Resonances of electromagnetic-induced transparency and electromagnetic-induced absorption at the transition with level momenta J=1/2 in unidirectional wave spectroscopy

The physical processes that form the saturated absorption resonance spectra on the atomic transition with level momenta J= 1/2 in the field of unidirectional waves of arbitrary intensities are investigated both analytically and numerically. It is shown that the narrow structures of the nonlinear resonance spectra (resonances of electromagnetic-induced transparency and absorption) and the processes forming them are determined by the direction of the light wave polarizations, degree of openness of the atomic transition, and the saturating wave intensity. The conditions under which the nonlinear resonance is exclusively coherent, due to the magnetic coherence of transition levels, are revealed.

Velocity effect on the stimulated transition process of a multilevel atom in a thermal bath

This paper investigates the stimulated transition process of a uniformly moving atom in interaction with a thermal bath of the quantum electromagnetic field. Using the perturbation theory, the atomic stimulated emission and absorption rates are calculated. The results indicate that the atomic transition rates depend crucially on the atomic velocity, the temperature of the thermal bath, and the atomic polarizability. As these factors change, the atomic stimulated transition processes can be enhanced or weakened at different degrees. In particular, slowly moving atoms in the thermal bath with high temperature ($$T\gg \omega _{0}$$ T ≫ ω 0 ) perceive a smaller effective temperature $$T \big ( 1-\frac{1}{10} v^{2} \big )$$ T ( 1 - 1 10 v 2 ) for the polarizability perpendicular to the atomic velocity or $$T \big ( 1-\frac{3}{10} v^{2} \big )$$ T ( 1 - 3 10 v 2 ) for the polarizability parallel to the atomic velocity. However, ultra-relativistic atoms perceive no influence of the background thermal bath. In turn, in terms of the atomic transition rates, this paper explores and examines the relativity of temperature of the quantum electromagnetic field.

Direct Kerr frequency comb atomic spectroscopy and stabilization

Microresonator-based soliton frequency combs, microcombs, have recently emerged to offer low-noise, photonic-chip sources for applications, spanning from timekeeping to optical-frequency synthesis and ranging. Broad optical bandwidth, brightness, coherence, and frequency stability have made frequency combs important to directly probe atoms and molecules, especially in trace gas detection, multiphoton light-atom interactions, and spectroscopy in the extreme ultraviolet. Here, we explore direct microcomb atomic spectroscopy, using a cascaded, two-photon 1529-nm atomic transition in a rubidium micromachined cell. Fine and simultaneous repetition rate and carrier-envelope offset frequency control of the soliton enables direct sub-Doppler and hyperfine spectroscopy. Moreover, the entire set of microcomb modes are stabilized to this atomic transition, yielding absolute optical-frequency fluctuations at the kilohertz level over a few seconds and <1-MHz day-to-day accuracy. Our work demonstrates direct atomic spectroscopy with Kerr microcombs and provides an atomic-stabilized microcomb laser source, operating across the telecom band for sensing, dimensional metrology, and communication.

Defective h-BN sheet embedded atomic metals as highly active and selective electrocatalysts for NH3 fabrication via NO reduction

The VB-containing defective h-BN sheet is proved to be a feasible support for atomic transition-metal anchoring. In particular, we found the Cu@h-BN and Ni@h-BN are highly active and selective catalysts for NO electro-reduction to generate NH3.

Development of a new database for Auger electron and X-ray spectra

An energy correction method is described to account for the Breit and QED effects on Auger electrons and X-ray energies in the recently developed atomic relaxation model BrIccEmis. The results are compared with literature and new experimental data for Z = 52. Overall this improves the agreement of the calculated energies with the literature values. A new atomic radiation database NS_Radlist, will contain atomic transition energies from the BrIccEmis program with these energy corrections.

Исследование взаимодействия атомов Cs с поверхностью сапфира с использованием сверхтонкой ячейки и метода вычисления второй производной спектра поглощения паров

The influence of the interaction of Cs atoms with a dielectric surface on the position and shape of the hyperfine components of the D2 line at nanometer-order distances between atoms and the surface is studied. The use of a nanocell with a wedge-shaped gap made it possible to study the dependence of the shifts of all the hyperfine components of the D2 line corresponding to the transitions Fg = 3- Fe = 2, 3, 4 and Fg = 4- Fe = 3, 4, 5, on the distance L between the atoms and the sapphire surface windows in the range of 50–400 nm. At L less than 100 nm, due to the van der Waals interaction, there is a strong broadening of atomic transitions and a shift of their frequencies to the low-frequency region of the spectrum (red shift). The calculation of the second derivative (SD) of the vapor absorption spectra in the nanocell allows one to spectrally resolve the hyperfine components of the atomic transition down to L about 50 nm and measure the coefficient of the van der Waals interaction C3. It is shown that, at L <100 nm, an additional red shift occurs with increasing atomic density, while at relatively large distances between atoms and the surface L about 400 nm, an increase in atomic density causes a blue shift of the atomic transition frequencies. The above results are important in the development of miniature submicron devices containing atomic vapor of alkali metal.