Propene Oxidation on V4O11−Cluster: Reaction Dynamics to Acrolein

2010 ◽  
Vol 114 (23) ◽  
pp. 6542-6549 ◽  
Author(s):  
Hai-Bei Li ◽  
Shan Xi Tian ◽  
Jinlong Yang
Keyword(s):  
Reaction Dynamics ◽  
Propene Oxidation ◽  
Cluster Reaction

Reaction Dynamics in Femtosecond and Microsecond Time Windows: Ammonia Clusters as a Paradigm

1996 ◽  
Author(s):  
S. Wei ◽  
A. W. , Jr Castleman
Keyword(s):  
Mass Spectrometry ◽  
Energy Transfer ◽  
Real Time ◽  
Gas Phase ◽  
Reaction Dynamics ◽  
Research Field ◽  
Pump Probe ◽  
Time Domains ◽  
Zero Kinetic Energy ◽  
Cluster Reaction

The last decade has seen tremendous growth in the study of gas phase clusters. Some areas of cluster research which have received considerable attention in this regard include solvation (Lee et al. 1980), (Armirav et al. 1982), and reactivity (Dantus et al. 1991; Khudkar and Zewail 1990; Rosker et al. 1988; Scherer et al. 1987). In particular, studies of the dynamics of formation and dissociation, and the changing properties of clusters at successively higher degrees of aggregation, enable an investigation of the basic mechanisms of nucleation and the continuous transformation of matter from the gas phase to the condensed phase to be probed at the molecular level (Castleman and Keesee 1986a, 1988). In this context, the progressive clustering of a molecule involves energy transfer and redistribution within the molecular system, with attendant processes of unimolecular dissociation taking place between growth steps (Kay and Castleman 1983). Related processes of energy transfer, proton transfer, and dissociation are also operative during the reorientation of molecules about ions produced during the primary ionization event required in detecting clusters via mass spectrometry (Castleman and Keesee 1986b), providing further motivation for studies of the reaction dynamics of clusters (Begemann et al. 1986; Boesl et al 1992; Castleman and Keesee 1987; Echt et al. 1985; Levine and Bernstein 1987; Lifshitz et al. 1990; Lifshitz and Louage 1989, 1990; Märk 1987; Märk and Castleman 1984, 1986; Morgan and Castleman 1989; Stace and Moore 1983; Wei et al. 1990a,b). The real-time probing of cluster reaction dynamics is a facilitating research field through femtosecond pump-probe techniques pioneered by Zewail and coworkers (Dantus et al. 1991; Khundkar and Zewail 1990; Rosker et al. 1988; Scherer et al. 1987). Some real-time investigations have been performed on metal, van der Waals, and hydrogen-bonded clusters by employing these pump-probe spectroscopic techniques. For example, the photoionization and fragmentation of sodium clusters have been investigated by ion mass spectrometry and zero kinetic energy photoelectron spectroscopy in both picosecond (Schreiber et al. 1992) and femtosecond (Baumert et al. 1992, 1993; Bühler et al. 1992) time domains. Studies have also been made to elucidate the effect of solvation on intracluster reactions.

Reaction Dynamics — Recent Advances

1991 ◽  
Vol 174 (Part_2) ◽  
pp. 225-225
Author(s):  
Wolfgang Schirmer
Keyword(s):  
Reaction Dynamics ◽  
Recent Advances

A Comparative Study of the Reaction Dynamics of a Model System Using Different Criteria in Parameterizing the Potential Energy Function

1991 ◽  
Author(s):  
Betsy M. Rice ◽  
Cary F. Chabalowski ◽  
George F. Adams ◽  
Richard C. Mowrey ◽  
Michael J. Page
Keyword(s):  
Potential Energy ◽  
Comparative Study ◽  
Energy Function ◽  
Reaction Dynamics ◽  
Potential Energy Function ◽  
Model System

Sixth Conference on Molecular Reaction Dynamics in Condensed Matter

2001 ◽  
Author(s):  
Dana D. Dlott
Keyword(s):  
Condensed Matter ◽  
Reaction Dynamics ◽  
Molecular Reaction

Study of Ionic Structure and Ion Reaction Dynamics by Cavity Ring-Down Spectroscopy

2001 ◽  
Author(s):  
Richard N. Zare ◽  
Marguerite B. Wilbur
Keyword(s):  
Reaction Dynamics ◽  
Ionic Structure ◽  
Cavity Ring Down Spectroscopy ◽  
Cavity Ring Down

Femtosecond reaction dynamics of Rydberg states. Methyl iodide

1993 ◽  
Vol 214 (3-4) ◽  
pp. 281-289 ◽  
Author(s):  
M.H.M. Janssen ◽  
M. Dantus ◽  
H. Guo ◽  
A.H. Zewail
Keyword(s):  
Methyl Iodide ◽  
Rydberg States ◽  
Reaction Dynamics

scholarly journals The influence of α-1,4-glucan substrates on 4,6-α-d-glucanotransferase reaction dynamics during isomalto/malto-polysaccharide synthesis

2021 ◽  
Author(s):  
C.E. Klostermann ◽  
P.H. van der Zaal ◽  
H.A. Schols ◽  
P.L. Buwalda ◽  
J.H. Bitter
Keyword(s):  
Reaction Dynamics ◽  
Polysaccharide Synthesis

Quantum calculations of the photoelectron spectra of the OH−·NH3 anion: implications for OH + NH3 → H2O + NH2 reaction dynamics

2021 ◽  
Vol 23 (11) ◽  
pp. 6950-6958
Author(s):  
Kohei Saito ◽  
Yutaro Sugiura ◽  
Takaaki Miyazaki ◽  
Yukinobu Takahashi ◽  
Toshiyuki Takayanagi
Keyword(s):  
Quantum Dynamics ◽  
Photoelectron Spectrum ◽  
Reaction Dynamics ◽  
Photoelectron Spectra ◽  
Quantum Calculations ◽  
Anion Complex

Quantum dynamics calculations were performed to analyze the experimentally measured photoelectron spectrum of the OH−·NH3 anion complex.

scholarly journals 7Be and 8B reaction dynamics at Coulomb barrier energies

2018 ◽  
Vol 184 ◽  
pp. 02015
Author(s):  
E. Strano ◽  
M. Mazzocco ◽  
A. Boiano ◽  
C. Boiano ◽  
M. La Commara ◽  
...  
Keyword(s):  
Cross Sections ◽  
Coulomb Barrier ◽  
Reaction Cross Section ◽  
Optical Model ◽  
Reaction Dynamics ◽  
Reaction Cross ◽  
Total Reaction Cross Section ◽  
Weakly Bound ◽  
Total Reaction ◽  
Reaction Cross Sections

We investigated the reaction dynamics induced by the 7Be,8B+208Pb collisions at energies around the Coulomb barrier. Charged particles originated by both the col- lisions were detected by means of 6 ΔE-Eres telescopes of a newly developed detector array. Experimental data were analysed within the framework of the Optical Model and the total reaction cross-sections were compared together and with the 6,7Li+208Pb colli-sion data. According to the preliminary results, 7Be nucleus reactivity is rather similar to the 7Li one whereas the 8B+208Pb total reaction cross section appears to be much larger than those measured for reactions induced by the other weakly-bound projectiles on the same target.

Sign in / Sign up

Export Citation Format

Share Document