scholarly journals Self-Recombination Rate Constants for 2-Propanol andtert-Butyl Alcohol Radicals in Water.

1999 ◽  
Vol 103 (36) ◽  
pp. 7380-7380
Author(s):  
Stephen P. Mezyk ◽  
Keith P. Madden
Keyword(s):  
Rate Constants ◽  
Recombination Rate ◽  
Butyl Alcohol

Self-Recombination Rate Constants for 2-Propanol andtert-Butyl alcohol Radicals in Water†

1999 ◽  
Vol 103 (2) ◽  
pp. 235-242 ◽  
Author(s):  
Stephen P. Mezyk ◽  
Keith P. Madden
Keyword(s):  
Rate Constants ◽  
Recombination Rate ◽  
Butyl Alcohol

Time-resolved FTIR study of CO recombination with horseradish peroxidase

2008 ◽  
Vol 36 (6) ◽  
pp. 1165-1168 ◽  
Author(s):  
Amandine Maréchal ◽  
W. John Ingledew ◽  
Peter R. Rich
Keyword(s):  
Fourier Transform ◽  
Ir Spectroscopy ◽  
Horseradish Peroxidase ◽  
Rate Constants ◽  
Recombination Rate ◽  
Thermal Equilibrium ◽  
Time Resolved ◽  
Fourier Transform Ir Spectroscopy ◽  
Rapid Scan ◽  
Fourier Transform Ir

Vibrational changes associated with CO recombination to ferrous horseradish peroxidase were investigated by rapid-scan FTIR (Fourier-transform IR) spectroscopy in the 1200–2200 cm−1 range. At pH 6.0, two conformers of bound CO are present that appear as negative bands at 1905 and 1934 cm−1 in photolysis spectra. Their recombination rate constants are identical, confirming that they arise from two substates of bound CO that are in rapid thermal equilibrium, rather than from heterogeneous protein sites. A smaller positive band at 2134 cm−1 also appears on photolysis and decays with the same rate constant, indicative of an intraprotein geminate site involved in recombination or, possibly, a weak-affinity surface CO-binding site. Other signals arising from protein and haem in the 1700–1200 cm−1 range can also be time-resolved with similar kinetics.

Measurement of oxygen recombination rate constants by the piezoelectric method

1987 ◽  
Vol 53 (3) ◽  
pp. 1054-1057 ◽  
Author(s):  
I. E. Zabelinskii ◽  
O. P. Shatalov
Keyword(s):  
Rate Constants ◽  
Recombination Rate

The Master Equation for the Dissociation of a Dilute Diatomic Gas. X. How Rotation Causes Low Arrhenius Temperature Coefficients

1973 ◽  
Vol 51 (18) ◽  
pp. 3152-3155 ◽  
Author(s):  
Huw O. Pritchard
Keyword(s):  
Low Temperature ◽  
Temperature Coefficient ◽  
Rate Constants ◽  
Recombination Rate ◽  
Negative Temperature Coefficient ◽  
Negative Temperature ◽  
Equilibrium Form ◽  
Temperature Coefficients ◽  
Recombination Rate Constant ◽  
Arrhenius Temperature

It is shown that previously calculated nonequilibrium rate constants for the dissociation of H2 and D2 appear to approach a rotationally averaged equilibrium expression at low temperature. This equilibrium form of the rate expression itself has an Arrhenius temperature coefficient for dissociation which is significantly less than the dissociation energy, and the corresponding recombination rate constant has a negative temperature coefficient. The reasons for this are explained.

Radiative and non-radiative exciton recombination rate constants in ZnSe clusters

2019 ◽  
Vol 92 (12) ◽  
Author(s):  
Ning Du ◽  
Shengping Yu ◽  
Yujuan Xie ◽  
Yingqi Cui ◽  
Li Zhang ◽  
...  
Keyword(s):  
Rate Constants ◽  
Recombination Rate ◽  
Exciton Recombination
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