobenzene-functionalized chain between the two terpyridine ligands.

scholarly journals Designing narcissistic self-sorting terpyridine moieties with high coordination selectivity for complex metallo-supramolecules

2021 ◽  
Vol 4 (1) ◽  
Author(s):  
Jianjun Ma ◽  
Tong Lu ◽  
Xiaozheng Duan ◽  
Yaping Xu ◽  
Zhikai Li ◽  
...  
Keyword(s):  
Self Assembly ◽  
High Selectivity ◽  
Coordination Complexes ◽  
The Self ◽  
Face To Face ◽  
Powerful Approach ◽  
Terpyridine Ligands ◽  
High Coordination

AbstractCoordination-driven self-assembly is a powerful approach for the construction of metallosupramolecules, but designing coordination moieties that can drive the self-assembly with high selectivity and specificity remains a challenge. Here we report two ortho-modified terpyridine ligands that form head-to-tail coordination complexes with Zn(II). Both complexes show narcissistic self-sorting behaviour. In addition, starting from these ligands, we obtain two sterically congested multitopic ligands and use them to construct more complex metallo-supramolecules hexagons. Because of the non-coaxial structural restrictions in the rotation of terpyridine moieties, these hexagonal macrocycles can hierarchically self-assemble into giant cyclic nanostructures via edge-to-edge stacking, rather than face-to-face stacking. Our design of dissymmetrical coordination moieties from congested coordination pairs show remarkable self-assembly selectivity and specificity.

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