η5-Cyclopentadienyl-η3-1-phenylallylpalladium, an Unusually Effective Catalyst Precursor for Copper-Free and Copper-Assisted Sonogashira Cross-Coupling Reactions Catalyzed by Bis-phosphine Palladium(0) Compounds: The Role of Bis-acetylide Intermediates in the Reduction of a Palladium(II) Catalyst Precursor to a Palladium(0) Catalyst

2013 ◽  
Vol 32 (15) ◽  
pp. 4192-4198 ◽  
Author(s):  
Bryan E. Jaksic ◽  
Jingsi Jiang ◽  
Andrew W. Fraser ◽  
Michael C. Baird
Keyword(s):  
Cross Coupling ◽  
Catalyst Precursor ◽  
Coupling Reactions ◽  
Effective Catalyst ◽  
Cross Coupling Reactions

Pd(η3-1-PhC3H4)(η5-C5H5), an Unusually Effective Catalyst Precursor for Heck–Mizoroki and Sonogashira Cross-Coupling Reactions Catalyzed by Bis-Phosphine Palladium(0) Compounds

2012 ◽  
Vol 32 (1) ◽  
pp. 9-11 ◽  
Author(s):  
Andrew W. Fraser ◽  
Bryan E. Jaksic ◽  
Rhys Batcup ◽  
Christopher D. Sarsons ◽  
Michael Woolman ◽  
...  
Keyword(s):  
Cross Coupling ◽  
Catalyst Precursor ◽  
Coupling Reactions ◽  
Effective Catalyst ◽  
Cross Coupling Reactions

SBA‐15/POSS‐Imidazolium Hybrid as Catalytic Nanoreactor: the role of the Support in the Stabilization of Palladium Species for C−C Cross Coupling Reactions.

2019 ◽  
Vol 361 (16) ◽  
pp. 3758-3767 ◽  
Author(s):  
Carla Calabrese ◽  
Vincenzo Campisciano ◽  
Fabiana Siragusa ◽  
Leonarda F. Liotta ◽  
Carmela Aprile ◽  
...  
Keyword(s):  
Cross Coupling ◽  
Coupling Reactions ◽  
Cross Coupling Reactions

Highly selective Suzuki reaction catalysed by a molecular Pd-P-MOF catalyst under mild conditions: role of ligands and palladium speciation

2022 ◽  
Author(s):  
Daniele Cartagenova ◽  
Stephan Bachmann ◽  
Kurt Püntener ◽  
Michelangelo Scalone ◽  
Mark A Newton ◽  
...  
Keyword(s):  
Large Scale ◽  
State Of The Art ◽  
Suzuki Reaction ◽  
Cross Coupling ◽  
Palladium Complexes ◽  
Fine Chemicals ◽  
Coupling Reactions ◽  
Mild Conditions ◽  
Cross Coupling Reactions

Cross-coupling reactions are a fundamental tool in the large scale synthesis of pharma-, agro- and fine chemicals. Homogeneous palladium complexes remain the state-of-the-art catalysts even though the use of heterogeneous...

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