Chemically Modified Ni/TiO2Nanocomposite Films:  Charge Transfer from Photoexcited TiO2Particles to Hexacyanoferrate Redox Centers within the Film and Unusual Photoelectrochemical Behavior

1997 ◽  
Vol 101 (49) ◽  
pp. 10151-10154 ◽  
Author(s):  
Norma R. de Tacconi ◽  
Judith Carmona ◽  
Krishnan Rajeshwar
Keyword(s):  
Charge Transfer ◽  
Chemically Modified ◽  
Redox Centers

Charge transfer electronic effects on chemically modified Mo(100) surfaces

1985 ◽  
Vol 159 (2-3) ◽  
pp. A466
Author(s):  
J.L. Grant ◽  
T.B. Fryberger ◽  
P.C. Stair
Keyword(s):  
Charge Transfer ◽  
Electronic Effects ◽  
Chemically Modified

Amide Tricobaltcarbon Clusters With Multiple Redox Centers

1986 ◽  
Vol 39 (9) ◽  
pp. 1435 ◽  
Author(s):  
BH Robinson ◽  
J Simpson ◽  
ME Trounson
Keyword(s):  
Charge Transfer ◽  
Amino Acid ◽  
Electronic Effects ◽  
Acid Moiety ◽  
Amide Linkage ◽  
Substituent Group ◽  
Irreversible Oxidation ◽  
Amino Acid Moiety ◽  
Intervalence Charge Transfer ◽  
Redox Centers

The complexes FcNHC (O)CCo3(CO)9 ( Fc = ferrocenyl ) (3) and Fc ( alaOMe )C(O)CCo3(CO)9 (ala = alanine ) (5) have been synthesized from the +C(O)CCo3(CO)9 cation and FcNH2 or Fc ( alaOMe )H respectively. Derivatives FcNHC (O)CCo3(CO)6[P( OPh )3]3 (4) and Fc ( alaOMe )C(O)CCo3(CO)6[P( OPh )3]3 (6) are also described. Analysis of the spectroscopic and redox behaviour shows that the amide linkage acts as a -I, -M substituent group to Fc and the Co3C unit acts as a-I, +M group. Unlike complexes where these redox centres are directly linked, electronic effects are not transmitted between Co3C and Fc . Oxidation at the ferrocene centre and reduction at the Co3C centre in (3) and (5) is chemically reversible whereas oxidation of the amino acid moiety is irreversible; oxidation of the cluster takes place in (4) and (6) but no intervalence charge transfer is observed.

Chemically modified electrodes. II. Predictability of formal potentials of covalently immobilized charge-transfer reagents

1978 ◽  
Vol 100 (16) ◽  
pp. 5213-5215 ◽  
Author(s):  
J. R. Lenhard ◽  
R. Rocklin ◽  
H. Abruna ◽  
K. Willman ◽  
K. Kuo ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Modified Electrodes ◽  
Chemically Modified Electrodes ◽  
Chemically Modified

Charge transfer electronic effects on chemically modified Mo(100) surfaces

1985 ◽  
Vol 159 (2-3) ◽  
pp. 333-352 ◽  
Author(s):  
J.L. Grant ◽  
T.B. Fryberger ◽  
P.C. Stair
Keyword(s):  
Charge Transfer ◽  
Electronic Effects ◽  
Chemically Modified

scholarly journals Chemically modified nanofoci unifying plasmonics and catalysis

2019 ◽  
Vol 10 (23) ◽  
pp. 5929-5934 ◽  
Author(s):  
Yueliang Wang ◽  
Lingling Fang ◽  
Ming Gong ◽  
Zhaoxiang Deng
Keyword(s):  
Charge Transfer ◽  
Plasmon Resonance ◽  
Chemically Modified ◽  
Self Assembled ◽  
Catalytic Functions

Chemical modifiability is achieved for self-assembled plasmonic nanogaps to enable charge transfer plasmon resonance and unified plasmonic and catalytic functions.

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