One-Pot, Room-Temperature Conversion of CO2 into Porous Metal–Organic Frameworks

2021 ◽  
Author(s):  
Kentaro Kadota ◽  
You-lee Hong ◽  
Yusuke Nishiyama ◽  
Easan Sivaniah ◽  
Daniel Packwood ◽  
...  
Keyword(s):  
Room Temperature ◽  
Metal Organic Frameworks ◽  
Porous Metal ◽  
One Pot ◽  
Metal Organic

Ultrafast room-temperature synthesis of hierarchically porous metal–organic frameworks with high space–time yields

CrystEngComm ◽  
2020 ◽  
Vol 22 (15) ◽  
pp. 2675-2680 ◽  
Author(s):  
Chongxiong Duan ◽  
Yi Yu ◽  
Feier Li ◽  
Ying Wu ◽  
Hongxia Xi
Keyword(s):  
Room Temperature ◽  
Metal Organic Frameworks ◽  
Porous Metal ◽  
Space Time ◽  
Ambient Conditions ◽  
Temperature Synthesis ◽  
Hierarchically Porous ◽  
Room Temperature Synthesis ◽  
Metal Organic ◽  
High Space

We developed a facile and general approach to rapidly synthesize four hierarchically porous MOFs (HKUST-1, ZIF-8, ZIF-61, and ZIF-90) under ambient conditions.

Porous metal–organic frameworks with Lewis basic nitrogen sites for high-capacity methane storage

2015 ◽  
Vol 8 (8) ◽  
pp. 2504-2511 ◽  
Author(s):  
Bin Li ◽  
Hui-Min Wen ◽  
Hailong Wang ◽  
Hui Wu ◽  
Taner Yildirim ◽  
...  
Keyword(s):  
Functional Groups ◽  
Room Temperature ◽  
Metal Organic Frameworks ◽  
High Capacity ◽  
Porous Metal ◽  
Methane Storage ◽  
Basic Nitrogen ◽  
Metal Organic

Incorporation of functional groups with Lewis basic nitrogen sites, including pyridine, pyridazine and pyrimidine groups, into NOTT-101 can remarkably improve both the total volumetric methane storage (at 65 bar and room temperature) and working capacities.

scholarly journals One-Pot, Room-Temperature Conversion of CO2 into Porous Metal−Organic Frameworks

2020 ◽  
Author(s):  
Kentaro Kadota ◽  
You-Lee Hong ◽  
Yusuke Nishiyama ◽  
Easan Sivaniah ◽  
Daniel Packwood ◽  
...  
Keyword(s):  
Atmospheric Pressure ◽  
Metal Organic Frameworks ◽  
Porous Metal ◽  
One Pot ◽  
Surface Areas ◽  
Piperazine Derivatives ◽  
Metal Organic ◽  
The One ◽  
Crystalline Metal ◽  
Highly Porous

We demonstrate the one-pot synthesis of highly porous crystalline metal−organic frameworks, [Zn<sub>4</sub>O(piperazine dicarbamate)<sub>3</sub>], an analogue of [Zn<sub>4</sub>O(1,4-benzenedicarboxylate)<sub>3</sub>] (MOF-5), directly from atmospheric pressure CO<sub>2</sub> gas and piperazine derivatives at 25 °C. The structures showed high CO<sub>2</sub> contents over 30 wt% and surface areas of 1270−2366 m<sup>2</sup> g<sup>−1</sup>. We also show that the synthesis is feasible even by the use of 400 ppm of CO<sub>2</sub>.

One-pot synthesis of nanoscale carbon dots-embedded metal–organic frameworks at room temperature for enhanced chemical sensing

2016 ◽  
Vol 4 (41) ◽  
pp. 15880-15887 ◽  
Author(s):  
Longhua Xu ◽  
Guozhen Fang ◽  
Jifeng Liu ◽  
Mingfei Pan ◽  
Ranran Wang ◽  
...  
Keyword(s):  
Carbon Dots ◽  
Chemical Sensing ◽  
Room Temperature ◽  
Metal Organic Frameworks ◽  
One Pot ◽  
Carbon Dot ◽  
One Pot Synthesis ◽  
Metal Organic

One-pot synthesis of nanoscale carbon dot-embedded metal–organic frameworks for enhanced chemical sensing.

scholarly journals Templated fabrication of hierarchically porous metal–organic frameworks and simulation of crystal growth

2019 ◽  
Vol 1 (3) ◽  
pp. 1062-1069 ◽  
Author(s):  
Chongxiong Duan ◽  
Hang Zhang ◽  
Minhui Yang ◽  
Feier Li ◽  
Yi Yu ◽  
...  
Keyword(s):  
Crystal Growth ◽  
Growth Mechanism ◽  
Room Temperature ◽  
Ambient Pressure ◽  
Metal Organic Frameworks ◽  
Porous Metal ◽  
Double Salt ◽  
Hierarchically Porous ◽  
Metal Organic

Hierarchically porous MOF materials were rapidly synthesized in a (Cu, Zn) hydroxy double salt (HDS) solution using a novel surfactant as template at room temperature and ambient pressure, and their growth mechanism was disclosed via mesodynamics (MesoDyn) simulation.

scholarly journals One-Pot, Room-Temperature Conversion of CO2 into Porous Metal−Organic Frameworks

2020 ◽  
Author(s):  
Kentaro Kadota ◽  
You-Lee Hong ◽  
Yusuke Nishiyama ◽  
Easan Sivaniah ◽  
Daniel Packwood ◽  
...  
Keyword(s):  
Atmospheric Pressure ◽  
Metal Organic Frameworks ◽  
Porous Metal ◽  
One Pot ◽  
Surface Areas ◽  
Piperazine Derivatives ◽  
Metal Organic ◽  
The One ◽  
Crystalline Metal ◽  
Highly Porous

We demonstrate the one-pot synthesis of highly porous crystalline metal−organic frameworks, [Zn<sub>4</sub>O(piperazine dicarbamate)<sub>3</sub>], an analogue of [Zn<sub>4</sub>O(1,4-benzenedicarboxylate)<sub>3</sub>] (MOF-5), directly from atmospheric pressure CO<sub>2</sub> gas and piperazine derivatives at 25 °C. The structures showed high CO<sub>2</sub> contents over 30 wt% and surface areas of 1270−2366 m<sup>2</sup> g<sup>−1</sup>. We also show that the synthesis is feasible even by the use of 400 ppm of CO<sub>2</sub>.

A Series of Metal-Organic Frameworks for Selective CO2 Capture and Catalytic Oxidative Carboxylation of Olefins

2018 ◽  
Author(s):  
Huong T. D. Nguyen ◽  
Y B. N. Tran ◽  
Hung N. Nguyen ◽  
Tranh C. Nguyen ◽  
Felipe Gándara ◽  
...  
Keyword(s):  
Room Temperature ◽  
Gas Adsorption ◽  
New Materials ◽  
One Pot ◽  
Acid Gas ◽  
Naphthalene Diimide ◽  
Styrene Carbonate ◽  
Metal Organic ◽  
Adsorption Of Co ◽  
The One

<p>Three novel lanthanide metal˗organic frameworks (Ln-MOFs), namely MOF-590, -591, and -592 were constructed from a naphthalene diimide tetracarboxylic acid. Gas adsorption measurements of MOF-591 and -592 revealed good adsorption of CO<sub>2</sub> (low pressure, at room temperature) and moderate CO<sub>2</sub> selectivity over N<sub>2</sub> and CH<sub>4</sub>. Accordingly, breakthrough measurements were performed on a representative MOF-592, in which the separation of CO<sub>2</sub> from binary mixture containing N<sub>2</sub> and CO<sub>2</sub> was demonstrated without any loss in performance over three consecutive cycles. Moreover, MOF-590, MOF-591, and MOF-592 exhibited catalytic activity in the one-pot synthesis of styrene carbonate from styrene and CO<sub>2</sub> under mild conditions (1 atm CO<sub>2</sub>, 80 °C, and solvent-free). Among the new materials, MOF-590 revealed a remarkable efficiency with exceptional conversion (96%), selectivity (95%), and yield (91%). </p><br>

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