scholarly journals Stereo-, Temporal and Chemical Control through Photoactivation of Living Radical Polymerization: Synthesis of Block and Gradient Copolymers

2015 ◽  
Vol 137 (31) ◽  
pp. 9988-9999 ◽  
Author(s):  
Sivaprakash Shanmugam ◽  
Cyrille Boyer
Keyword(s):  
Radical Polymerization ◽  
Chemical Control ◽  
Living Radical Polymerization ◽  
Gradient Copolymers

scholarly journals One-pot synthesis for gradient copolymers via concurrent tandem living radical polymerization: mild and selective transesterification of methyl acrylate through Al(acac)3 with common alcohols

RSC Advances ◽  
2021 ◽  
Vol 11 (42) ◽  
pp. 26049-26055
Author(s):  
Tam Thi-Thanh Huynh ◽  
Si Eun Kim ◽  
Soon Cheon Kim ◽  
Jin Chul Kim ◽  
Young Il Park ◽  
...  
Keyword(s):  
Radical Polymerization ◽  
Methyl Acrylate ◽  
Living Radical Polymerization ◽  
One Pot ◽  
Gradient Copolymers ◽  
One Pot Synthesis

The acrylate based gradient copolymers were successfully synthesized by concurrent tandem living radical polymerization using Al(acac)3 as cocatalyst with common alcohols.

scholarly journals Self-Assembly of Hydrogen-Bonding Gradient Copolymers: Sequence Control via Tandem Living Radical Polymerization with Transesterification

2017 ◽  
Vol 50 (8) ◽  
pp. 3215-3223 ◽  
Author(s):  
Yusuke Ogura ◽  
Müge Artar ◽  
Anja R. A. Palmans ◽  
Mitsuo Sawamoto ◽  
E. W. Meijer ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Radical Polymerization ◽  
Self Assembly ◽  
Living Radical Polymerization ◽  
Gradient Copolymers

Synthesis of fluorinated gradient copolymers via in situ transesterification with fluoroalcohols in tandem living radical polymerization

2017 ◽  
Vol 8 (15) ◽  
pp. 2299-2308 ◽  
Author(s):  
Yusuke Ogura ◽  
Takaya Terashima ◽  
Mitsuo Sawamoto
Keyword(s):  
Methyl Methacrylate ◽  
Radical Polymerization ◽  
Living Radical Polymerization ◽  
Titanium Alkoxide ◽  
Tandem Catalysis ◽  
In Situ Transesterification ◽  
Gradient Copolymers

Fluorinated gradient copolymers were synthesized by the tandem catalysis of ruthenium-catalyzed living radical polymerization and titanium alkoxide-mediated transesterification of methyl methacrylate (MMA) with fluoroalcohols.

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