Tailored One- and Two-Dimensional Self-Assembly of a Perylene Diimide Derivative in Organic Solvents

2011 ◽  
Vol 115 (32) ◽  
pp. 9703-9709 ◽  
Author(s):  
Michal T. Usowicz ◽  
Michael J. Kelley ◽  
Kenneth D. Singer ◽  
Volodimyr V. Duzhko
Keyword(s):  
Organic Solvents ◽  
Self Assembly ◽  
Perylene Diimide ◽  
Two Dimensional

scholarly journals Self-Assembly of Silver Clusters into One- and Two-Dimensional Structures as Artificial Intelligent Sensors of Alcohol

2021 ◽  
Author(s):  
Gao Li ◽  
Zhaoxian Qin ◽  
Sachil Sharma ◽  
Yongwu Peng
Keyword(s):  
Organic Solvents ◽  
Self Assembly ◽  
Silver Cluster ◽  
Silver Clusters ◽  
Two Dimensional ◽  
Artificial Intelligent ◽  
Atomic Structures ◽  
Intelligent Sensors ◽  
Crucial Component ◽  
Solvent Molecules

Abstract Reggeization and response to external stimulus is an important part of artificial intelligence, which would significantly improve the quality of life in the future. The development of new materials for the design of sensitive and responsive sensors has become a crucial component. Here, two silver cluster-based polymers (Ag-CBPs), including one-dimensional (1D) {Ag22(L1)8(CF3CO2)14(CH3OH)2}n chain and two-dimensional (2D) {[Ag12(L2)2(CO2CF3)14(H2O)4(AgCO2CF3)4](HNEt3)2}n film, are designed and used to simulate the human nose - an elegant sensor to smells, to distinguish organic solvents. We study the relationship between the atomic structures of Ag-CBPs determined by X-ray diffraction and electrical properties in the presence of organic solvents (e.g. methanol, ethanol). The ligands, cations and the ligated solvent molecules not only play an important role in the self-assembly process of Ag-CBP materials, but also determine their physiochemical properties. An application of cluster-based polymers is demonstrated in the artificial intelligent sensors.

Two-Dimensional Self-Assembly of Liquid-Crystalline Perylene Diimide Derivatives at the Air/Water Interface

ChemPhysChem ◽  
2002 ◽  
Vol 3 (12) ◽  
pp. 1041-1044 ◽  
Author(s):  
Guodong Sui ◽  
Jhony Orbulescu ◽  
Mustapha Mabrouki ◽  
Roger M. Leblanc ◽  
Shenggao Liu ◽  
...  
Keyword(s):  
Self Assembly ◽  
Liquid Crystalline ◽  
Perylene Diimide ◽  
Water Interface ◽  
Two Dimensional ◽  
Air Water Interface ◽  
Perylene Diimide Derivatives

Generation of Emissive Nanosphere from Micro-Aggregates in Anionic Perylene Diimide: Co-relation of Self-Assembly, Emission, and Electrical Properties

2021 ◽  
pp. 109461
Author(s):  
Susmita Roy ◽  
Nilima Sinha ◽  
Srimanta Pakhira ◽  
Chanchal Chakraborty
Keyword(s):  
Electrical Properties ◽  
Self Assembly ◽  
Perylene Diimide

scholarly journals Template-Free Self-Assembly of Two-Dimensional Polymers into Nano/Microstructured Materials

Molecules ◽  
2021 ◽  
Vol 26 (11) ◽  
pp. 3310
Author(s):  
Shengda Liu ◽  
Jiayun Xu ◽  
Xiumei Li ◽  
Tengfei Yan ◽  
Shuangjiang Yu ◽  
...  
Keyword(s):  
Self Assembly ◽  
Recent Progress ◽  
Two Dimensional ◽  
Subsequent Removal ◽  
The Past ◽  
2D Polymers ◽  
Template Free ◽  
Self Assembled ◽  
The Relationship ◽  
Polymer Tubes

In the past few decades, enormous efforts have been made to synthesize covalent polymer nano/microstructured materials with specific morphologies, due to the relationship between their structures and functions. Up to now, the formation of most of these structures often requires either templates or preorganization in order to construct a specific structure before, and then the subsequent removal of previous templates to form a desired structure, on account of the lack of “self-error-correcting” properties of reversible interactions in polymers. The above processes are time-consuming and tedious. A template-free, self-assembled strategy as a “bottom-up” route to fabricate well-defined nano/microstructures remains a challenge. Herein, we introduce the recent progress in template-free, self-assembled nano/microstructures formed by covalent two-dimensional (2D) polymers, such as polymer capsules, polymer films, polymer tubes and polymer rings.

General Interfacial Self‐Assembly Engineering for Patterning Two‐Dimensional Polymers with Cylindrical Mesopores on Graphene

2019 ◽  
Vol 58 (30) ◽  
pp. 10173-10178 ◽  
Author(s):  
Hao Tian ◽  
Jieqiong Qin ◽  
Dan Hou ◽  
Qian Li ◽  
Chen Li ◽  
...  
Keyword(s):  
Self Assembly ◽  
Two Dimensional

Percolation in two-dimensional nanoparticle films from colloidal self-assembly

2007 ◽  
Vol 204 (6) ◽  
pp. 1856-1862 ◽  
Author(s):  
Ching-Ling Hsu ◽  
Szu-Ming Chu ◽  
Kiwi Wood ◽  
Yi-Rong Yang
Keyword(s):  
Self Assembly ◽  
Two Dimensional ◽  
Nanoparticle Films

Synthesis, Self-assembly, and Crystal Structure of a Shape-Persistent Polyhedral-Oligosilsesquioxane-Nanoparticle-Tethered Perylene Diimide

2010 ◽  
Vol 114 (14) ◽  
pp. 4802-4810 ◽  
Author(s):  
Xiangkui Ren ◽  
Bin Sun ◽  
Chi-Chun Tsai ◽  
Yingfeng Tu ◽  
Siwei Leng ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Self Assembly ◽  
Perylene Diimide ◽  
Polyhedral Oligosilsesquioxane

Dispersions of Two-Dimensional Titanium Carbide MXene in Organic Solvents

2017 ◽  
Vol 29 (4) ◽  
pp. 1632-1640 ◽  
Author(s):  
Kathleen Maleski ◽  
Vadym N. Mochalin ◽  
Yury Gogotsi
Keyword(s):  
Titanium Carbide ◽  
Organic Solvents ◽  
Two Dimensional

Large Scale Supramolecular Self-Assembly of Graft-Copolymers Prepared by Rapid Evaporation of Organic Solvents

1999 ◽  
Vol 28 (11) ◽  
pp. 1221-1222 ◽  
Author(s):  
Akio Kishida ◽  
Fusako Seto ◽  
Ken-ichiro Hiwatari ◽  
Takeshi Serizawa ◽  
Youichiro Muraoka ◽  
...  
Keyword(s):  
Organic Solvents ◽  
Self Assembly ◽  
Large Scale ◽  
Graft Copolymers
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