Size Effects on Miscibility and Glass Transition Temperature of Binary Polymer Blend Films

Langmuir ◽  
2006 ◽  
Vol 22 (3) ◽  
pp. 1241-1246 ◽  
Author(s):  
Zhi Min Ao ◽  
Qing Jiang
Keyword(s):  
Glass Transition ◽  
Transition Temperature ◽  
Glass Transition Temperature ◽  
Polymer Blend ◽  
Size Effects ◽  
Blend Films ◽  
Binary Polymer

Size Effects on Miscibility and Glass Transition Temperature of PS/TMPC Blend Films: a Simulation and Thermodynamic Approach

2007 ◽  
Vol 334-335 ◽  
pp. 105-108 ◽  
Author(s):  
Zhi Min Ao ◽  
Qing Jiang
Keyword(s):  
Glass Transition ◽  
Transition Temperature ◽  
Glass Transition Temperature ◽  
Size Effects ◽  
Md Simulation ◽  
Weight Fraction ◽  
Blend Films ◽  
Size Dependent ◽  
Binary Polymer ◽  
Interaction Parameter Χ

The size dependent miscibility of binary polymer blend films of polystyrene (PS) and tetramethylbisphenol-A polycarbonate (TMPC) is studied by the molecular dynamics (MD) simulation in the way of computing Flory-Huggins interaction parameter, χ, of the blend films, which determines the blend films compatibility. It is found that the miscibility of the two polymers decreases as the film thickness D decreases. After that, the size dependent glass transition temperature Tg(w,D) of the two polymers blend films in miscible ranges are determined by computer simulation and the Fox equation where w is the weight fraction of the second component.

Thickness and Composition Dependence of the Glass Transition Temperature in Thin Homogeneous Polymer Blend Films

2002 ◽  
Vol 35 (1) ◽  
pp. 311-313 ◽  
Author(s):  
Jae Hyun Kim ◽  
Jyongsik Jang ◽  
Deuk-Young Lee ◽  
Wang-Cheol Zin
Keyword(s):  
Glass Transition ◽  
Transition Temperature ◽  
Glass Transition Temperature ◽  
Polymer Blend ◽  
Composition Dependence ◽  
Blend Films

Determination of the Glass-Transition Temperature of a Coal Extract, Using a Polymer Blend Methodology

2004 ◽  
Vol 18 (6) ◽  
pp. 1648-1655 ◽  
Author(s):  
Pakorn Opaprakasit ◽  
Paul C. Painter
Keyword(s):  
Glass Transition ◽  
Transition Temperature ◽  
Glass Transition Temperature ◽  
Polymer Blend

Interdiffusion in a homogeneous polymer blend far above its glass transition temperature

1993 ◽  
Vol 26 (20) ◽  
pp. 5310-5315 ◽  
Author(s):  
G. Meier ◽  
G. Fytas ◽  
B. Momper ◽  
G. Fleischer
Keyword(s):  
Glass Transition ◽  
Transition Temperature ◽  
Glass Transition Temperature ◽  
Polymer Blend

Glass Transition Temperature of a Component near Infinite Dilution in Binary Polymer Blends: Determination via Fluorescence Spectroscopy

2011 ◽  
Vol 44 (17) ◽  
pp. 6645-6648 ◽  
Author(s):  
Christopher M. Evans ◽  
Robert W. Sandoval ◽  
John M. Torkelson
Keyword(s):  
Glass Transition ◽  
Transition Temperature ◽  
Glass Transition Temperature ◽  
Fluorescence Spectroscopy ◽  
Polymer Blends ◽  
Infinite Dilution ◽  
Binary Polymer

Use of Inverse Gas Chromatography To Study Binary Polymer−Solvent Systems near the Glass Transition Temperature

2004 ◽  
Vol 37 (24) ◽  
pp. 9201-9210 ◽  
Author(s):  
Peter K. Davis ◽  
Ronald P. Danner ◽  
J. Larry Duda ◽  
Ilyess Hadj Romdhane
Keyword(s):  
Gas Chromatography ◽  
Glass Transition ◽  
Transition Temperature ◽  
Glass Transition Temperature ◽  
Inverse Gas Chromatography ◽  
Binary Polymer ◽  
Solvent Systems ◽  
Polymer Solvent
Sign in / Sign up

Export Citation Format

Share Document