Molecular Catalysis of the Electrochemical and Photochemical Reduction of CO2 with Earth-Abundant Metal Complexes. Selective Production of CO vs HCOOH by Switching of the Metal Center

2015 ◽  
Vol 137 (34) ◽  
pp. 10918-10921 ◽  
Author(s):  
Lingjing Chen ◽  
Zhenguo Guo ◽  
Xi-Guang Wei ◽  
Charlotte Gallenkamp ◽  
Julien Bonin ◽  
...  
Keyword(s):  
Metal Complexes ◽  
Metal Center ◽  
Photochemical Reduction ◽  
Earth Abundant ◽  
Molecular Catalysis ◽  
Reduction Of Co2

Electrons, Photons, Protons and Earth-Abundant Metal Complexes for Molecular Catalysis of CO2 Reduction

ACS Catalysis ◽  
2016 ◽  
Vol 7 (1) ◽  
pp. 70-88 ◽  
Author(s):  
Hiroyuki Takeda ◽  
Claudio Cometto ◽  
Osamu Ishitani ◽  
Marc Robert
Keyword(s):  
Metal Complexes ◽  
Co2 Reduction ◽  
Earth Abundant ◽  
Molecular Catalysis

High catalytic abilities of binuclear rhenium(i) complexes in the photochemical reduction of CO2 with a ruthenium(ii) photosensitiser

2016 ◽  
Vol 45 (37) ◽  
pp. 14668-14677 ◽  
Author(s):  
Yusuke Tamaki ◽  
Daisuke Imori ◽  
Tatsuki Morimoto ◽  
Kazuhide Koike ◽  
Osamu Ishitani
Keyword(s):  
Photochemical Reduction ◽  
Alkyl Chains ◽  
Diimine Ligands ◽  
Reduction Of Co2

Photocatalytic systems for CO2 reduction using a Ru(ii) photosensitiser and dinuclear Re(i) diimine tricarbonyl complexes (Re(n)Re), in which diimine ligands are connected by alkyl chains of various lengths (–CnH2n–: n = 2, 3, 4, 6, 14), as catalysts were investigated.

A convenient access to N-phosphonio-substituted NHC metal complexes [M = Ag(i), Rh(i), Pd(ii)]

2017 ◽  
Vol 46 (36) ◽  
pp. 12293-12305 ◽  
Author(s):  
Idir Benaissa ◽  
Rachid Taakili ◽  
Noël Lugan ◽  
Yves Canac
Keyword(s):  
Metal Complexes ◽  
Metal Center ◽  
Convenient Access

NHC Pd(ii) complexes featuring a propyl bridge were ionized by the introduction of a phosphonium moiety, which may coordinate to the metal center or remain pendant.

scholarly journals Photoredox Catalysis with Metal Complexes Made from Earth-Abundant Elements

2017 ◽  
Vol 24 (9) ◽  
pp. 2039-2058 ◽  
Author(s):  
Christopher B. Larsen ◽  
Oliver S. Wenger
Keyword(s):  
Metal Complexes ◽  
Photoredox Catalysis ◽  
Earth Abundant

A renewable amine for photochemical reduction of CO2

2011 ◽  
Vol 3 (4) ◽  
pp. 301-303 ◽  
Author(s):  
Robert D. Richardson ◽  
Edward J. Holland ◽  
Barry K. Carpenter
Keyword(s):  
Photochemical Reduction ◽  
Reduction Of Co2

scholarly journals Mechanisms of catalytic reduction of CO2 with heme and nonheme metal complexes

2018 ◽  
Vol 9 (28) ◽  
pp. 6017-6034 ◽  
Author(s):  
Shunichi Fukuzumi ◽  
Yong-Min Lee ◽  
Hyun S. Ahn ◽  
Wonwoo Nam
Keyword(s):  
Metal Complex ◽  
Metal Complexes ◽  
Critical Review ◽  
Catalytic Reduction ◽  
Electron Reduction ◽  
Reduction Of Co2 ◽  
Metal Complex Catalysts

This critical review discusses the thermal and photocatalytic mechanisms of one-, two-, four-, six- and eight-electron reduction of CO2 with metal complex catalysts.

Electrochemical and Photochemical Reduction of CO2 Catalyzed by Re(I) Complexes Carrying Local Proton Sources

2019 ◽  
Vol 38 (6) ◽  
pp. 1351-1360 ◽  
Author(s):  
Laura Rotundo ◽  
Claudio Garino ◽  
Emanuele Priola ◽  
Daniele Sassone ◽  
Heng Rao ◽  
...  
Keyword(s):  
Photochemical Reduction ◽  
Reduction Of Co2
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