Free radical oxidations in water: decomposition of azo initiators and oxidation of p-cresol and p-isopropylphenol

1983 ◽  
Vol 48 (13) ◽  
pp. 2133-2138 ◽  
Author(s):  
Andrew Pohlman ◽  
Theodore Mill
Keyword(s):  
Free Radical ◽  
Water Decomposition ◽  
Azo Initiators

Free-radical crosslinking copolymerization of 2,2?-azobis[N-(2-propenyl)-2-methylpropionamide] with vinyl benzoate resulting in polymeric azo initiators

2002 ◽  
Vol 40 (3) ◽  
pp. 317-325 ◽  
Author(s):  
Akira Matsumoto ◽  
Yoshikatsu Ichiryu ◽  
Hiroyuki Aota ◽  
Kazuo Shiraki ◽  
Tsutomu Iwata
Keyword(s):  
Free Radical ◽  
Azo Initiators

A facile, green, and tunable method to functionalize carbon nanotubes with water-soluble azo initiators by one-step free radical addition

2010 ◽  
Vol 256 (10) ◽  
pp. 3286-3292 ◽  
Author(s):  
Yingkui Yang ◽  
Shengqiang Qiu ◽  
Xiaolin Xie ◽  
Xianbao Wang ◽  
Robert Kwok Yiu Li
Keyword(s):  
Carbon Nanotubes ◽  
Free Radical ◽  
Radical Addition ◽  
Water Soluble ◽  
One Step ◽  
Azo Initiators ◽  
Free Radical Addition

Potentiation of bromotrichloromethane hepatotoxicity in male rats exposed to 10 ppm dietary chlordecone: Electron Microscopic and biochemical study

1990 ◽  
Vol 48 (3) ◽  
pp. 284-285
Author(s):  
O. M. Faroon ◽  
R. W. Henry ◽  
M. G. Soni ◽  
H. M. Mehendale
Keyword(s):  
Free Radical ◽  
Biochemical Study ◽  
Prior Exposure ◽  
Male Rats ◽  
Cellular Injury ◽  
Low Doses ◽  
Mixed Function Oxidase ◽  
Electron Microscopic ◽  
Potent Inducer ◽  
Cellular Energy

Previous work has shown that mirex undergoes photolytic dechlorination to chlordecone (CD) (KeponeR) in the environment. Much work has shown that prior exposure to nontoxic levels of CD causes potentiation of hepatotoxicity and lethality of CCl4, BrCCl3 and other halomethane compounds. Potentiation of bromotrichloromethane hepatotoxicity has been associated with compounds that stimulate the activity of hepatic mixed-function oxidase (MFO). An increase in the metabolism of halomethane by the MFO to a free radical initiates peroxidative decomposition of membranal lipids ending in massive cellular injury. However, not all MFO inducers potentiate BrCCl3 hepatotoxicity. Potentiation by much larger doses of phenobarbital is minimal and th at by a more potent inducer of MFO, mirex, is negligible at low doses. We suggest that the CD and bromotrichloromethane interaction results in a depletion of cellular energy and thereby reducing the cellular ability to undergo mitosis.

Deaminative carbonylative thioesterification of activated alkylamines with thiophenols under transition-metal-free conditions

2021 ◽  
Author(s):  
Fengqian Zhao ◽  
Xiao-Feng Wu
Keyword(s):  
Free Radical ◽  
Transition Metal ◽  
Metal Free

A transition-metal-free radical carbonylation of activated alkylamines with thiophenols has been successfully developed. Various thioesters were selectively produced with moderate to good yields.

1120: Citrate and Vitamin E Blunt the SWL-Induced Free Radical Surge in an In-Vitro MDCK Cell Culture Model

2004 ◽  
Vol 171 (4S) ◽  
pp. 295-295
Author(s):  
Fernando C. Delvecchio ◽  
Ricardo M. Brizuela ◽  
Karen J. Byer ◽  
W. Patrick Springhart ◽  
Saeed R. Khan ◽  
...  
Keyword(s):  
Cell Culture ◽  
Free Radical ◽  
Vitamin E ◽  
Mdck Cell ◽  
Cell Culture Model ◽  
Culture Model

Prognostic significance of serum free radical level in head injury

2005 ◽  
Vol 2 (2) ◽  
pp. 107-109
Author(s):  
A. Mishra ◽  
M.F. Huda ◽  
V.P. Singh ◽  
S. Mohanty ◽  
A. Sodhi
Keyword(s):  
Free Radical ◽  
Head Injury ◽  
Prognostic Significance ◽  
Serum Free
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