Charge-Site Effects on the Radical Reactivity of Distonic Ions†

2002 ◽  
Vol 106 (42) ◽  
pp. 9767-9775 ◽  
Author(s):  
Christopher J. Petzold ◽  
Eric D. Nelson ◽  
Harvey A. Lardin ◽  
Hilkka I. Kenttämaa
2021 ◽  
Vol 12 (13) ◽  
pp. 4800-4809
Author(s):  
Totan Mondal ◽  
Sason Shaik ◽  
Hilkka Kenttämaa ◽  
Thijs Stuyver

This manuscript reports the electrostatic nature of the modulation of H-abstraction reactivity of phenyl radicals by (positive and negative) distonic ions.


2020 ◽  
Vol 24 ◽  
Author(s):  
Wengui Wang ◽  
Shoufeng Wang

Abstract:: Minisci-type reactions have become widely known as reactions that involve the addition of carbon-centered radicals to basic heteroarenes followed by formal hydrogen atom loss. While the originally developed protocols for radical generation remain in active use today, in recent years by a new array of radical generation strategies allow use of a wider variety of radical precursors that often operate under milder and more benign conditions. New transformations based on free radical reactivity are now available to a synthetic chemist looking to utilize a Minisci-type reaction. Radical-generation methods based on photoredox catalysis and electrochemistry, which utilize thermal cleavage or the in situ generation of reactive radical precursors, have become popular approaches. Our review will cover the remarkably literature that has appeared on this topic in recent 5 years, from 2015-01 to 2020-01, in an attempt to provide guidance to the synthetic chemist, on both the challenges that have been overcome and applications in organic synthesis.


2021 ◽  
pp. 875529302110194
Author(s):  
Daniel Verret ◽  
Denis LeBœuf ◽  
Éric Péloquin

Eastern North America (ENA) is part of a region with low-to-moderate seismicity; nonetheless, some significant seismic events have occurred in the last few decades. Recent events have reemphasized the need to review ENA seismicity and ground motion models, along with continually reevaluating and updating procedures related to the seismic safety assessment of hydroelectric infrastructures, particularly large dams in Québec. Furthermore, recent researchers have shown that site-specific characteristics, topography, and valley shapes may significantly aggravate the severity of ground motions. To the best of our knowledge, very few instrumental data from actual earthquakes have been published for examining the site effects of hydroelectric dam structures located in eastern Canada. This article presents an analysis of three small earthquakes that occurred in 1999 and 2002 at the Denis-Perron (SM-3) dam. This dam, the highest in Québec, is a rockfill embankment structure with a height of 171 m and a length of 378 m; it is located in a narrow valley. The ground motion datasets of these earthquakes include the bedrock and dam crest three-component accelerometer recordings. Ground motions are analyzed both in the time and frequency domains. The spectral ratios and transfer functions obtained from these small earthquakes provide new insights into the directionality of resonant frequencies, vibration modes, and site effects for the Denis-Perron dam. The crest amplifications observed for this dam are also compared with previously published data for large dams. New statistical relationships are proposed to establish dam crest amplification on the basis of the peak ground acceleration (PGA) at the foundation.


ChemBioChem ◽  
2020 ◽  
Author(s):  
Brandon Wilbanks ◽  
Brian Garcia ◽  
Shane Byrne ◽  
Peter Dedon ◽  
Louis Maher

1979 ◽  
Vol 254 (20) ◽  
pp. 10206-10212
Author(s):  
G.F. Azzone ◽  
T. Pozzan ◽  
F. Di Virgilio

Author(s):  
Emily Mulvany ◽  
Sara McMahan ◽  
Jiazhu Xu ◽  
Narges Yazdani ◽  
Rebecca Willits ◽  
...  

2021 ◽  
Vol 127 ◽  
pp. 107794
Author(s):  
Vinicius Costa Cysneiros ◽  
Fernanda Coelho de Souza ◽  
Tatiana Dias Gaui ◽  
Allan Libanio Pelissari ◽  
Gabriel Agostini Orso ◽  
...  

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