Catenation and Kinetics of the Diels-Alder Step-Growth Reaction in the Synthesis of Phenylated Polyphenylenes

1972 ◽  
Vol 5 (1) ◽  
pp. 49-55 ◽  
Author(s):  
J. K. Stille ◽  
G. K. Noren
Keyword(s):  
Diels Alder ◽  
Growth Reaction ◽  
Step Growth ◽  
Kinetics Of

Kinetic Study of the Diels-Alder Reaction of Cyclopentadiene with Bis(2-Ethylhexyl) Maleate

2013 ◽  
Vol 634-638 ◽  
pp. 541-545 ◽  
Author(s):  
Jun Seong Park ◽  
Dae Hee Yun ◽  
Tae Won Ko ◽  
Yong Sung Park ◽  
Je Wan Woo
Keyword(s):  
Kinetic Study ◽  
Reaction Temperature ◽  
Atmospheric Pressure ◽  
Arrhenius Equation ◽  
Alder Reaction ◽  
Diels Alder ◽  
Influence Of Temperature ◽  
Diels Alder Reaction ◽  
Influence Of Temperature On ◽  
Kinetics Of

The kinetics of the Diels-Alder reaction of cyclopentadiene with bis(2-ethylhexyl) maleate has been studied at temperatures between 25 and 100 °C and at atmospheric pressure. The influence of temperature on the kinetic constants was determined by fitting the results to the Arrhenius equation. As a result, fitting line similar with the linear curve of the Arrhenius equation at 25, 30 and 40 °C. However, the fitting curve, at 60, 80 and 100 °C, tended towards the outside of the curve in the form of Arrhenius equation. The ratio of endo/exo was a slight change from increase of the reaction temperature.

Kinetics of the diels-alder addition of ethene to cyclohexa-1,3-diene and its reverse reaction in the gas phase

1980 ◽  
Vol 12 (4) ◽  
pp. 253-259 ◽  
Author(s):  
G. Huybrechts ◽  
D. Rigaux ◽  
J. Vankeerberghen ◽  
B. Van Mele
Keyword(s):  
Gas Phase ◽  
Diels Alder ◽  
Reverse Reaction ◽  
Kinetics Of

Reply to Comment on “Kinetics of a Diels−Alder Reaction of Maleic Anhydride and Isoprene in Supercritical CO2”

2003 ◽  
Vol 107 (43) ◽  
pp. 9249-9249 ◽  
Author(s):  
Evgeni M. Glebov ◽  
Larisa G. Krishtopa ◽  
Victor Stepanov ◽  
Lev N. Krasnoperov
Keyword(s):  
Maleic Anhydride ◽  
Supercritical Co2 ◽  
Alder Reaction ◽  
Diels Alder ◽  
Diels Alder Reaction ◽  
Kinetics Of

Kinetics of a Diels—Alder Reaction in Supercritical Propane

1995 ◽  
pp. 166-178 ◽  
Author(s):  
Barbara L. Knutson ◽  
Angela K. Dillow ◽  
Charles L. Liotta ◽  
Charles A. Eckert
Keyword(s):  
Alder Reaction ◽  
Diels Alder ◽  
Diels Alder Reaction ◽  
Kinetics Of

Synthesis and Incorporation of Thienylene Vinylene Oligomers in Main-Chain Copolymers

1997 ◽  
Vol 488 ◽  
Author(s):  
L. G. Madrigal ◽  
E. H. Elandaloussi ◽  
C. W. Spangler
Keyword(s):  
Main Chain ◽  
Radical Cations ◽  
Synthetic Approach ◽  
Chemical Doping ◽  
Third Order ◽  
The Past ◽  
Growth Reaction ◽  
Oxidative Doping ◽  
Step Growth ◽  
Conductivity Behavior

AbstractPoly [2,5-thienylene vinylene] (PTV) has been studied extensively over the past decade for both its metallic conductivity behavior upon chemical doping, as well as its interesting third order nonlinear optical properties. PTV oligomers have been synthesized by our group 1, as well as others 2, and the formation of polaron-like radical-cations or bipolaron-like dications by oxidative doping has been demonstrated. In this paper we describe a general synthetic approach to PTV oligomers functionalized for copolymer formation by step-growth reaction.

Direct insight into the kinetics of the high-pressure step-growth polymerization of DGEBA/aniline model system

Polymer ◽  
2019 ◽  
Vol 172 ◽  
pp. 322-329 ◽  
Author(s):  
Andrzej Dzienia ◽  
Kajetan Koperwas ◽  
Magdalena Tarnacka ◽  
Mirosław Chorążewski ◽  
Eugene B. Postnikov ◽  
...  
Keyword(s):  
High Pressure ◽  
Model System ◽  
Pressure Step ◽  
Step Growth ◽  
Step Growth Polymerization ◽  
Kinetics Of ◽  
Insight Into

Step growth polymerization via tandem ene and diels-alder reactions

1997 ◽  
Vol 198 (2) ◽  
pp. 251-263 ◽  
Author(s):  
Shadpour E. Mallakpour ◽  
Heinz Kolshorn ◽  
Dieter Schollmeyer ◽  
Reimund Stadler
Keyword(s):  
Diels Alder ◽  
Step Growth ◽  
Step Growth Polymerization

Kinetics of Diels-Alder Reactions of Eleostearic Acids with Maleic Anhydride and Substituted Maleic Anhydrides

1957 ◽  
Vol 22 (9) ◽  
pp. 1080-1083 ◽  
Author(s):  
W. G. BICKFORD ◽  
JOAN S. HOFFMANN ◽  
DOROTHY C. HEINZELMAN ◽  
SARA P. FORE
Keyword(s):  
Maleic Anhydride ◽  
Diels Alder ◽  
Kinetics Of
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