Finite-size effects on the glass transition temperature

1994 ◽  
Vol 90 (8) ◽  
pp. 527-532 ◽  
Author(s):  
Allen Hunt
Keyword(s):  
Glass Transition ◽  
Transition Temperature ◽  
Glass Transition Temperature ◽  
Size Effects ◽  
Finite Size ◽  
Finite Size Effects

scholarly journals End of aging as a probe of finite-size effects near the spin-glass transition temperature

2018 ◽  
Vol 98 (10) ◽  
Author(s):  
Gregory G. Kenning ◽  
Daniel M. Tennant ◽  
Christina M. Rost ◽  
Fagner Garrote da Silva ◽  
Brian J. Walters ◽  
...  
Keyword(s):  
Glass Transition ◽  
Transition Temperature ◽  
Glass Transition Temperature ◽  
Spin Glass ◽  
Size Effects ◽  
Finite Size ◽  
Finite Size Effects ◽  
Spin Glass Transition

Size Effects on Miscibility and Glass Transition Temperature of PS/TMPC Blend Films: a Simulation and Thermodynamic Approach

2007 ◽  
Vol 334-335 ◽  
pp. 105-108 ◽  
Author(s):  
Zhi Min Ao ◽  
Qing Jiang
Keyword(s):  
Glass Transition ◽  
Transition Temperature ◽  
Glass Transition Temperature ◽  
Size Effects ◽  
Md Simulation ◽  
Weight Fraction ◽  
Blend Films ◽  
Size Dependent ◽  
Binary Polymer ◽  
Interaction Parameter Χ

The size dependent miscibility of binary polymer blend films of polystyrene (PS) and tetramethylbisphenol-A polycarbonate (TMPC) is studied by the molecular dynamics (MD) simulation in the way of computing Flory-Huggins interaction parameter, χ, of the blend films, which determines the blend films compatibility. It is found that the miscibility of the two polymers decreases as the film thickness D decreases. After that, the size dependent glass transition temperature Tg(w,D) of the two polymers blend films in miscible ranges are determined by computer simulation and the Fox equation where w is the weight fraction of the second component.

Size Effect on Glass Transition Temperature of Nanopolymers

2007 ◽  
Vol 121-123 ◽  
pp. 1317-1320 ◽  
Author(s):  
X.Y. Lang ◽  
Qing Jiang
Keyword(s):  
Glass Transition ◽  
Transition Temperature ◽  
Glass Transition Temperature ◽  
Size Effect ◽  
Methyl Methacrylate ◽  
Finite Size ◽  
Unified Model ◽  
Finite Size Effect ◽  
Interface Conditions ◽  
Poly Methyl Methacrylate

A unified model is developed for the finite size effect on the glass transition temperature of polymers Tg(D) where D denotes diameter of particles or thickness of films. In terms of this model, Tg(D) depends on both the size and interface conditions. The predicated results are consistent with the experimental evidences of polystyrene (PS) and poly (methyl methacrylate) (PMMA) films and nanoparticles with different interface situations.

scholarly journals Finite-size effects on the vortex-glass transition in thinYBa2Cu3O7−δfilms

1995 ◽  
Vol 52 (6) ◽  
pp. 4536-4544 ◽  
Author(s):  
P. J. M. Wöltgens ◽  
C. Dekker ◽  
R. H. Koch ◽  
B. W. Hussey ◽  
A. Gupta
Keyword(s):  
Glass Transition ◽  
Size Effects ◽  
Finite Size ◽  
Finite Size Effects ◽  
Vortex Glass
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