scholarly journals Roles of Iron Complexes in Catalytic Radical Alkene Cross-Coupling: A Computational and Mechanistic Study

2019 ◽  
Vol 141 (18) ◽  
pp. 7473-7485 ◽  
Author(s):  
Dongyoung Kim ◽  
S. M. Wahidur Rahaman ◽  
Brandon Q. Mercado ◽  
Rinaldo Poli ◽  
Patrick L. Holland
Keyword(s):  
Cross Coupling ◽  
Iron Complexes ◽  
Mechanistic Study

Evidence for “cocktail”-type catalysis in Buchwald–Hartwig reaction. A mechanistic study

2021 ◽  
Author(s):  
Darya O. Prima ◽  
Malena Madiyeva ◽  
Julia V. Burykina ◽  
Mikhail E. Minyaev ◽  
Daniil A. Boiko ◽  
...  
Keyword(s):  
Type System ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Mechanistic Study ◽  
Cross Coupling Reaction

The mechanism of the C–N cross-coupling reaction, catalyzed by Pd/NHC, was evaluated at the molecular and nanoscale levels. The first evidence for the involvement of a “cocktail”-type system in the Buchwald–Hartwig reaction is provided.

Mechanistic study on the cross-coupling of alkynyl stannanes with aryl iodides catalyzed by η2-(dimethyl fumarate)palladium(0) complexes with iminophosphine ligands

2003 ◽  
pp. 2194-2202 ◽  
Author(s):  
Bruno Crociani ◽  
Simonetta Antonaroli ◽  
Valentina Beghetto ◽  
Ugo Matteoli ◽  
Alberto Scrivanti
Keyword(s):  
Cross Coupling ◽  
Dimethyl Fumarate ◽  
Mechanistic Study ◽  
Aryl Iodides ◽  
The Cross

scholarly journals A mechanistic investigation of the photoinduced, copper-mediated cross-coupling of an aryl thiol with an aryl halide

2016 ◽  
Vol 7 (7) ◽  
pp. 4091-4100 ◽  
Author(s):  
Miles W. Johnson ◽  
Kareem I. Hannoun ◽  
Yichen Tan ◽  
Gregory C. Fu ◽  
Jonas C. Peters
Keyword(s):  
Electron Transfer ◽  
Aryl Halide ◽  
Cross Coupling ◽  
Single Electron ◽  
Mechanistic Study ◽  
Single Electron Transfer ◽  
Radical Recombination ◽  
Mechanistic Investigation

A mechanistic study establishes the viability of a copper-mediated pathway for photoinduced C–S cross-coupling involving single electron transfer and in-cage radical recombination.

Mechanistic Study of Indolizine Heterocycle Formation by Ruthenium(II)-Assisted Three-Component Cross-Coupling/Cyclization

2013 ◽  
Vol 32 (13) ◽  
pp. 3738-3743 ◽  
Author(s):  
Chunhong Zhang ◽  
Hong Zhang ◽  
Laiying Zhang ◽  
Ting Bin Wen ◽  
Xumin He ◽  
...  
Keyword(s):  
Cross Coupling ◽  
Mechanistic Study

scholarly journals A mechanistic study of cross-coupling reactions catalyzed by palladium nanoparticles supported on polyaniline nanofibers

2015 ◽  
Vol 2 (1) ◽  
pp. 35-41 ◽  
Author(s):  
William M. Lemke ◽  
Richard B. Kaner ◽  
Paula L. Diaconescu
Keyword(s):  
Palladium Nanoparticles ◽  
Cross Coupling ◽  
Mechanistic Study ◽  
Coupling Reactions ◽  
Polyaniline Nanofibers ◽  
Cross Coupling Reactions ◽  
Homogeneous Mechanism

Pd/PANI nanocomposites effect C–C coupling reactions mainly through a homogeneous mechanism.

Theoretical mechanistic study of metallaphotoredox catalysis: C–N cross-coupling via Ni(ii)-mediated σ-bond metathesis

2020 ◽  
Vol 7 (16) ◽  
pp. 2168-2178 ◽  
Author(s):  
Run-Han Li ◽  
Bo Zhu ◽  
Shuang Wang ◽  
Yun Geng ◽  
Li-Kai Yan ◽  
...  
Keyword(s):  
Cross Coupling ◽  
Mechanistic Study ◽  
Radical Mechanism

A radical mechanism merging *IrIII reductive quenching and NiII-mediated σ-bond metathesis has been proposed for metallaphotoredox catalyzed C–N cross-coupling.

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