Di-tert-butyl peroxide: can its photolysis be quenched by carbon tetrachloride and why is it stable at room temperature?

1984 ◽  
Vol 49 (18) ◽  
pp. 3415-3416 ◽  
Author(s):  
S. A. Davis ◽  
B. C. Gilbert ◽  
D. Griller ◽  
A. S. Nazran
Keyword(s):  
Carbon Tetrachloride ◽  
Room Temperature ◽  
Tert Butyl ◽  
Butyl Peroxide

ChemInform Abstract: DI-TERT-BUTYL PEROXIDE: CAN ITS PHOTOLYSIS BE QUENCHED BY CARBON TETRACHLORIDE AND WHY IS IT STABLE AT ROOM TEMPERATURE?

1985 ◽  
Vol 16 (9) ◽  
Author(s):  
S. A. DAVIS ◽  
B. C. GILBERT ◽  
D. GRILLER ◽  
A. S. NAZRAN
Keyword(s):  
Carbon Tetrachloride ◽  
Room Temperature ◽  
Tert Butyl ◽  
Butyl Peroxide

ChemInform Abstract: REACTION OF TERT-BUTYL PEROXIDE AND TERT-BUTYLPEROXYTRIMETHYLSILANE WITH TRIBUTYLBORON IN CARBON TETRACHLORIDE

1979 ◽  
Vol 10 (18) ◽  
Author(s):  
G. A. RAZUVAEV ◽  
M. A. LOPATIN ◽  
V. A. DODONOV
Keyword(s):  
Carbon Tetrachloride ◽  
Tert Butyl ◽  
Butyl Peroxide

Photolysis of Di-tert-butyl Peroxide in Solution

1974 ◽  
Vol 52 (13) ◽  
pp. 2491-2492 ◽  
Author(s):  
Eduardo Lissi
Keyword(s):  
Carbon Tetrachloride ◽  
Quantum Yield ◽  
Gas Phase ◽  
Hydrocarbon Concentration ◽  
Tert Butyl ◽  
Carbon Tetrachloride Solution ◽  
Butyl Peroxide ◽  
Peroxide Molecule

Di-tert-butyl peroxide has been photolyzed at 3130 Å in carbon tetrachloride solution in the presence of cyclohexane. The quantum yield of free tert-butoxy radicals was 1.9 ± 0.1, independent of the hydrocarbon concentration. Unlike results obtained in the gas phase at 2537 Å, no evidence for the quenching of the excited peroxide molecule could be detected.

Iron-Catalyzed Carboiodination of Alkynes

Synthesis ◽  
2018 ◽  
Vol 50 (15) ◽  
pp. 2974-2980 ◽  
Author(s):  
You-Gui Li ◽  
Hongli Bao ◽  
Weili Deng ◽  
Yajun Li
Keyword(s):  
Room Temperature ◽  
Cyano Group ◽  
Alkyl Chains ◽  
Radical Initiator ◽  
Tert Butyl ◽  
Butyl Peroxide ◽  
Alkyl Iodides ◽  
Vinyl Iodides ◽  
Fluoroalkyl Group

An iron-catalyzed carboiodination of alkynes with alkyl iodides­ at room temperature was developed. This method could provide synthetically useful vinyl iodides with general alkyl chains, fluoroalkyl group, ester, and cyano group. Conjugated alkynes or unconjugated alkynes were both suitable for this transformation. A radical pathway was proposed for the mechanism and acetyl tert-butyl peroxide was selected as the radical initiator. Alkenes could also be applied to this chemistry and produce more complex alkyl iodides.

Fundamental Thermal Hazard Investigation for Tert-Butyl Peroxide Reactor Using DSC and TGA Techniques

2011 ◽  
Vol 21 (1) ◽  
pp. 53-63 ◽  
Author(s):  
Chien-Jung Chen ◽  
Jen-Hao Chi ◽  
Sheng-Hung Wu ◽  
Cheng-Tung Chen ◽  
Hsiu-Fen Tsai
Keyword(s):  
Thermal Hazard ◽  
Tert Butyl ◽  
Butyl Peroxide

Energy partitioning on photolysis of di-tert-butyl peroxide

1971 ◽  
Vol 75 (24) ◽  
pp. 3651-3655 ◽  
Author(s):  
F. H. Dorer ◽  
S. N. Johnson
Keyword(s):  
Energy Partitioning ◽  
Tert Butyl ◽  
Butyl Peroxide

Room-Temperature, Water-Promoted, Radical-Coupling Reactions of Phenols with tert-Butyl Nitrite

Synlett ◽  
2017 ◽  
Vol 28 (16) ◽  
pp. 2153-2156 ◽  
Author(s):  
Wen-Ting Wei ◽  
Hongze Liang ◽  
Wen-Ming Zhu ◽  
Weida Liang ◽  
Yi Wu ◽  
...  
Keyword(s):  
Room Temperature ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Phenol Derivative ◽  
Tert Butyl ◽  
Radical Coupling ◽  
Air Atmosphere ◽  
Cross Coupling Reaction ◽  
Temperature Water

A radical–radical cross-coupling reaction of phenols with tert-butyl nitrite has been developed with the use of water as an additive. This method allows the construction of C–N bonds under an air atmosphere at room temperature, providing the ortho-nitrated phenol derivative in moderate to good yields.

ChemInform Abstract: MANUFACTURE OF DIMETHYL(VINYLETHYNYL)METHYL TERT-BUTYL PEROXIDE

1979 ◽  
Vol 10 (48) ◽  
Author(s):  
M. R. VILENSKAYA ◽  
D. S. KARAMOV ◽  
E. I. SOROKIN ◽  
G. A. PETROVSKAYA ◽  
V. A. PUCHIN
Keyword(s):  
Tert Butyl ◽  
Butyl Peroxide

Influence of nitrobenzene on the reactivity of certain aroxyl radicals in the reaction with di-tert-butyl peroxide and on the EPR spectra of these radicals

1969 ◽  
Vol 18 (8) ◽  
pp. 1543-1547
Author(s):  
A. I. Prokof'ev ◽  
S. P. Solodovnikov ◽  
N. N. Bubnov ◽  
N. G. Radzhabov
Keyword(s):  
Epr Spectra ◽  
Tert Butyl ◽  
Butyl Peroxide
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