High Methane Storage Working Capacity in Metal–Organic Frameworks with Acrylate Links

2016 ◽  
Vol 138 (32) ◽  
pp. 10244-10251 ◽  
Author(s):  
Juncong Jiang ◽  
Hiroyasu Furukawa ◽  
Yue-Biao Zhang ◽  
Omar M. Yaghi
Keyword(s):  
Metal Organic Frameworks ◽  
Methane Storage ◽  
Working Capacity ◽  
Metal Organic

scholarly journals Tailoring the pore geometry and chemistry in microporous metal–organic frameworks for high methane storage working capacity

2019 ◽  
Vol 55 (76) ◽  
pp. 11402-11405 ◽  
Author(s):  
Kai Shao ◽  
Jiyan Pei ◽  
Jia-Xin Wang ◽  
Yu Yang ◽  
Yuanjing Cui ◽  
...  
Keyword(s):  
Pore Size ◽  
Metal Organic Frameworks ◽  
Pore Geometry ◽  
Methane Storage ◽  
Working Capacity ◽  
Metal Organic

We realized that engineering the pore size/geometry and chemistry in a series of MOFs can optimize the volumetric methane storage working capacity.

Dynamic Spacer Installation for Multirole Metal–Organic Frameworks: A New Direction toward Multifunctional MOFs Achieving Ultrahigh Methane Storage Working Capacity

2017 ◽  
Vol 139 (17) ◽  
pp. 6034-6037 ◽  
Author(s):  
Cheng-Xia Chen ◽  
Zhang-Wen Wei ◽  
Ji-Jun Jiang ◽  
Shao-Ping Zheng ◽  
Hai-Ping Wang ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Methane Storage ◽  
Working Capacity ◽  
Metal Organic

scholarly journals Unravelling thermal stress due to thermal expansion mismatch in metal–organic frameworks for methane storage

2021 ◽  
Author(s):  
Jelle Wieme ◽  
Veronique Van Speybroeck
Keyword(s):  
Thermal Expansion ◽  
Thermal Stress ◽  
Pressure Coefficient ◽  
Metal Organic Frameworks ◽  
Methane Storage ◽  
Thermal Expansion Mismatch ◽  
Thermal Pressure ◽  
Temperature Changes ◽  
Metal Organic ◽  
The Impact

Thermal stress is present in metal–organic frameworks undergoing temperature changes during adsorption and desorption. We computed the thermal pressure coefficient as a proxy for this phenomenon and discuss the impact of thermal expansion mismatch.

Methane storage in flexible metal–organic frameworks with intrinsic thermal management

Nature ◽  
2015 ◽  
Vol 527 (7578) ◽  
pp. 357-361 ◽  
Author(s):  
Jarad A. Mason ◽  
Julia Oktawiec ◽  
Mercedes K. Taylor ◽  
Matthew R. Hudson ◽  
Julien Rodriguez ◽  
...  
Keyword(s):  
Thermal Management ◽  
Metal Organic Frameworks ◽  
Methane Storage ◽  
Metal Organic ◽  
Flexible Metal

Metal−Organic Frameworks for Methane Storage

2015 ◽  
pp. 173-191 ◽  
Author(s):  
Xuan Wang ◽  
Stephen Fordham ◽  
Hong-Cai Zhou
Keyword(s):  
Metal Organic Frameworks ◽  
Methane Storage ◽  
Metal Organic

A metal–organic framework functionalized with piperazine exhibiting enhanced CH4 storage

2017 ◽  
Vol 5 (1) ◽  
pp. 349-354 ◽  
Author(s):  
Mingxing Zhang ◽  
Cong Chen ◽  
Qian Wang ◽  
Wensheng Fu ◽  
Kunlin Huang ◽  
...  
Keyword(s):  
Room Temperature ◽  
Storage Capacity ◽  
Metal Organic Framework ◽  
Methane Storage ◽  
Working Capacity ◽  
Metal Organic ◽  
Organic Framework ◽  
Ch4 Storage

NJU-Bai 19, the first cycloaliphatic ring (piperazine) functionalized MOF-505 analogue, exhibits a notably high methane storage capacity of 246 cm3 (STP) cm−3 (at room temperature and 65 bar) and a working capacity of 185 cm3 (STP) cm−3.

scholarly journals Implementing Metal-Organic Frameworks for Natural Gas Storage

Crystals ◽  
2019 ◽  
Vol 9 (8) ◽  
pp. 406 ◽  
Author(s):  
Eyas Mahmoud ◽  
Labeeb Ali ◽  
Asmaa El Sayah ◽  
Sara Awni Alkhatib ◽  
Hend Abdulsalam ◽  
...  
Keyword(s):  
Natural Gas ◽  
Thermal Management ◽  
Active Sites ◽  
Storage Capacity ◽  
Metal Organic Frameworks ◽  
Department Of Energy ◽  
Working Capacity ◽  
Adsorbed Natural Gas ◽  
Metal Organic ◽  
Temperature And Pressure

Methane can be stored by metal-organic frameworks (MOFs). However, there remain challenges in the implementation of MOFs for adsorbed natural gas (ANG) systems. These challenges include thermal management, storage capacity losses due to MOF packing and densification, and natural gas impurities. In this review, we discuss discoveries about how MOFs can be designed to address these three challenges. For example, Fe(bdp) (bdp2− = 1,4-benzenedipyrazolate) was discovered to have intrinsic thermal management and released 41% less heat than HKUST-1 (HKUST = Hong Kong University of Science and Technology) during adsorption. Monolithic HKUST-1 was discovered to have a working capacity 259 cm3 (STP) cm−3 (STP = standard temperature and pressure equivalent volume of methane per volume of the adsorbent material: T = 273.15 K, P = 101.325 kPa), which is a 50% improvement over any other previously reported experimental value and virtually matches the 2012 Department of Energy (Department of Energy = DOE) target of 263 cm3 (STP) cm−3 after successful packing and densification. In the case of natural gas impurities, higher hydrocarbons and other molecules may poison or block active sites in MOFs, resulting in up to a 50% reduction of the deliverable energy. This reduction can be mitigated by pore engineering.

Engineering of Pore Geometry for Ultrahigh Capacity Methane Storage in Mesoporous Metal–Organic Frameworks

2017 ◽  
Vol 139 (38) ◽  
pp. 13300-13303 ◽  
Author(s):  
Cong-Cong Liang ◽  
Zhao-Lin Shi ◽  
Chun-Ting He ◽  
Jing Tan ◽  
Hu-Die Zhou ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Pore Geometry ◽  
Methane Storage ◽  
Metal Organic ◽  
Mesoporous Metal

High-Capacity Methane Storage in Metal−Organic Frameworks M2(dhtp): The Important Role of Open Metal Sites

2009 ◽  
Vol 131 (13) ◽  
pp. 4995-5000 ◽  
Author(s):  
Hui Wu ◽  
Wei Zhou ◽  
Taner Yildirim
Keyword(s):  
Metal Organic Frameworks ◽  
High Capacity ◽  
Methane Storage ◽  
Open Metal Sites ◽  
Metal Organic
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