Mechanism of Isotactic Polypropylene Formation withC1-Symmetric Metallocene Catalysts

2006 ◽  
Vol 25 (15) ◽  
pp. 3576-3592 ◽  
Author(s):  
Stephen A. Miller ◽  
John E. Bercaw
Keyword(s):  
Isotactic Polypropylene ◽  
Metallocene Catalysts

Tailoring the Physical Properties of Isotactic Polypropylene through Incorporation of Comonomers and the Precise Control of Stereo- and Regioregularity by Metallocene Catalysts

2007 ◽  
Vol 19 (21) ◽  
pp. 5122-5130 ◽  
Author(s):  
Claudio De Rosa ◽  
Finizia Auriemma ◽  
Odda Ruiz de Ballesteros ◽  
Luigi Resconi ◽  
Isabella Camurati
Keyword(s):  
Physical Properties ◽  
Isotactic Polypropylene ◽  
Metallocene Catalysts ◽  
Precise Control

Structure−Property Correlations in Polypropylene from Metallocene Catalysts:  Stereodefective, Regioregular Isotactic Polypropylene

2004 ◽  
Vol 126 (51) ◽  
pp. 17040-17049 ◽  
Author(s):  
Claudio De Rosa ◽  
Finizia Auriemma ◽  
Annunziata Di Capua ◽  
Luigi Resconi ◽  
Simona Guidotti ◽  
...  
Keyword(s):  
Isotactic Polypropylene ◽  
Metallocene Catalysts ◽  
Structure Property ◽  
Property Correlations

Properties of nanocomposites based on isotactic polypropylene and high-pressure polyethylene with metal-containing nanofillers

2020 ◽  
pp. 59-64
Author(s):  
N. I. Kurbanova ◽  
◽  
T. M. Gulieva ◽  
N. Ya. Ischenko ◽  
◽  
...  
Keyword(s):  
High Pressure ◽  
Synergistic Effect ◽  
Polymer Matrix ◽  
Isotactic Polypropylene ◽  
Rheological Parameters ◽  
Mechanochemical Method ◽  
X Ray ◽  
Effect Of Additives ◽  
High Pressure Polyethylene ◽  
Properties Of Composites

The effect of additives of nanofillers (NF) containing nanoparticles (NP) of copper oxide, stabilized by a polymer matrix of maleized polyethylene (MPE), obtained by the mechanochemical method, on the properties of composites based on isotactic polypropylene (PP) and high-pressure polyethylene (PE) was studied by X-ray phase (XRD) and thermogravimetric (TGA) analyzes. The enhancement of strength, deformation, and rheological parameters, as well as the thermo-oxidative stability of the obtained nanocomposites was revealed, which, apparently, is due to the synergistic effect of the interaction of copper-containing nanoparticles with anhydride groups of MPE. It is shown that nanocomposites based on PP/PE/NF can be processed both by pressing and injection molding and extrusion, which expands the scope of its application.

Cationic modifications of polyalkenes II. Effect of a single or continuous supply of Co-initiator

1989 ◽  
Vol 54 (5) ◽  
pp. 1269-1275
Author(s):  
Miloslav Kučera ◽  
Dušan Kimmer ◽  
Karla Majerová ◽  
Zdeněk Fiala
Keyword(s):  
Isotactic Polypropylene ◽  
Graft Copolymers ◽  
Single Addition

For an effective modification of polyalkenes leading to the formation of block and/or graft copolymers, the presence of co-initiating water is absolutely necessary. We have compared two procedures used in the co-initiation of cationic reactions on polymers. Gradually supplied air moisture raises the efficiency of modification of isotactic polypropylene with poly(oxyethylene) several times, compared with a single addition of co-initiating water.

Radiation Induced Graft Copolymerization of Vinyl Acetate and Isopropenyl Acetate Onto Isotactic Polypropylene

1996 ◽  
Vol 61 (2) ◽  
pp. 259-267 ◽  
Author(s):  
Bhupendra N. Misra ◽  
G. S. Chauhan ◽  
Inderjeet Kaur
Keyword(s):  
Vinyl Acetate ◽  
Isotactic Polypropylene ◽  
Graft Copolymerization ◽  
Optimum Conditions ◽  
Reaction Parameters ◽  
Maximum Percentage ◽  
Radiation Induced ◽  
Isopropenyl Acetate

Radiation-induced graft copolymerization of vinyl acetate (VAC) and isopropenyl acetate (PAC) onto isotactic polypropylene (IPP) has been studied. The percentage of grafting was calculated for various reaction parameters, and the optimum conditions for attaining the maximum percentage of grafting were determined. Maximal achieved extents of grafting are 39% and 29% for VAC and PAC, respectively. The reactivity of the two monomers with respect to grafting is discussed.

scholarly journals Unique Slow Crack Growth Behavior of Isotactic Polypropylene: The Role of Shear Layer-Spherulites Layer Alternated Structure

Polymers ◽  
2020 ◽  
Vol 12 (11) ◽  
pp. 2746
Author(s):  
Mingjin Liu ◽  
Jiaxu Luo ◽  
Jin Chen ◽  
Xueqin Gao ◽  
Qiang Fu ◽  
...  
Keyword(s):  
Shear Layer ◽  
Crack Growth ◽  
Isotactic Polypropylene ◽  
Slow Crack Growth ◽  
Crack Growth Behavior ◽  
Polymer Science ◽  
The Past ◽  
Propagation Behavior ◽  
Crack Propagation Behavior

With the development of polymer science, more attention is being paid to the longevity of polymer products. Slow crack growth (SCG), one of the most important factors that reveal the service life of the products, has been investigated widely in the past decades. Here, we manufactured an isotactic polypropylene (iPP) sample with a novel shear layer–spherulites layer alternated structure using multiflow vibration injection molding (MFVIM). However, the effect of the alternated structure on the SCG behavior has never been reported before. Surprisingly, the results showed that the resistivity of polymer to SCG can be enhanced remarkably due to the special alternated structure. Moreover, this sample shows unique slow crack propagation behavior in contrast to the sample with the same thickness of shear layer, presenting multiple microcracks in the spherulites layer, which can explain the reason of the resistivity improvement of polymer to SCG.

Mesoporous films based on isotactic polypropylene deformed via the mechanism of crazing

2021 ◽  
Vol 70 (1) ◽  
pp. 62-66
Author(s):  
L. M. Yarysheva ◽  
A. Yu. Yarysheva ◽  
O. V. Arzhakova ◽  
A. L. Volynskii
Keyword(s):  
Isotactic Polypropylene ◽  
Mesoporous Films
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