Rate Constants for 1,5- and 1,6-Hydrogen Atom Transfer Reactions of Mono-, Di-, and Tri-aryl-substituted Donors, Models for Hydrogen Atom Transfers in Polyunsaturated Fatty Acid Radicals

2008 ◽  
Vol 112 (9) ◽  
pp. 1891-1896 ◽  
Author(s):  
Christopher B. DeZutter ◽  
John H. Horner ◽  
Martin Newcomb
Keyword(s):  
Fatty Acid ◽  
Hydrogen Atom ◽  
Polyunsaturated Fatty Acid ◽  
Rate Constants ◽  
Hydrogen Atom Transfer ◽  
Transfer Reactions ◽  
Atom Transfer ◽  
Atom Transfer Reactions ◽  
Hydrogen Atom Transfers

Hydrogen atom transfer reactions of ferrate(vi) with phenols and hydroquinone. Correlation of rate constants with bond strengths and application of the Marcus cross relation

2016 ◽  
Vol 45 (1) ◽  
pp. 70-73 ◽  
Author(s):  
Jianhui Xie ◽  
Li Ma ◽  
William W. Y. Lam ◽  
Kai-Chung Lau ◽  
Tai-Chu Lau
Keyword(s):  
Hydrogen Atom ◽  
Rate Constant ◽  
Rate Constants ◽  
Hydrogen Atom Transfer ◽  
Transfer Reactions ◽  
Atom Transfer ◽  
Bond Strengths ◽  
Oxidation Of Phenols ◽  
Atom Transfer Reactions

The oxidation of phenols (X-CH6H4OH) and hydroquinone (H2Q) by HFeO4− proceeds via a hydrogen atom transfer (HAT) mechanism. The Marcus cross relation can be used to predict the rate constant of HAT from H2Q to HFeO4−.

scholarly journals Trends in Ground-State Entropies for Transition Metal Based Hydrogen Atom Transfer Reactions

2009 ◽  
Vol 131 (12) ◽  
pp. 4335-4345 ◽  
Author(s):  
Elizabeth A. Mader ◽  
Virginia W. Manner ◽  
Todd F. Markle ◽  
Adam Wu ◽  
James A. Franz ◽  
...  
Keyword(s):  
Hydrogen Atom ◽  
Transition Metal ◽  
Ground State ◽  
Hydrogen Atom Transfer ◽  
Transfer Reactions ◽  
Atom Transfer ◽  
Atom Transfer Reactions
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