Atmospheric Chemistry of CF3OCF2CF2H and CF3OC(CF3)2H:  Reaction with Cl Atoms and OH Radicals, Degradation Mechanism, Global Warming Potentials, and Empirical Relationship betweenk(OH) andk(Cl) for Organic Compounds

2005 ◽  
Vol 109 (17) ◽  
pp. 3926-3934 ◽  
Author(s):  
M. P. Sulbaek Andersen ◽  
O. J. Nielsen ◽  
T. J. Wallington ◽  
M. D. Hurley ◽  
W. B. DeMore
Keyword(s):  
Global Warming ◽  
Organic Compounds ◽  
Atmospheric Chemistry ◽  
Degradation Mechanism ◽  
Empirical Relationship ◽  
Oh Radicals ◽  
Global Warming Potentials ◽  
Cl Atoms

Atmospheric chemistry of (CF3)2CCH2: OH radicals, Cl atoms and O3 rate coefficients, oxidation end-products and IR spectra

2015 ◽  
Vol 17 (38) ◽  
pp. 25607-25620 ◽  
Author(s):  
Vassileios C. Papadimitriou ◽  
Christina S. Spitieri ◽  
Panos Papagiannakopoulos ◽  
Mathieu Cazaunau ◽  
Maria Lendar ◽  
...  
Keyword(s):  
Global Warming ◽  
Ir Spectra ◽  
Atmospheric Chemistry ◽  
Rate Coefficients ◽  
Oh Radicals ◽  
End Products ◽  
Photochemical Ozone ◽  
Global Warming Potentials ◽  
Cl Atoms

OH, Cl and O3 kinetics and IR spectra of (CF3)2CCH2 utilized to estimate tropospheric lifetimes, radiative efficiencies, global warming potentials, estimated photochemical ozone creation potentials and tropospheric oxidation end-products.

The environmental impact of unsaturated fluoroesters: atmospheric chemistry towards OH radicals and Cl atoms, radiative behavior and cumulative ozone creation

RSC Advances ◽  
2016 ◽  
Vol 6 (26) ◽  
pp. 21833-21843 ◽  
Author(s):  
Ana Rodríguez ◽  
Iván Bravo ◽  
Diana Rodríguez ◽  
Mercedes Tajuelo ◽  
Yolanda Diaz-de-Mera ◽  
...  
Keyword(s):  
Global Warming ◽  
Environmental Impact ◽  
Infrared Spectra ◽  
Atmospheric Chemistry ◽  
Reaction Mechanisms ◽  
Radiative Forcing ◽  
Oh Radicals ◽  
Global Warming Potentials ◽  
Cl Atoms

Atmospheric lifetimes, reaction mechanisms, infrared spectra, radiative forcing efficiencies, global warming potentials and ozone creation potentials of the allyl and vinyl trifluoroacetate were determined to assess their environmental impact.

A theoretical insight into atmospheric chemistry of HFE-7100 and perfluoro-butyl formate: reactions with OH radicals and Cl atoms and the fate of alkoxy radicals

2016 ◽  
Vol 40 (7) ◽  
pp. 6148-6155 ◽  
Author(s):  
Bhupesh Kumar Mishra ◽  
Makroni Lily ◽  
Ramesh Chandra Deka ◽  
Asit K. Chandra
Keyword(s):  
Global Warming ◽  
Atmospheric Chemistry ◽  
Global Warming Potential ◽  
Rate Constants ◽  
Oh Radicals ◽  
Atmospheric Lifetime ◽  
Alkoxy Radicals ◽  
Cl Atoms ◽  
Theoretical Insight ◽  
Insight Into

The calculated rate constants for C4F9OCH3 + OH/Cl reactions are found to be 1.94 × 10−14 and 1.74 × 10−12 cm3 molecule−1 s−1, respectively, at 298 K. The atmospheric lifetime and global warming potential for HFE-7100 are computed to be 2.12 years and 155.3, respectively.

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