Isopiestic determination of the osmotic and activity coefficients of aqueous magnesium chloride solutions at 25 .degree.C

1981 ◽  
Vol 26 (1) ◽  
pp. 38-43 ◽  
Author(s):  
Joseph A. Rard ◽  
Donald G. Miller
Keyword(s):  
Activity Coefficients ◽  
Magnesium Chloride ◽  
Chloride Solutions

NaCl and CaCl2 activity coefficients in mixed aqueous solutions

1965 ◽  
Vol 20 (6) ◽  
pp. 1332-1336 ◽  
Author(s):  
Edward W. Moore ◽  
James W. Ross
Keyword(s):  
Ionic Strength ◽  
Activity Coefficients ◽  
Technical Assistance ◽  
Osmotic Coefficients ◽  
Electrode System ◽  
Glass Electrode ◽  
Concentration Data ◽  
Harned's Rule ◽  
Potentiometric Measurement

In the investigation of numerous physiological phenomena it is the activity of an ion species which is desired, rather than stoichiometric concentration. The calculation of mean ionic activity from known concentration data requires accurate activity coefficients (ggr). This report concerns the determination of ggrNaCl and ggrCaCl2 in mixed NaCl-CaCl2 solutions by potentiometric measurement with a sodium-selective glass electrode-Ag/AgCl electrode system over the ionic strength range 0.05–0.5 m. Log ggrNaCl varied linearly, at constant total ionic strength, with the ionic strength of CaCl2 in the mixture, in accordance with Harned's rule. From data thus obtained, ggrCaCl2 coefficients in such mixed solutions have been calculated and compared with values calculated from published osmotic data. Resulting activity coefficient curves for ggrCaCl2 are presented over the concentration range encountered in serum and other extracellular fluids. Note: (With the Technical Assistance of Leonard Kaye and Leonard L. Anderson) glass electrodes; ion interaction; electrolyte metabolism; Harned's rule; membrane transport; osmotic coefficients Submitted on March 11, 1965

scholarly journals Obtaining artificial carnallites from magnesium chloride brines

2020 ◽  
Vol 56 (2) ◽  
pp. 229-234
Author(s):  
V. V. Shevchuk ◽  
T. N. Potkina ◽  
A. I. Vaitenka ◽  
O. V. Smetanina
Keyword(s):  
Calcium Chloride ◽  
Magnesium Chloride ◽  
Calcium Sulfate ◽  
Raw Materials ◽  
Potassium Sulfate ◽  
Sulfate Ions ◽  
Chloride Solutions ◽  
Excess Concentration ◽  
Almost All ◽  
Complete Precipitation

The excess of magnesium chloride brines is formed during the polymineral ores processing in order to obtain potassium sulfate. One way to regenerate such brines is to produce artificial carnallite. It is necessary to purify these brines from sulfates for their further use as raw materials for the artificial carnallite production. In this work, the process of desulfurization of magnesium chloride brines with a solution of calcium chloride is studied. The temperature and the processing time, the magnesium chloride solutions concentration and the consumption of desulfurizing agent (calcium chloride) influence on the degree of magnesium chloride solutions purification from sulfate ions was determined. It has been established that almost all sulfate ions interact with calcium ion in 15 minutes and the desulfurization degree reaches 98,08 %. The increase in duration of the suspension mixing is necessary in order to establish equilibrium in the system and relieve the supersaturation in the solution. It has been shown that with increasing solutions saturation with MgCl2, the degree of the magnesium chloride brines purification from SO4 2– ion increases. Complete precipitation of calcium sulfate requires a certain excess concentration of calcium chloride.

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