Multicomponent Adsorption of Alcohols onto Silicalite-1 from Aqueous Solution: Isotherms, Structural Analysis, and Assessment of Ideal Adsorbed Solution Theory

Langmuir ◽  
2012 ◽  
Vol 28 (44) ◽  
pp. 15566-15576 ◽  
Author(s):  
Peng Bai ◽  
Michael Tsapatsis ◽  
J. Ilja Siepmann
Keyword(s):  
Aqueous Solution ◽  
Structural Analysis ◽  
Solution Theory ◽  
Multicomponent Adsorption ◽  
Ideal Adsorbed Solution Theory ◽  
Adsorbed Solution ◽  
Adsorbed Solution Theory

Prediction of multicomponent adsorption equilibria using ideal adsorbed solution theory

1985 ◽  
Vol 19 (11) ◽  
pp. 1037-1043 ◽  
Author(s):  
David W. Hand ◽  
Scott. Loper ◽  
Metin. Ari ◽  
John C. Crittenden
Keyword(s):  
Solution Theory ◽  
Multicomponent Adsorption ◽  
Adsorption Equilibria ◽  
Ideal Adsorbed Solution Theory ◽  
Adsorbed Solution ◽  
Adsorbed Solution Theory

Correction. Prediction of Multicomponent Adsorption Equilibria Using Ideal Adsorbed Solution Theory

1986 ◽  
Vol 20 (8) ◽  
pp. 840-840
Author(s):  
John C. Crittenden ◽  
Paul. Luft ◽  
David W. Hand ◽  
Jacqueline L. Oravitz ◽  
Scott W. Loper ◽  
...  
Keyword(s):  
Solution Theory ◽  
Multicomponent Adsorption ◽  
Adsorption Equilibria ◽  
Ideal Adsorbed Solution Theory ◽  
Adsorbed Solution ◽  
Adsorbed Solution Theory

Predicting multicomponent adsorption: 50 years of the ideal adsorbed solution theory

AIChE Journal ◽  
2015 ◽  
Vol 61 (9) ◽  
pp. 2757-2762 ◽  
Author(s):  
Krista S. Walton ◽  
David S. Sholl
Keyword(s):  
Solution Theory ◽  
Multicomponent Adsorption ◽  
Ideal Adsorbed Solution Theory ◽  
Adsorbed Solution ◽  
The Ideal ◽  
Adsorbed Solution Theory

scholarly journals Incorporation of pora network connerctivity on the prediction of binary liquid phase adsorption of flavour esters in activated carbon

2018 ◽  
Vol 4 (1) ◽  
pp. 146
Author(s):  
Suryadi Ismadji
Keyword(s):  
Activated Carbon ◽  
Network Connectivity ◽  
Structural Heterogeneity ◽  
Pore Network ◽  
Probe Molecules ◽  
Solution Theory ◽  
Multicomponent Adsorption ◽  
Ideal Adsorbed Solution Theory ◽  
Adsorbed Solution ◽  
Adsorbed Solution Theory

The structural heterogeneity of activated carbon is a result of the existence of micropores, mesopores, and macropores of different sizes and shapes, randomly connected in a pore network. In a pore network, some of the pores that are large enough to accommodate the probe molecules may be accessible through smaller pores that only permit the passage of probe molecules having a smaller size. In the adsorption process, especially involving large and complex probe molecules, the pore network connectivity is very important, and governs the transport and reaction properties of the pores. A method for incorporation of the pore network connectivity along with lAST (Ideal Adsorbed Solution Theory Method) on the prediction of binary component adsorption isotherm is proposed in this article. IAST is used in conjunction with the modified DR (Dubinin-Radushkevich) single component isotherm, and is found that the incorporation of the connectivity can improve the accuracy of model inpredicts the multicomponent adsorption performance.Keywords: Adsorption,  IAST, Pore Network ConnectivityAbstrak Pore network connectivity memegang peranan yang penting dalam proses adsorpsi yang melibatkan senyawa senyawa kompleks. Pada makalah ini diusulkan suatu metode yang menggabungkan Pore network connectivity dan persamaan IAST untuk prediksi isotherm adsorpsi senyawa biner. Untuk mendapatkan isotherm adsorpsi dilakukan percobaan dengan menggunakan ethyl propionate dan ethyl butyrate sebagai adsorbate dan sebagai adsorbent digunakan karbon aktif Filtrasorb F-400 dan Norit ROW 0.8. Untuk menggambarkan isotherm adsorpsi dari hasil percobaan digunakan persamaan The Ideal Adsorbed Solution Theory dengan modifikasi persamaan isotherm adsorpsi dari Dubinin-Radushkevich dan Pore network connectivity. Dari hasil yang dipero/eh dapat disimpulkan bahwa persamaan yang melibatkan pengaruh pore network connectivity dapat meningkatkan unjuk kerja dari persamaan isotherm multi komponen untuk prediksi data data percobaan adsorpsi biner.Kata Kunci: Adsorpsi, IAST, Pore Network Connectivity

scholarly journals Adsorption for efficient low carbon hydrogen production: part 2—Cyclic experiments and model predictions

Adsorption ◽  
2021 ◽  
Author(s):  
Anne Streb ◽  
Marco Mazzotti
Keyword(s):  
Hydrogen Production ◽  
Carbon Capture And Storage ◽  
Clean Energy ◽  
Separation Performance ◽  
Low Carbon ◽  
Solution Theory ◽  
Feed Composition ◽  
Ideal Adsorbed Solution Theory ◽  
Adsorbed Solution ◽  
Adsorbed Solution Theory

Abstract Hydrogen as clean energy carrier is expected to play a key role in future low-carbon energy systems. In this paper, we demonstrate a new technology for coupling fossil-fuel based hydrogen production with carbon capture and storage (CCS): the integration of CO2 capture and H2 purification in a single vacuum pressure swing adsorption (VPSA) cycle. An eight step VPSA cycle is tested in a two-column lab-pilot for a ternary CO2–H2–CH4 stream representative of shifted steam methane reformer (SMR) syngas, while using commercial zeolite 13X as adsorbent. The cycle can co-purify CO2 and H2, thus reaching H2 purities up to 99.96%, CO2 purities up to 98.9%, CO2 recoveries up to 94.3% and H2 recoveries up to 81%. The key decision variables for adjusting the separation performance to reach the required targets are the heavy purge (HP) duration, the feed duration, the evacuation pressure and the flow rate of the light purge (LP). In contrast to that, the separation performance is rather insensitive towards small changes in feed composition and in HP inlet composition. Comparing the experimental results with simulation results shows that the model for describing multi-component adsorption is critical in determining the predictive capabilities of the column model. Here, the real adsorbed solution theory (RAST) is necessary to describe all experiments well, whereas neither extended isotherms nor the ideal adsorbed solution theory (IAST) can reproduce all effects observed experimentally.

scholarly journals Effective Separation of Prime Olefins from Gas Stream Using Anion Pillared Metal Organic Frameworks: Ideal Adsorbed Solution Theory Studies, Cyclic Application and Stability

Catalysts ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 510
Author(s):  
Majeda Khraisheh ◽  
Fares. Almomani ◽  
Gavin Walker
Keyword(s):  
Breakthrough Curves ◽  
Isotherm Models ◽  
Regeneration Ability ◽  
Solution Theory ◽  
Experimental Conditions ◽  
Ideal Adsorbed Solution Theory ◽  
Adsorbed Solution ◽  
The Stability ◽  
Adsorption Desorption ◽  
Adsorbed Solution Theory

The separation of C3H4/C3H6 is one of the most energy intensive and challenging operations, requiring up to 100 theoretical stages, in traditional cryogenic distillation. In this investigation, the potential application of two MOFs (SIFSIX-3-Ni and NbOFFIVE-1-Ni) was tested by studying the adsorption–desorption behaviors at a range of operational temperatures (300–360 K) and pressures (1–100 kPa). Dynamic adsorption breakthrough tests were conducted and the stability and regeneration ability of the MOFs were established after eight consecutive cycles. In order to establish the engineering key parameters, the experimental data were fitted to four isotherm models (Langmuir, Freundlich, Sips and Toth) in addition to the estimation of the thermodynamic properties such as the isosteric heats of adsorption. The selectivity of the separation was tested by applying ideal adsorbed solution theory (IAST). The results revealed that SIFSIX-3-Ni is an effective adsorbent for the separation of 10/90 v/v C3H4/C3H6 under the range of experimental conditions used in this study. The maximum adsorption reported for the same combination was 3.2 mmolg−1. Breakthrough curves confirmed the suitability of this material for the separation with a 10-min gab before the lighter C3H4 is eluted from the column. The separated C3H6 was obtained with a 99.98% purity.

scholarly journals Robust algorithms for the solution of the ideal adsorbed solution theory equations

AIChE Journal ◽  
2014 ◽  
Vol 61 (3) ◽  
pp. 981-991 ◽  
Author(s):  
Enzo Mangano ◽  
Daniel Friedrich ◽  
Stefano Brandani
Keyword(s):  
Solution Theory ◽  
Robust Algorithms ◽  
Ideal Adsorbed Solution Theory ◽  
Adsorbed Solution ◽  
The Ideal ◽  
Adsorbed Solution Theory
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