EPR Spectra of [Cr(CO)2L(η-C6Me6)]+(L = PEt3, PPh3, P(OEt)3, P(OPh)3):  Analysis of Line Widths and Determination of Ground State Configuration from Interpretation of31P Couplings

1997 ◽  
Vol 16 (20) ◽  
pp. 4369-4376 ◽  
Author(s):  
Michael P. Castellani ◽  
Neil G. Connelly ◽  
Robert D. Pike ◽  
Anne L. Rieger ◽  
Philip H. Rieger
2021 ◽  
Vol 2021 (8) ◽  
Author(s):  
Simeon Hellerman ◽  
Nozomu Kobayashi ◽  
Shunsuke Maeda ◽  
Masataka Watanabe

Abstract As a sequel to previous work, we extend the study of the ground state configuration of the D = 3, Wilson-Fisher conformal O(4) model. In this work, we prove that for generic ratios of two charge densities, ρ1/ρ2, the ground-state configuration is inhomogeneous and that the inhomogeneity expresses itself towards longer spatial periods. This is the direct extension of the similar statements we previously made for ρ1/ρ2 ≪ 1. We also compute, at fixed set of charges, ρ1, ρ2, the ground state energy and the two-point function(s) associated with this inhomogeneous configuration on the torus. The ground state energy was found to scale (ρ1 + ρ2)3/2, as dictated by dimensional analysis and similarly to the case of the O(2) model. Unlike the case of the O(2) model, the ground also strongly violates cluster decomposition in the large-volume, fixed-density limit, with a two-point function that is negative definite at antipodal points of the torus at leading order at large charge.


2014 ◽  
Vol 69 (8-9) ◽  
pp. 397-402
Author(s):  
Leyla Özdemir ◽  
Sadiye Tuna

We have investigated the correlation, relativistic, and isotope shift effects on the fine structure levels in the ground state configuration for the antimony anion ( Sb-). Energies and radiative transition probabilities (for magnetic dipole, M1, and electric quadrupole, E2) have been obtained using the multiconfiguration Hartree-Fock method within the framework of the Breit-Pauli Hamiltonian. Therefore, the most important configuration interaction and relativistic effects have been included. Comparisons with other available works are presented. For some M1 and E2 lines the considered transition probabilities are reported for the first time


1983 ◽  
Vol 133 (1-2) ◽  
pp. 44-46 ◽  
Author(s):  
R. Eder ◽  
E. Hagn ◽  
E. Zech

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