Structure of Aggregates in Diluted Aqueous Octyl Glucoside/Tetraethylene Glycol Monododecyl Ether Mixtures with Different Alkanols

Langmuir ◽  
2010 ◽  
Vol 26 (4) ◽  
pp. 2256-2262 ◽  
Author(s):  
Ramon Pons ◽  
Mercedes Valiente ◽  
Gemma Montalvo
2018 ◽  
Author(s):  
Elaine A. Kelly ◽  
Judith E. Houston ◽  
Rachel Evans

Understanding the dynamic self-assembly behaviour of azobenzene photosurfactants (AzoPS) is crucial to advance their use in controlled release applications such as<i></i>drug delivery and micellar catalysis. Currently, their behaviour in the equilibrium <i>cis-</i>and <i>trans</i>-photostationary states is more widely understood than during the photoisomerisation process itself. Here, we investigate the time-dependent self-assembly of the different photoisomers of a model neutral AzoPS, <a>tetraethylene glycol mono(4′,4-octyloxy,octyl-azobenzene) </a>(C<sub>8</sub>AzoOC<sub>8</sub>E<sub>4</sub>) using small-angle neutron scattering (SANS). We show that the incorporation of <i>in-situ</i>UV-Vis absorption spectroscopy with SANS allows the scattering profile, and hence micelle shape, to be correlated with the extent of photoisomerisation in real-time. It was observed that C<sub>8</sub>AzoOC<sub>8</sub>E<sub>4</sub>could switch between wormlike micelles (<i>trans</i>native state) and fractal aggregates (under UV light), with changes in the self-assembled structure arising concurrently with changes in the absorption spectrum. Wormlike micelles could be recovered within 60 seconds of blue light illumination. To the best of our knowledge, this is the first time the degree of AzoPS photoisomerisation has been tracked <i>in</i><i>-situ</i>through combined UV-Vis absorption spectroscopy-SANS measurements. This technique could be widely used to gain mechanistic and kinetic insights into light-dependent processes that are reliant on self-assembly.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Alejandro Lapresta-Fernández ◽  
Alfonso Salinas-Castillo ◽  
Luis Fermín Capitán-Vallvey

AbstractEncapsulation of magnetic nanoparticles (MNPs) of iron (II, III) oxide (Fe3O4) with a thermopolymeric shell of a crosslinked poly(2-(2-methoxyethoxy)ethyl methacrylate) P(MEO2MA) is successfully developed. Magnetic aggregates of large size, around 150–200 nm are obtained during the functionalization of the iron oxide NPs with vinyl groups by using 3-butenoic acid in the presence of a water soluble azo-initiator and a surfactant, at 70 °C. These polymerizable groups provide a covalent attachment of the P(MEO2MA) shell on the surface of the MNPs while a crosslinked network is achieved by including tetraethylene glycol dimethacrylate in the precipitation polymerization synthesis. Temperature control is used to modulate the swelling-to-collapse transition volume until a maximum of around 21:1 ratio between the expanded: shrunk states (from 364 to 144 nm in diameter) between 9 and 49 °C. The hybrid Fe3O4@P(MEO2MA) microgel exhibits a lower critical solution temperature of 21.9 °C below the corresponding value for P(MEO2MA) (bulk, 26 °C). The MEO2MA coating performance in the hybrid microgel is characterized by dynamic light scattering and transmission electron microscopy. The content of preformed MNPs [up to 30.2 (wt%) vs. microgel] was established by thermogravimetric analysis while magnetic properties by vibrating sample magnetometry.


1964 ◽  
Vol 42 (2) ◽  
pp. 304-320 ◽  
Author(s):  
F. W. Smith

The structure of 3-dimensional aggregates is discussed as a set of points on which graphs are constructed. By constructing the Voronoi honeycomb (Dirichlet regions) for the points and applying a small "irregularizing transformation", a "simplicial graph" and a "primitive coordination number" (whose value is close to 14 for all aggregates) can be defined universally for both regular and irregular aggregates. Recent studies of the geometry of irregular aggregates (of steel balls, crystal grains, etc.) are reviewed. The theory of liquids of J. D. Bernal is discussed and the simplicial graph is used to show that the "activation volume" of a Bernal liquid is about one-tenth of the molecular volume. The kinematics of flow of aggregates is discussed in terms of their graphs and in terms of a process of "volume exchange"—the production and destruction of free volume. Using these concepts, an equation is derived for the viscosity of a Bernal liquid as a product of five terms expressing respectively the kinematic, stoichiometric, kinetic, pressure-dependent, and shear-dependent factors.


RSC Advances ◽  
2016 ◽  
Vol 6 (36) ◽  
pp. 29920-29930 ◽  
Author(s):  
Anu Kadyan ◽  
Kamalakanta Behera ◽  
Siddharth Pandey

In mixture of a deep eutectic solvent Reline with tetraethylene glycol, inter-species interactions are stronger than the intra-species interactions.


2015 ◽  
Vol 4 (8) ◽  
pp. 788-793
Author(s):  
Hui Nie ◽  
Yanfang Geng ◽  
Dapeng Luo ◽  
Miaoqing Liu ◽  
Yifei Wang ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document