Nitrogen Dioxide Reactions with 46 Atomic Main-Group and Transition Metal Cations in the Gas phase: Room Temperature Kinetics and Periodicities in Reactivity

2012 ◽  
Vol 117 (6) ◽  
pp. 1151-1157 ◽  
Author(s):  
Michael J. Y. Jarvis ◽  
Voislav Blagojevic ◽  
Gregory K. Koyanagi ◽  
Diethard K. Bohme
Keyword(s):  
Transition Metal ◽  
Nitrogen Dioxide ◽  
Gas Phase ◽  
Room Temperature ◽  
Metal Cations ◽  
Main Group ◽  
Transition Metal Cations

Early atomic transition metal cations reacting with ammonia at room temperature: H2 elimination and NH3 ligation kinetics across and down the periodic table

2019 ◽  
Vol 435 ◽  
pp. 181-187 ◽  
Author(s):  
Voislav Blagojevic ◽  
Vitali V. Lavrov ◽  
Gregory K. Koyanagi ◽  
Diethard K. Bohme
Keyword(s):  
Transition Metal ◽  
Periodic Table ◽  
Room Temperature ◽  
Metal Cations ◽  
Atomic Transition ◽  
Transition Metal Cations ◽  
H2 Elimination

scholarly journals Ligation kinetics as a probe for gas-phase ligand field effects: Ligation of atomic transition metal cations with ammonia at room temperature

2019 ◽  
Vol 25 (1) ◽  
pp. 44-49 ◽  
Author(s):  
Voislav Blagojevic ◽  
Vitali V Lavrov ◽  
Gregory K Koyanagi ◽  
Diethard K Bohme
Keyword(s):  
Transition Metal ◽  
Gas Phase ◽  
Strong Correlation ◽  
Inductively Coupled Plasma ◽  
Metal Cations ◽  
Ligand Field ◽  
Transition Metal Cations ◽  
Inductively Coupled ◽  
Field Effects ◽  
Selected Ion Flow Tube

The kinetics of ammonia ligation to atomic first and second row transition metal cations were measured in an attempt to assess the role of ligand field effects in gas-phase ion-molecule reaction kinetics. Measurements were performed at 295 ± 2 K in helium bath gas at 0.35 Torr using an inductively coupled plasma/selected-ion flow tube tandem mass spectrometer. The atomic cations were produced at ca. 5500 K in an inductively coupled plasma source and were allowed to decay radiatively and to thermalize by collisions with argon and helium atoms prior to reaction. A strong correlation was observed across the periodic table between the measured rate coefficients for ammonia ligation and measured/calculated bond dissociation energies. A similar strong correlation is seen with the ligand field stabilization energy. So ligand field stabilization energies should provide a useful predictor of relative rates of ligation of atomic metal ions.

Heavy Water Reactions with Atomic Transition-Metal and Main-Group Cations:  Gas Phase Room-Temperature Kinetics and Periodicities in Reactivity

2007 ◽  
Vol 111 (35) ◽  
pp. 8561-8573 ◽  
Author(s):  
Ping Cheng ◽  
Gregory K. Koyanagi ◽  
Diethard K. Bohme
Keyword(s):  
Transition Metal ◽  
Gas Phase ◽  
Heavy Water ◽  
Room Temperature ◽  
Main Group ◽  
Atomic Transition

Bimolecular Gas-Phase Reactions of d-Block Transition-Metal Cations With Dimethyl Peroxide: Trends Across the Periodic Table

1995 ◽  
Vol 1 (9) ◽  
pp. 608-613 ◽  
Author(s):  
Ralf Wesendrup ◽  
Christoph A. Schalley ◽  
Detlef Schröder ◽  
Helmut Schwarz
Keyword(s):  
Transition Metal ◽  
Gas Phase ◽  
Periodic Table ◽  
Metal Cations ◽  
Gas Phase Reactions ◽  
Transition Metal Cations

Carbon Disulfide Reactions with Atomic Transition-Metal and Main-Group Cations:  Gas-Phase Room-Temperature Kinetics and Periodicities in Reactivity

2006 ◽  
Vol 110 (8) ◽  
pp. 2718-2728 ◽  
Author(s):  
Ping Cheng ◽  
Gregory K. Koyanagi ◽  
Diethard K. Bohme
Keyword(s):  
Transition Metal ◽  
Gas Phase ◽  
Carbon Disulfide ◽  
Room Temperature ◽  
Main Group ◽  
Atomic Transition

Gas-phase reactivity of transition metal cations with cyanogen radical precursors

1994 ◽  
Vol 35 (18) ◽  
pp. 2895-2898 ◽  
Author(s):  
Michel Sablier ◽  
Laure Capron ◽  
Hélène Mestdagh ◽  
Christian Rolando
Keyword(s):  
Transition Metal ◽  
Gas Phase ◽  
Metal Cations ◽  
Transition Metal Cations
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