Vibronic Participation of the Bridging Ligand in Electron Transfer and Delocalization:  New Application of a Three-State Model in Pyrazine-Bridged Mixed-Valence Complexes of Trinuclear Ruthenium Clusters

2003 ◽  
Vol 107 (44) ◽  
pp. 9301-9311 ◽  
Author(s):  
Casey H. Londergan ◽  
Clifford P. Kubiak
Keyword(s):  
Electron Transfer ◽  
Mixed Valence ◽  
State Model ◽  
Ruthenium Clusters ◽  
Bridging Ligand ◽  
Three State Model

Three-State Model for Two-Electron Transfer Reactions

1997 ◽  
Vol 101 (22) ◽  
pp. 4136-4141 ◽  
Author(s):  
Leonid D. Zusman ◽  
David N. Beratan
Keyword(s):  
Electron Transfer ◽  
State Model ◽  
Transfer Reactions ◽  
Electron Transfer Reactions ◽  
Three State Model

On the performance of the Kohn–Sham orbital approach in the calculation of electron transfer parameters. The three state model

2014 ◽  
Vol 16 (32) ◽  
pp. 17154-17162 ◽  
Author(s):  
C. Butchosa ◽  
S. Simon ◽  
L. Blancafort ◽  
A. A. Voityuk
Keyword(s):  
Electron Transfer ◽  
State Model ◽  
Transfer Parameters ◽  
Three State Model

The electron transfer parameters for the 3-state G⋯Ind system can be obtained using an efficient Kohn–Sham orbital based scheme.

Intramolecular Electron Transfer Mediated by a Tetrathiafulvalene Bridge in a Purely Organic Mixed-Valence System

2003 ◽  
Vol 42 (24) ◽  
pp. 2765-2768 ◽  
Author(s):  
Nicolas Gautier ◽  
Frédéric Dumur ◽  
Vega Lloveras ◽  
José Vidal-Gancedo ◽  
Jaume Veciana ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Mixed Valence ◽  
Intramolecular Electron Transfer

scholarly journals Pronounced effects of grinding on rates of intramolecular electron transfer in mixed-valence 1′,2′,1‴,2‴-tetranaphthylmethyl- and 1′,3′,1‴,3‴-tetranaphthylmethyl-biferrocenium triiodides

2003 ◽  
Vol 679 (2) ◽  
pp. 181-193 ◽  
Author(s):  
Teng-Yuan Dong ◽  
Mei-Ching Lin ◽  
Liangshiu Lee ◽  
Ching-Hung Cheng ◽  
Shie-Ming Peng ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Mixed Valence ◽  
Intramolecular Electron Transfer

scholarly journals Three state model of actin-tropomyosin complex

2000 ◽  
Vol 40 (supplement) ◽  
pp. S139
Author(s):  
K-I. Sano ◽  
K. Maeda ◽  
Y. Maeda
Keyword(s):  
State Model ◽  
Three State Model

scholarly journals Blocker-related changes of channel density. Analysis of a three-state model for apical Na channels of frog skin.

1990 ◽  
Vol 95 (4) ◽  
pp. 647-678 ◽  
Author(s):  
S I Helman ◽  
L M Baxendale
Keyword(s):  
Frog Skin ◽  
Noise Analysis ◽  
Kinetic Scheme ◽  
State Model ◽  
Na Channel ◽  
Na Channels ◽  
Na Transport ◽  
Open Probability ◽  
Wide Range ◽  
Three State Model

Blocker-induced noise analysis of apical membrane Na channels of epithelia of frog skin was carried out with the electroneutral blocker (CDPC, 6-chloro-3,5-diamino-pyrazine-2-carboxamide) that permitted determination of the changes of single-channel Na currents and channel densities with minimal inhibition of the macroscopic rates of Na transport (Baxendale, L. M., and S. I. Helman. 1986. Biophys. J. 49:160a). Experiments were designed to resolve changes of channel densities due to mass law action (and hence the kinetic scheme of blocker interaction with the Na channel) and to autoregulation of Na channel densities that occur as a consequence of inhibition of Na transport. Mass law action changes of channel densities conformed to a kinetic scheme of closed, open, and blocked states where blocker interacts predominantly if not solely with open channels. Such behavior was best observed in "pulse" protocol experiments that minimized the time of exposure to blocker and thus minimized the contribution of much longer time constant autoregulatory influences on channel densities. Analysis of data derived from pulse, staircase, and other experimental protocols using both CDPC and amiloride as noise-inducing blockers and interpreted within the context of a three-state model revealed that Na channel open probability in the absence of blocker averaged near 0.5 with a wide range among tissues between 0.1 and 0.9.

Worklife and Unemployment: A New Consideration

2021 ◽  
Author(s):  
David I. Rosenbaum ◽  
Kalana Jayanetti
Keyword(s):  
Initial Data ◽  
State Model ◽  
Inactive State ◽  
Three State Model ◽  
Good Proxy ◽  
Two State Model

Abstract Do traditional two-state worklife estimates need adjustment for unemployment? To answer, an augmented three-state model classifies individuals as either 1) employed; 2) unemployed; or 3) inactive but not marginally attached. Periods of unemployment may reduce worklives; however, removal of those marginally attached or discouraged from the inactive state raises worklives. The three-state model results are compared to worklife estimates from the same initial data using the traditional two-state model. Results show that in many cases, the two-state model results are a good proxy for the three-state results that control for unemployment.

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