Isobaric vapor-liquid equilibria for the ternary system acetone-ethyl acetate-ethanol

1984 ◽  
Vol 29 (4) ◽  
pp. 463-466 ◽  
Author(s):  
Renzo Carta ◽  
Stella Dernini ◽  
Paolo Sanna
2013 ◽  
Vol 791-793 ◽  
pp. 141-144
Author(s):  
Xiu Min Shi ◽  
Min Wang

In order to research the possibility of separating the azeotrope of ethyl acetate + acetonitrile with ionic liquid as the extractant. Isobaric vapor-liquid equilibria for the ternary system ethyl acetate + acetonitrile + 1-octyl-3-methylimidazolium tetrafluoroborate ([OMIBF4) were measured at 101.32 kPa using a recirculation still. The results showed that the VLE of the ternary system was different from that of the binary system. The ionic liquid (IL) studied showed a slight crossover salt effect, which changed the relative volatility of ethyl acetate to acetonitrile and eliminated the azeotropic point when the mole fraction of IL in the liquid phase was greater than 0.05. Therefore, [OMIBF4 can be used as the extractant of extractive distillation for ethyl acetate + acetonitrile system, the suitable mole fraction of [OMIBF4 is about 10%.


1967 ◽  
Vol 12 (3) ◽  
pp. 440-442 ◽  
Author(s):  
Koichiro Nakanishi ◽  
Koichi Nakasato ◽  
Ritsuji Toba ◽  
Hideko Shirai

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